Lithium bis(trifluoromethanesulphonyl)imide
- Product Name
- Lithium bis(trifluoromethanesulphonyl)imide
- CAS No.
- 90076-65-6
- Chemical Name
- Lithium bis(trifluoromethanesulphonyl)imide
- Synonyms
- LITFSI;LITHIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE;LITHIUM BIS(TRIFLUOROMETHANESULFONIMIDE);LiTFSA;LithiuM bis;BISTRIFLUOROMETHANESULFONIMIDE LITHIUM SALT;LiN（SO2CF3）2;LITHIUM TRIFLUOROMETHANESULFONIMIDE;Bistrifluoromethanesulfonimide lithium;LITHIUM BIS(TRIFLUOROMETHANESULFONYL)AMIDE
- CBNumber
- CB6311504
- Molecular Formula
- C2F6LiNO4S2
- Formula Weight
- 287.09
- MOL File
- 90076-65-6.mol
Lithium bis(trifluoromethanesulphonyl)imide Property
- Melting point:
- 234-238 °C(lit.)
- Density
- 1,334 g/cm3
- vapor pressure
- 0Pa at 25℃
- Flash point:
- >100°C (>212°F)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- H2O: 10 mg/mL, clear, colorless
- form
- Hygroscopic Powder
- color
- White
- Specific Gravity
- 1.334
- Water Solubility
- Soluble in water.
- Sensitive
- Moisture Sensitive
- BRN
- 6625414
- InChIKey
- QSZMZKBZAYQGRS-UHFFFAOYSA-N
- LogP
- -1.46
- CAS DataBase Reference
- 90076-65-6(CAS DataBase Reference)
- EPA Substance Registry System
- Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-, lithium salt (90076-65-6)
- Boiling point:
- 234-238?°C (lit.)
Safety
- Hazard Codes
- T,C
- Risk Statements
- 24/25-34-52/53-48/22
- Safety Statements
- 22-26-36/37/39-45-61
- RIDADR
- UN 2923 8/PG 2
- WGK Germany
- 2
- Hazard Note
- Harmful/Corrosive/Moisture Sensitive
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29309090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
H373May cause damage to organs through prolonged or repeated exposure
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 449504
- Product name
- Bis(trifluoromethane)sulfonimide lithium salt
- Packaging
- 250G
- Price
- $1280
- Updated
- 2024/03/01
- Product number
- 15224
- Product name
- Bis(trifluoromethane)sulfonimide lithium salt
- Purity
- puriss., ≥99.0% (19F-NMR)
- Packaging
- 10G
- Price
- $126
- Updated
- 2024/03/01
- Product number
- 15224
- Product name
- Bis(trifluoromethane)sulfonimide lithium salt
- Purity
- puriss., ≥99.0% (19F-NMR)
- Packaging
- 50G
- Price
- $326
- Updated
- 2024/03/01
- Product number
- B2542
- Product name
- Lithium Bis(trifluoromethanesulfonyl)imide
- Purity
- >98.0%(T)
- Packaging
- 25g
- Price
- $87
- Updated
- 2024/03/01
- Product number
- B2542
- Product name
- Lithium Bis(trifluoromethanesulfonyl)imide
- Packaging
- 5G
- Price
- $26
- Updated
- 2021/12/16
Lithium bis(trifluoromethanesulphonyl)imide Chemical Properties,Usage,Production
Description
Lithium bis(trifluoromethylsulphonyl)imide (LiTFSI) is normally used as a p-dopant to enhance the conductivity and hole mobility of the Spiro-OMeTAD for perovskite solar cells. It is believed that The function of LiTFSI in PSCs is similar to that in solid-state dye-sensitised solar cells.
Chemical Properties
White hygroscopic powder
Uses
Lithium bis(trifluoromethylsulfonyl)imide is used in the preparation of chiral imidazolium salt through an anion metathesis of the corresponding triflate organic electrolyte-based lithium batteries. It finds application in the preparation of rare-earth Lewis acid catalysts. It is also useful in primary and secondary lithium cells using organic liquid electrolytes and polymer batteries.
General Description
Bis(trifluoromethane)sulfonimide lithium salt is a synthetic reagent.
Flammability and Explosibility
Non flammable
Synthesis
5.91 g of anhydrous lithium fluoride and N-butyl-bistrifluoromethylsulfonimide 51.26 g. Add to 250 g of isopropyl acetate and reflux for 10 hours. It was filtered after being cooled to room temperature, and the filtrate was concentrated to dryness under reduced pressure.200 g of dichloromethane was added dropwise, and the mixture was stirred at 20 ° C for 2 hours and then filtered. Wash with dichloromethane. The filter cake was dried at 80 ° C to obtain 39.57 g of Lithium bis(trifluoromethanesulphonyl)imide. The yield is 90.7%.
Properties and Applications
Lithium bis(trifluoromethanesulphonyl)imide (LiTFSI) is a hydrophilic organic salt with many uses in electric and electronic systems. Its bis(trifluoromethane)sulfonimide anion, often called bistriflimide, is helpful in coordinating weakly with cations. LiTFSI's other important property is its extremely high solubility in water: 21 molal or ≈6 kg/L of solution. LiTFSI is safer than the formerly used salt, lithium hexafluorophosphate (LiPF6). To improve the cells' ability to transport electrical charges, researchers are doped with a combination of LiTFSI and a semiconductor called Spiro-OMeTAD1; however, this process is extremely slow. Taylor and his fellow researchers solved the problem by bubbling carbon dioxide into a solution of spiro-OMeTAD and LiTFSI while irradiating the mixture with ultraviolet light. They then cast a film from the solution onto the perovskite light absorber. The process can be completed in ≈1 minute, compared with the older, hours-long doping procedure.
Lithium bis(trifluoromethanesulphonyl)imide Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Lithium bis(trifluoromethanesulphonyl)imide manufacturers
- Product
- Lithium bis(trifluoromethanesulphonyl)imide 90076-65-6
- Price
- US $8.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20000
- Release date
- 2024-01-03
- Product
- Lithium bis(trifluoromethanesulphonyl)imide 90076-65-6
- Price
- US $6.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 2000KG/Month
- Release date
- 2024-08-05
- Product
- Lithium bis(trifluoromethanesulphonyl)imide 90076-65-6
- Price
- US $60.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 5000kg/week
- Release date
- 2024-06-04