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Tetrabutylammonium acetate

Product Name
Tetrabutylammonium acetate
CAS No.
10534-59-5
Chemical Name
Tetrabutylammonium acetate
Synonyms
TETRA-N-BUTYLAMMONIUM ACETATE;etrabutylammonium acetate;[B4N]Ac;TETRABUTYLAMMON;TETRABUTYLAMINE ACETATE;Tetrabutylaminium·acetate;TETRABUTYLAMMONIUM ACETATE;tetrabutylammomium acetate;TetrabutylaMMoniuM acetate 97%;Tetra Butyl Ammonium Acetate 1
CBNumber
CB5237001
Molecular Formula
C18H39NO2
Formula Weight
301.51
MOL File
10534-59-5.mol
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Tetrabutylammonium acetate Property

Melting point:
95-98 °C (lit.)
Boiling point:
100 °C
Density 
0.99 g/mL at 25 °C
refractive index 
n20/D 1.389
Flash point:
100°C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
acetonitrile: 0.1 g/mL, clear, colorless to very faint brown
form 
Crystalline
color 
White
Sensitive 
Hygroscopic
BRN 
3599376
Stability:
Hygroscopic
InChIKey
MCZDHTKJGDCTAE-UHFFFAOYSA-M
CAS DataBase Reference
10534-59-5(CAS DataBase Reference)
EPA Substance Registry System
1-Butanaminium, N,N,N-tributyl-, acetate (10534-59-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
3-10
TSCA 
Yes
HS Code 
29239000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
335991
Product name
Tetrabutylammonium acetate
Purity
97%
Packaging
5g
Price
$111
Updated
2024/03/01
Sigma-Aldrich
Product number
335991
Product name
Tetrabutylammonium acetate
Purity
97%
Packaging
10g
Price
$189
Updated
2024/03/01
TCI Chemical
Product number
T2694
Product name
Tetrabutylammonium Acetate
Purity
>90.0%(T)
Packaging
25g
Price
$69
Updated
2024/03/01
TCI Chemical
Product number
T2694
Product name
Tetrabutylammonium Acetate
Purity
>90.0%(T)
Packaging
100g
Price
$199
Updated
2024/03/01
Alfa Aesar
Product number
019279
Product name
Tetra-n-butylammonium acetate
Packaging
1g
Price
$24.65
Updated
2024/03/01
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Tetrabutylammonium acetate Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

Tetrabutylammonium Acetate acts as a catalyst in organic syntheses of anion sensors.

Application

Tetrabutylammonium acetate can be used:
To catalyze the alkynylation of carbonyl compounds with trimethylsilylacetylenes providing good yields of propargylic alcohols.
Along with tetrabutylammonium bromide (TBAB) as a molten reaction medium in the synthesis of 4-aryl-2-quinolones.
As a promoter in the regioselective direct arylation of azoles (1-methylpyrazole, oxazole, and thiazole) with aryl bromides in presence of palladium acetate catalyst.
As an ionic liquid to dissolve cellulose in the presence of DMSO co-solvent.
As an activator in the synthesis of disubstituted alkynes through copper-free Sonogashira coupling reaction.

General Description

Tetrabutylammonium acetate (TBAA) is a phase transfer catalyst (PTC).

Advantages

Tetrabutylammonium Acetate (TBAAc) could be used as the Buffer Layer between the SnO2 Electron Transport Film and CsPbI3 within All-Inorganic Perovskite Solar Cells. The TBAAc buffer layer suppresses heterogeneous CsPbI3 perovskite nucleation, which leads to larger grain sizes, better charge transfer, and the enhancement of the photovoltaic performance of CsPbI3 PSCs. In addition, interfacial trap-assisted recombination was reduced and the charge extraction efficiency was remarkably improved[1].

References

[1] Hang Zhong. “All-Inorganic Perovskite Solar Cells with Tetrabutylammonium Acetate as the Buffer Layer between the SnO2 Electron Transport Film and CsPbI3.” ACS Applied Materials Interfaces 14 4 (2022): 5183–5193.

Tetrabutylammonium acetate Preparation Products And Raw materials

Raw materials

Preparation Products

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Tetrabutylammonium acetate Suppliers

Dishman USA, Inc.
Tel
--
Fax
--
Country
Canada
ProdList
743
Advantage
75
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View Lastest Price from Tetrabutylammonium acetate manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
Tetrabutylammonium acetate 10534-59-5
Price
US $100.00-75.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000
Release date
2024-08-21
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Tetrabutylammonium acetate 10534-59-5
Price
US $0.00-0.00/Kg/Drum
Min. Order
1KG
Purity
98%min
Supply Ability
1000KGS
Release date
2021-07-21
Henan Fengda Chemical Co., Ltd
Product
Tetrabutylammonium acetate 10534-59-5
Price
US $5.00-0.50/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-13

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