ChemicalBook > CAS DataBase List > Methyl 4-cyanobenzoate

Methyl 4-cyanobenzoate

Product Name
Methyl 4-cyanobenzoate
CAS No.
1129-35-7
Chemical Name
Methyl 4-cyanobenzoate
Synonyms
RARECHEM AL BF 0074;SPECS AC-907/25014377;Methy-4-cyanobenzoate;Methyl-4-Cyanobenoate;METHYL P-CYANOBENZOATE;LABOTEST-BB LT00159784;METHYL 4-CYANOBENZOATE;Methyle4-cyanobenzoate;Mesocyanobenzoaldehyde;Methyl4-Cyanobenzoate>
CBNumber
CB5280052
Molecular Formula
C9H7NO2
Formula Weight
161.16
MOL File
1129-35-7.mol
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Methyl 4-cyanobenzoate Property

Melting point:
65-67 °C(lit.)
Boiling point:
142-144 °C12 mm Hg(lit.)
Density 
1.2480 (rough estimate)
refractive index 
1.5050 (estimate)
Flash point:
142-144°C/12mm
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform, Ethyl Acetate
form 
Crystalline Powder
color 
White to off-white
Water Solubility 
Insoluble in water. Soluble in chloroform and ethyl acetate.
BRN 
1866980
InChIKey
KKZMIDYKRKGJHG-UHFFFAOYSA-N
CAS DataBase Reference
1129-35-7(CAS DataBase Reference)
NIST Chemistry Reference
4-Cyanobenzoic acid methyl ester(1129-35-7)
EPA Substance Registry System
Methyl 4-cyanobenzoate (1129-35-7)
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Safety

Risk Statements 
20/21/22-36/37/38
Safety Statements 
22-24/25-60-36/37-26-9
RIDADR 
3439
WGK Germany 
3
Hazard Note 
Harmful
HazardClass 
6.1
PackingGroup 
III
HS Code 
29269090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H301Toxic if swalloed

H311Toxic in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
230634
Product name
Methyl 4-cyanobenzoate
Purity
99%
Packaging
5g
Price
$113
Updated
2024/03/01
Sigma-Aldrich
Product number
230634
Product name
Methyl 4-cyanobenzoate
Purity
99%
Packaging
25g
Price
$341
Updated
2023/06/20
TCI Chemical
Product number
C1119
Product name
Methyl 4-Cyanobenzoate
Purity
>98.0%(GC)
Packaging
25g
Price
$76
Updated
2024/03/01
TCI Chemical
Product number
C1119
Product name
Methyl 4-Cyanobenzoate
Purity
>98.0%(GC)
Packaging
250g
Price
$436
Updated
2024/03/01
Alfa Aesar
Product number
L08365
Product name
Methyl 4-cyanobenzoate, 99%
Packaging
5g
Price
$43
Updated
2024/03/01
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Methyl 4-cyanobenzoate Chemical Properties,Usage,Production

Description

Methyl 4-cyanobenzoate, which is 4-cyanobenzoic acid or its methyl ester, is an intermediate used in various applications, such as pharmaceuticals, pesticides, precursors of liquid crystals, and/or functional polymer monomers.

Chemical Properties

Off-White Solid

Uses

Methyl 4-Cyanobenzoate (cas# 1129-35-7) is a compound useful in organic synthesis.

Synthesis Reference(s)

Synthesis, p. 750, 1991 DOI: 10.1055/s-1991-26566

Synthesis

m-Cyanobenzamide (73.0 g, 0.5 mol), which has a purity of 99% or more and methanol (460.3 g) were placed in a 2 l-separable flask. The mixture was allowed to react at 64° C. for 12 hours while a 20% hydrochloric acid/methanol solution (162.4 g) prepared in advance was added to it with stirring. Gas chromatographic analysis revealed that the reaction mixture contained 74.9 g of Methyl 4-cyanobenzoate (yield 93%).

Methyl 4-cyanobenzoate Preparation Products And Raw materials

Raw materials

Sodium Methoxide Diethyl ether 1,4-Dicyanobenzene Hydrochloric acid Methanol

Preparation Products

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View Lastest Price from Methyl 4-cyanobenzoate manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Methyl 4-cyanobenzoate 1129-35-7
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-12-03
Shaanxi Dideu Medichem Co. Ltd
Product
Methyl 4-cyanobenzoate 1129-35-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000MT
Release date
2024-07-17
Shaanxi Dideu Medichem Co. Ltd
Product
Methyl 4-cyanobenzoate 1129-35-7
Price
US $0.10/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10
Release date
2024-07-14

1129-35-7, Methyl 4-cyanobenzoateRelated Search:

Ethyl 4-cyanobenzoate Methyl 4-formylbenzoate Methyl 4-fluorobenzoate Methyl 4-ethoxybenzoate METHYL 4-FLUOROBENZOYLACETATE 4-(Hydroxymethyl)phenoxyacetic acid Sodium methylparaben Sodium propylparaben Methyl benzoate METHYL 2-CYANOBENZOATE METHYL 3-CYANOBENZOATE,Methyl m-cyanobenzoate Methyl 4-cyanobenzoate 5-Cyanophthalide Methyl 4-cyano-3-fluorobenzoate 4-Cyanobenzoic acid ETHYL 4-CYANO-3-NITROBENZOATE Hydroquinone, mono(p-cyanobenzoate) (8CI) Methyl 2-bromomethyl-4-cyanobenzoate

  • Benzoic acid, 4-cyano-, methyl ester
  • Benzoic acid, p-cyano-, methyl ester
  • RARECHEM AL BF 0074
  • SPECS AC-907/25014377
  • P-CYANOBENZOIC ACID METHYL ESTER
  • METHYL 4-CYANOBENZOATE
  • LABOTEST-BB LT00159784
  • METHYL P-CYANOBENZOATE
  • 4-CYAN-BENZOIC ACID-METHYL ESTER
  • 4-CYANOBENZOIC ACID METHYL ESTER
  • Methy-4-cyanobenzoate
  • 4-(Methoxycarbonyl)benzonitrile
  • Cyanbenzoicacidmethylester
  • Methyl-4-Cyanobenoate
  • Methyl 4-cyanobenzoate 98%
  • 4-Cyanobenzoic acid methyl
  • Methyl 4-cyanobenzoate,99%
  • Methyle4-cyanobenzoate
  • Methyl 4-Cyanobenzoate, 97+%
  • Methyl4-Cyanobenzoate&gt
  • BENZOIC ACID， METHYL-4-CYANOBENZOATE
  • Mesocyanobenzoaldehyde
  • 4-Cyanobenzoicacidmethylester / Methyl 4-cyanobenzoate
  • 1129-35-7
  • 1229-35-7
  • NCC6H4CO2CH3
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  • C8 to C9
  • Organic Building Blocks
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