N-Phenyl-bis(trifluoromethanesulfonimide)

ChemicalBook > CAS DataBase List > N-Phenyl-bis(trifluoromethanesulfonimide)

N-Phenyl-bis(trifluoromethanesulfonimide)

Product Name: N-Phenyl-bis(trifluoromethanesulfonimide)
CAS No.: 37595-74-7
Chemical Name: N-Phenyl-bis(trifluoromethanesulfonimide)
Synonyms: PHENYL TRIFLIMIDE;N,N-BIS(TRIFLUOROMETHYLSULFONYL)ANILINE;N-PHENYLBIS(TRIFLUOROMETHANESULFONIMIDE);1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide;N-PHENYLTRIFLUOROMETHANESULFONIMIDE;phenyltrifluoromethanesulfonimide;N-PHENYLBIS(TRIFLUOROMETHANESULPHONIMIDE);trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide;N-PHENYLT;NSC 240874
CBNumber: CB5289550
Molecular Formula: C8H5F6NO4S2
Formula Weight: 357.25
MOL File: 37595-74-7.mol

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N-Phenyl-bis(trifluoromethanesulfonimide) Property

Melting point:: 100-102 °C(lit.)
Boiling point:: 305.3±52.0 °C(Predicted)
Density: 1.766±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Soluble in methanol. Slightly soluble in chloroform and ethyl acetate.
form: Crystals or Crystalline Powder
pka: -13.12±0.50(Predicted)
color: White or colorless
Sensitive: Moisture Sensitive
BRN: 1269141
Stability:: Moisture Sensitive
InChI: InChI=1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H
InChIKey: DIOHEXPTUTVCNX-UHFFFAOYSA-N
SMILES: C(F)(F)(F)S(N(C1=CC=CC=C1)S(C(F)(F)F)(=O)=O)(=O)=O
CAS DataBase Reference: 37595-74-7(CAS DataBase Reference)
NIST Chemistry Reference: N-phenyltrifluoromethanesulfonimide(37595-74-7)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
F: 21
TSCA: No
HazardClass: IRRITANT
HS Code: 29242100

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 295973
Product name: N-Phenyl-bis(trifluoromethanesulfonimide)
Purity: 99%
Packaging: 5g
Price: $82.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 295973
Product name: N-Phenyl-bis(trifluoromethanesulfonimide)
Purity: 99%
Packaging: 25g
Price: $201
Updated: 2024/03/01

TCI Chemical

Product number: P1257
Product name: N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent]
Purity: >98.0%(GC)
Packaging: 5g
Price: $23
Updated: 2024/03/01

TCI Chemical

Product number: P1257
Product name: N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent]
Purity: >98.0%(GC)
Packaging: 25g
Price: $80
Updated: 2024/03/01

Alfa Aesar

Product number: L12531
Product name: N-Phenylbis(trifluoromethanesulfonimide), 99%
Packaging: 5g
Price: $72.1
Updated: 2024/03/01

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N-Phenyl-bis(trifluoromethanesulfonimide) Chemical Properties,Usage,Production

Description

N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation.

Chemical Properties

white to off-white crystalline powder

Uses

N-Phenylbis(trifluoromethanesulfonamide) is used in the enantioselective synthesis of β-amino acids via the Mannich reaction. Used in the synthesis of sphingosine 1-phosphate-1 receptor agonists useful in pharmaceutical application.

Uses

Acts as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes

Reactant for:
Synthesis of amphoteric alpha-boryl aldehydes
Enantioselective synthesis of core ring skeleton of leucosceptroids A-D
Stereoselective synthesis of monoamine reuptake inhibitor NS9544 acetate
Stereoselective sulfoxidation

Synthesis

Add methylene chloride, aniline, 4-dimethylaminopyridine (DMAP), and triethylamine to a reactor equipped with a thermometer, distillation device, and mechanical stirring. When the vacuum of the reactor is evacuated to -0.095MPa and cooled to -40°C, trifluoromethanesulfonyl fluoride gas is introduced and then stirred at -20°C ~ 0°C and 0.02MPa ~ 0.1MPa reaction pressure, and react for 6 hours Finally, the excess trifluoromethanesulfonyl fluoride gas in the reactor is released and collected by cooling. After the inside of the reactor is brought to normal pressure, 500 mL of water is added, and the liquid is separated. A light yellow solid is obtained after the organic phase is heated to 40°C and methylene chloride is distilled. The light yellow solid is recrystallized with toluene to obtain 650g of white crystal N-Phenyl-bis(trifluoromethanesulfonimide).

N-Phenyl-bis(trifluoromethanesulfonimide) Preparation Products And Raw materials

Raw materials

Sodium hydride Ethanol Sodium chloride Trifluoromethanesulfonyl chloride Potassium carbonate Trifluoromethanesulfonic anhydride Triethylamine Tetrahydrofuran Aniline Dichloromethane Sodium hydroxide Magnesium sulfate

Preparation Products

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View Lastest Price from N-Phenyl-bis(trifluoromethanesulfonimide) manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7
Price: US $0.00-0.00/KG
Min. Order: 10mg
Purity: 99%HPLC
Supply Ability: 2000tons
Release date: 2020-01-19

Zibo Hangyu Biotechnology Development Co., Ltd

Product: N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7
Price: US $65.00-650.00/kg
Min. Order: 10kg
Purity: 0.99
Supply Ability: 20tons
Release date: 2023-11-01

WUHAN FORTUNA CHEMICAL CO., LTD

Product: N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7
Price: US $0.00-0.00/Kg/Drum
Min. Order: 1KG
Purity: 98%min GC
Supply Ability: 500 KGS
Release date: 2021-06-10

37595-74-7, N-Phenyl-bis(trifluoromethanesulfonimide)Related Search:

Triphenylmethyl Chloride O-Phthalimide Lithium bis(trifluoromethanesulphonyl)imide Aniline Succinimide Bismaleimide Trifluoromethanesulfonyl chloride Trifluoromethanesulfonimide Dimethyl sulfone N-Phenylmethanesulfonamide N-PHENYLETHYLENEDIAMINE N-phenyl-1,3,5-triazin-2-amine N-Iodosuccinimide N-Carbobenzyloxy-D-asparagine N-Fluorobenzenesulfonimide (3-Nitrobenzyl)methylamine N-Phenylmaleimide N-PHENYLMETHACRYLAMIDE

phenyltrifluoromethanesulfonimide

N-PHENYLBIS(TRIFLUOROMETHANESULFONIMIDE)

N-PHENYLBIS(TRIFLUOROMETHANESULPHONIMIDE)

N-PHENYLTRIFLUOROMETHANESULFONIMIDE

N-PHENYLTRIFLUOROMETHANESULPHONIMIDE

N,N-BIS(TRIFLUOROMETHYLSULFONYL)ANILINE

1,1,1-TRIFLUORO-N-PHENYL-N-[(TRIFLUOROMETHYL)SULFONYL]METHANESULFONAMIDE

N-Phenylbis(trifluoromethanesulphonimide), Phenyl triflimide

NSC 240874

N-Phenyl bis trifluorosulphonamide

N-Bis(trifluoromethylsulfonyl)aniline

1,1,1-trifluoro-N-(methylsulfonyl)methanesulfonamide

N- phenyl-bis (trifluoromethanesulfonyl) imide

N-Phenylbis(trifluoroMethanesulfoniMide), 97% 5GR

N,N-Bis(trifluoromethylsulfonyl)aniline Phenyl Triflimide N-Phenyltrifluoromethanesulfonimide

N,N-Bis(trifluoroMethylsufonyl)aniline

N,N-Bis(trifluoroMethylsulfonyl)aniline SynonyMs N-Phenylbis(trifluoroMethanesulfon)iMide

N-phenyldouble(threefluoro Methanesulfonic acidiMide

N-Phenyl-bis(trifluoroMethanesulfoniMide) >=98.0% (HPLC)

1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide

N-phenyl bis(trifluoromethanesulfonyl)amide

N-PHENYLT

N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7

N,N-Bis(trifluoromethylsulfonyl)aniline 37595-74-7

PHENYL TRIFLIMIDE

N,N-Bis(trifluoromethanesulphonyl)aniline~Phenyl triflimide~N-Phenyltrifluoromethanesulphonimide

Phenyl triflimide~N-Phenyltrifluoromethanesulphonimide

N-PHENYL-BIS-(TRIFLUORMETHANSULFONIMID)

N,N-BIS-(TRIFLUOROMETHANESULFONYL)ANILINE

1,1,1-Trifluoro-N-phenyl-N-(trifluoromethyl)sulphonylmethanesulphonamide

n-phenylbis(trifluorometanesulfonimide)

N-Phenyl-bis(trifluoromethyl)sulfonimide

N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent]

N-phenyl-bis(trifluoromethanesulfonamide)

N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide, Phenyl triflimide, 1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide

N-Phenyltrifluoromethanesulfonimide ,98%

N-Phenyl-bis(trifluoromethanesulfonimide),1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide, N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide, Pheny

N,N-Bis(trifluoromethylsulphonyl)aniline 98%

N-Phenylbis(trifluoromethanesulfonyl)amine

N-Phenylbis(trifluoromethylsulfonyl)amine

N-Phenyl-N,N-bis(trifluoromethylsulfonyl)amine

N-Phenylbis(trifluoromethanesulphonimide)97%

N-Phenylbis(trifluoromethanesulfonimide),97%

N-Phenylbis(trifluromethanesulphonimide)99%

trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide

-bis(trifL

fonimide)

N-Phenylbis(trifluoromethanesulfonimide)[TriflatingReagent]&gt

Methanesulfonamide, 1,1,1-trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]-

1,1,1-trifluoro-N-phenyl-N

TIANFUCHEM--37595-74-7--N-Phenyl-bis(trifluoromethanesulfonimide) factory price

Bis(trifluoromethylsulfonyl)aniline

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37595-74-7

7595-74-7

37595-74-4