Carbamic acid, N-(cis-3-aminocyclobutyl)-, 1,1-dimethylethyl ester
- Product Name
- Carbamic acid, N-(cis-3-aminocyclobutyl)-, 1,1-dimethylethyl ester
- CAS No.
- 1212395-34-0
- Chemical Name
- Carbamic acid, N-(cis-3-aminocyclobutyl)-, 1,1-dimethylethyl ester
- Synonyms
- tert-butyl ((1s,3s)-3-aMinocyclobutyl)carbaMate;cis-N-Boc-1,3-diaMinocyclobutane;cis-N1-Boc-cyclobutane-1,3-diamine;cis-tert-butyl-3-aMinocyclobutylcarbaMate;cis-tert-Butyl 3-aMinocyclobutanecarbaMate;tert-Butyl N-(3-aMinocyclobutyl)-carbaMate;tert-butyl (cis-3-aMinocyclobutyl)carbaMate;tert-ButylN-(cis-3-aminocyclobutyl)carbamate;cis tert-Butyl N-(3-aMinocyclobutyl)carbaMate;real- TERT-BUTYL N-(3-AMINOCYCLOBUTYL)CARBAMATE, cis
- CBNumber
- CB52525258
- Molecular Formula
- C9H18N2O2
- Formula Weight
- 186.25
- MOL File
- 1212395-34-0.mol
Carbamic acid, N-(cis-3-aminocyclobutyl)-, 1,1-dimethylethyl ester Property
- Boiling point:
- 285.8±29.0 °C(Predicted)
- Density
- 1.06±0.1 g/cm3(Predicted)
- storage temp.
- 2-8°C, protect from light
- pka
- 12.32±0.40(Predicted)
- Appearance
- White to yellow Solid
Safety
- HS Code
- 2924297099
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- OR308090
- Product name
- tert-Butyl (cis-3-aminocyclobutyl)carbamate
- Packaging
- 100mg
- Price
- $237
- Updated
- 2021/12/16
- Product number
- 068481
- Product name
- cis tert-Butyl N-(3-aminocyclobutyl)carbamate
- Purity
- >95%
- Packaging
- 500mg
- Price
- $295
- Updated
- 2021/12/16
- Product number
- OR308090
- Product name
- tert-Butyl (cis-3-aminocyclobutyl)carbamate
- Packaging
- 250mg
- Price
- $412
- Updated
- 2021/12/16
- Product number
- 068481
- Product name
- cis tert-Butyl N-(3-aminocyclobutyl)carbamate
- Purity
- >95%
- Packaging
- 1g
- Price
- $450
- Updated
- 2021/12/16
- Product number
- 4256-1-41
- Product name
- tert-Butyl (cis-3-aminocyclobutyl)carbamate
- Packaging
- 1g
- Price
- $575
- Updated
- 2021/12/16
Carbamic acid, N-(cis-3-aminocyclobutyl)-, 1,1-dimethylethyl ester Chemical Properties,Usage,Production
Synthesis
1239589-57-1
1212395-34-0
Tert-butyl cis-3-azido cyclobutylcarbamate (15.00 g, 70.7 mmol) was used as a feedstock and mixed with 10 wt% palladium/activated carbon catalyst (dry basis) in a 1000 mL three-neck flask. The system was flushed with N2 and sealed with methanol (200 mL) and 2 M ammonia (3.76 mL, 35.3 mmol, Sigma-Aldrich Chemical Company, Inc.). The flask was evacuated and filled with hydrogen (balloon supply). The reaction mixture was stirred at room temperature for 18 hours and subsequently filtered. The filtrate was concentrated under reduced pressure to afford tert-butyl cis-3-amino-1-cyclobutylcarbamate (11.1 g, 59.6 mmol, 84% yield), which could be used in subsequent steps without further purification.
References
[1] Journal of Organic Chemistry, 2010, vol. 75, # 17, p. 5941 - 5952
[2] Patent: US2013/225552, 2013, A1. Location in patent: Paragraph 0990
Carbamic acid, N-(cis-3-aminocyclobutyl)-, 1,1-dimethylethyl ester Preparation Products And Raw materials
Raw materials
Preparation Products
Carbamic acid, N-(cis-3-aminocyclobutyl)-, 1,1-dimethylethyl ester Suppliers
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