N-Phenyl-bis(trifluoromethanesulfonimide)
- Product Name
- N-Phenyl-bis(trifluoromethanesulfonimide)
- CAS No.
- 37595-74-7
- Chemical Name
- N-Phenyl-bis(trifluoromethanesulfonimide)
- Synonyms
- PHENYL TRIFLIMIDE;N,N-BIS(TRIFLUOROMETHYLSULFONYL)ANILINE;N-PHENYLBIS(TRIFLUOROMETHANESULFONIMIDE);1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide;N-PHENYLTRIFLUOROMETHANESULFONIMIDE;phenyltrifluoromethanesulfonimide;N-PHENYLBIS(TRIFLUOROMETHANESULPHONIMIDE);trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide;N-PHENYLT;NSC 240874
- CBNumber
- CB5289550
- Molecular Formula
- C8H5F6NO4S2
- Formula Weight
- 357.25
- MOL File
- 37595-74-7.mol
N-Phenyl-bis(trifluoromethanesulfonimide) Property
- Melting point:
- 100-102 °C(lit.)
- Boiling point:
- 305.3±52.0 °C(Predicted)
- Density
- 1.766±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Soluble in methanol. Slightly soluble in chloroform and ethyl acetate.
- form
- Crystals or Crystalline Powder
- pka
- -13.12±0.50(Predicted)
- color
- White or colorless
- Sensitive
- Moisture Sensitive
- BRN
- 1269141
- Stability:
- Moisture Sensitive
- InChI
- InChI=1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H
- InChIKey
- DIOHEXPTUTVCNX-UHFFFAOYSA-N
- SMILES
- C(F)(F)(F)S(N(C1=CC=CC=C1)S(C(F)(F)F)(=O)=O)(=O)=O
- CAS DataBase Reference
- 37595-74-7(CAS DataBase Reference)
- NIST Chemistry Reference
- N-phenyltrifluoromethanesulfonimide(37595-74-7)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 295973
- Product name
- N-Phenyl-bis(trifluoromethanesulfonimide)
- Purity
- 99%
- Packaging
- 5g
- Price
- $82.1
- Updated
- 2024/03/01
- Product number
- 295973
- Product name
- N-Phenyl-bis(trifluoromethanesulfonimide)
- Purity
- 99%
- Packaging
- 25g
- Price
- $201
- Updated
- 2024/03/01
- Product number
- P1257
- Product name
- N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent]
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $23
- Updated
- 2024/03/01
- Product number
- P1257
- Product name
- N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent]
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $80
- Updated
- 2024/03/01
- Product number
- L12531
- Product name
- N-Phenylbis(trifluoromethanesulfonimide), 99%
- Packaging
- 5g
- Price
- $72.1
- Updated
- 2024/03/01
N-Phenyl-bis(trifluoromethanesulfonimide) Chemical Properties,Usage,Production
Description
N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation.
Chemical Properties
white to off-white crystalline powder
Uses
N-Phenylbis(trifluoromethanesulfonamide) is used in the enantioselective synthesis of β-amino acids via the Mannich reaction. Used in the synthesis of sphingosine 1-phosphate-1 receptor agonists useful in pharmaceutical application.
Uses
Acts as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes
Reactant for:
Synthesis of amphoteric alpha-boryl aldehydes
Enantioselective synthesis of core ring skeleton of leucosceptroids A-D
Stereoselective synthesis of monoamine reuptake inhibitor NS9544 acetate
Stereoselective sulfoxidation
Synthesis
Add methylene chloride, aniline, 4-dimethylaminopyridine (DMAP), and triethylamine to a reactor equipped with a thermometer, distillation device, and mechanical stirring. When the vacuum of the reactor is evacuated to -0.095MPa and cooled to -40°C, trifluoromethanesulfonyl fluoride gas is introduced and then stirred at -20°C ~ 0°C and 0.02MPa ~ 0.1MPa reaction pressure, and react for 6 hours Finally, the excess trifluoromethanesulfonyl fluoride gas in the reactor is released and collected by cooling. After the inside of the reactor is brought to normal pressure, 500 mL of water is added, and the liquid is separated. A light yellow solid is obtained after the organic phase is heated to 40°C and methylene chloride is distilled. The light yellow solid is recrystallized with toluene to obtain 650g of white crystal N-Phenyl-bis(trifluoromethanesulfonimide).
N-Phenyl-bis(trifluoromethanesulfonimide) Preparation Products And Raw materials
Raw materials
Preparation Products
N-Phenyl-bis(trifluoromethanesulfonimide) Suppliers
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View Lastest Price from N-Phenyl-bis(trifluoromethanesulfonimide) manufacturers
- Product
- N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 ton
- Release date
- 2024-11-18
- Product
- N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7
- Price
- US $0.00-0.00/Kg/Drum
- Min. Order
- 1KG
- Purity
- 98%min GC
- Supply Ability
- 500 KGS
- Release date
- 2021-06-10
- Product
- N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-25