Description Reference
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Geranyl acetate

Description Reference
Product Name
Geranyl acetate
CAS No.
105-87-3
Chemical Name
Geranyl acetate
Synonyms
GERANIOL ACETATE;(2E)-3,7-Dimethyl-2,6-octadienyl acetate;FEMA 2509;GERANYL ACETATE 60;ACETIC ACID GERANYL ESTER;(E)-3,7-diMethylocta-2,6-dien-1-yl acetate;3,7-DIMETHYL-TRANS-2,6-OCTADIEN-1-YL-ACETATE;Meraneine;NCI-C54728;Geranylacetat
CBNumber
CB5334054
Molecular Formula
C12H20O2
Formula Weight
196.29
MOL File
105-87-3.mol
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Geranyl acetate Property

Melting point:
25°C
Boiling point:
236-242 °C(lit.)
Density 
0.916 g/mL at 25 °C
vapor density 
6.8 (vs air)
vapor pressure 
0.07 mm Hg ( 20 °C)
refractive index 
n20/D 1.462
FEMA 
2509 | GERANYL ACETATE
Flash point:
220 °F
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form 
Liquid
color 
Colourless
Specific Gravity
0.916
Odor
at 100.00 %. floral rose lavender green waxy
Odor Type
floral
Water Solubility 
<0.1 g/100 mL at 20 ºC
JECFA Number
58
LogP
4.04 at 20℃
CAS DataBase Reference
105-87-3(CAS DataBase Reference)
NIST Chemistry Reference
2,6-Octadien-1-ol, 3,7-dimethyl-, acetate, (E)-(105-87-3)
EPA Substance Registry System
trans-Geraniol acetate (105-87-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-24/25
RIDADR 
UN1230 - class 3 - PG 2 - Methanol, solution
WGK Germany 
3
RTECS 
RG5920000
F 
10-23
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29153900
Hazardous Substances Data
105-87-3(Hazardous Substances Data)
Toxicity
The acute oral UD 50 value in rats was reported as 6.33 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W250910
Product name
Geranyl acetate
Purity
natural, FCC
Packaging
100g
Price
$79.9
Updated
2024/03/01
Sigma-Aldrich
Product number
W250910
Product name
Geranyl acetate
Purity
natural, FCC
Packaging
1kg
Price
$280
Updated
2024/03/01
Sigma-Aldrich
Product number
W250910
Product name
Geranyl acetate
Purity
natural, FCC
Packaging
5kg
Price
$967
Updated
2024/03/01
Sigma-Aldrich
Product number
W250902
Product name
Geranyl acetate
Purity
FCC
Packaging
SAMPLE-K
Price
$54.6
Updated
2024/03/01
Sigma-Aldrich
Product number
W250902
Product name
Geranyl acetate
Purity
FCC
Packaging
1kg
Price
$77.5
Updated
2024/03/01
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Geranyl acetate Chemical Properties,Usage,Production

Description

Geranyl acetate, used in numerous essential oils, is one of the most important natural fragrances. It is a colorless organic liquid with a sweet fruity or citrus top-note aroma. It can be used in soaps, creams, and in food as a fragrant and flavoring agent, in over 60 flavors including rose, lavender, carrot, lemongrass, peach, citronella, and many more. It is a major constituent of lime oil, with great economic importance. In addition, its antifungal, anti-inflammatory, and antimicrobial effects have been investigated. It has been found safe for food use by the FDA.

Reference

http://silverstripe.fkit.hr/cabeq/assets/Uploads/Cabeq-2016-01-2232.pdf
https://en.wikipedia.org/wiki/Note_(perfumery)#Top_notes
http://ayurvedicoils.com/tag/general-uses-of-geranyl-acetate
https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/geranyl-acetate
https://en.wikipedia.org/wiki/Geranyl_acetate

Description

Geranyl acetate is a monoterpene that has been found in C. sativa with diverse biological activities. It reduces compound action potential (CAP) peak amplitude in isolated frog sciatic nerves (IC50 = 0.51 mM). Geranyl acetate inhibits the radial growth of M. gypsum, T. vercossum, and C. tropicalis on solid media. It is sporicidal against B. subtilis when used at a concentration of 1% in an agar diffusion assay. Geranyl acetate inhibits growth of COLO 205 cells (IC50 = 30 μM) via induction of DNA damage, cell cycle arrest at the G2/M phase, and mitochondrial apoptosis.

Description

Geranyl acetate has a pleasant, flowery odor reminiscent of rose lavender. It has a burning taste, initially somewhat bitter and then sweet. It is produced from geraniol by acetylation or by fractional distillation of essential oils in which it is present.

Chemical Properties

Geranyl acetate has a pleasant, fowery odor reminiscent of rose lavender It has a burning taste, initially somewhat bitter and then sweet.

Chemical Properties

Geranyl Acetate occurs in varying amounts in many essential oils: up to 60% in oils from Callitris and Eucalyptus species and up to 14% in palmarosa oil. A smaller amount occurs in, for example, geranium, citronella, petitgrain, and lavender oils. Geranyl acetate is a liquid with a fruity rose note, reminiscent of pear and slightly of lavender. It is used frequently in perfumery not only to create floral, fruity nuances (e.g., rose) but also for citrus and lavender notes. A small amount is added to fruit aromas for shading.

Chemical Properties

Clear, colorless liquid; odor of lavender. Soluble in alcohol and ether; insoluble in water and glycerol. Combustible.

Occurrence

Reported found in a large number of essential oils; Ceylon citronella, palmarose, lemongrass, petitgrain, neroi bigarade, geranium, coriander, lavender, carrot, sassafras, in various Callitris species (C verrucosa, C robusta, and others) and Eucalyptus species (E acervula, E urnigera, etc ) A 60% level has been reported in the essential oil of Eucalyptus macar- thuri and up to 50% in the essential oil of Orthodon citraliferum; also identifed in bitter orange essential oil and Cymbopogon citratus oil Also reported found in citrus peel oils and juices, black currants, pineapple, celery seed, cinnamon, ginger, pepper- mint oil, corn mint oil, nutmeg, mace, thymus, hop oil, beer, rum, grape wines, coffee, tea, passion fruit, tomato, almond, muscal grape, cardamom, coriander leaf and seed, tarragon, lovage, Ocimum basilicum, laurel, myrtle leaf and berry, rosemary, clary sage and calabash nutmeg

Uses

β-Geranyl Acetate is found in essential oils such as Moroccan commercial essential oils which has anti-oxidant, anti-inflammatory and anti-proliferative activities; and in Salvia scabiosifolia from Bulgaria.

Uses

Perfumery, flavoring

Definition

ChEBI: A monoterpenoid that is the acetate ester derivative of geraniol.

Preparation

From geraniol by acetylation or by fractional distillation of essential oils in which it is present.

Aroma threshold values

Detection: 9 to 460 ppb.

Taste threshold values

Taste characteristics at 20 ppm: green, foral, fruity with a citrus nuance.

General Description

Clear colorless liquid with an odor of lavender.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Geranyl acetate should be protected from light. Geranyl acetate reacts with strong oxidizing agents.

Fire Hazard

Geranyl acetate is probably combustible.

Flammability and Explosibility

Non flammable

Safety Profile

Mildly toxic by ingestion. A human skin irritant. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

Purification Methods

Purify the fragrant smelling geranyl acetate by fractional distillation at as high a vacuum as possible. It is very soluble in EtOH but insoluble in H2O. [Beilstein 2 H 140, 2 I 65, 2 II 153, 2 III 299, 2 IV 204.]

Geranyl acetate Preparation Products And Raw materials

Raw materials

Geraniol Sodium acetate trihydrate Ylang Ylang Oil CORIANDER OIL Neroli oil LEMONGRASS OIL, WEST INDIAN TYPE

Preparation Products

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View Lastest Price from Geranyl acetate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Geranyl Acetate 105-87-3
Price
US $75.00-20.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-29
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Geranyl acetate 105-87-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000KG/month
Release date
2021-07-17
Shandong Deshang Chemical Co., Ltd.
Product
Geranyl acetate 105-87-3
Price
US $10.00-7.00/kg
Min. Order
1kg
Purity
99.99%
Supply Ability
10 tons
Release date
2024-06-19

105-87-3, Geranyl acetateRelated Search:

Dimethyl phthalate Linalyl acetate cis-2-methyl-5-(1-methylvinyl)cyclohex-2-en-1-yl acetate Benzyl acetate Triacetin Amyl acetate Dimethyl sulfoxide Dimethyl sulfate Glatiramer acetate Ethyl acetate Dimethyl disulfide Dacthal Tocopheryl acetate Dimethyl carbonate ETHANE POLY(VINYL ACETATE) Methyl acetate Neryl acetate, 97%, mixt. of ca 55-65% neryl- and 35-45% geranyl acetate,cis-Geranyl acetate

  • (2E)-3,7-Dimethyl-2,6-octadienyl acetate
  • (E)-3,7-Dimethyl-2,6-octadien-1-yl acetate
  • 2,6-dimethyl-2,6-octadiene-8-ylacetate
  • 2,6-Octadien-1-ol, 3,7-dimethyl-, acetate, trans-
  • 2,6-Octadien-1-ol,3,7-dimethyl-,acetate,(E)-
  • trans-3,7-dimethyl-2,6-octadien-1-ol,acetate
  • GERANYL ACETATE
  • GERANYL ACETATE 60
  • GERANIOL ACETATE
  • FEMA 2509
  • 3,7-DIMETHYL-TRANS-2,6-OCTADIEN-1-YL-ACETATE
  • 3,7-DIMETHYL-2,6-OCTADIEN-1-YL ACETATE
  • ACETIC ACID GERANYL ESTER
  • TRANS-3,7-DIMETHYL-2,6-OCTADIEN-1-YL ACETATE
  • TRANS-3,7-DIMETHYL-2,6-OCTADIENYL ACETATE
  • GERANYL ACETATE 60 FCC
  • 2,6-Octadien-1-ol, 3,7-dimethyl-, 1-acetate, (2E)-
  • GERANYL ACETATE FCC
  • 3,7-dimethyl-,acetate,(e)-6-octadien-1-ol
  • 3,7-dimethyl-,acetate,trans-6-octadien-1-ol
  • 3,7-Dimethyl-2-trans, 6-octadienyl acetate
  • GERANYL ACETATE WITH GC
  • GERANYL ACETATE EXTRA
  • GERANYL ACETATE PRIME
  • GERANYL ACETATE, NATURAL
  • trans-3,7-Dimethyl-2,6-octadien-1-yl acetate, trans-3,7-Dimethyl-2,6-octadienyl acetate
  • 3,7-Dimethyl-trans-2,6-octadien-1-yl-acetate, 98%, mixture of isomers
  • (E)-3,7-Dimethyl-2,6-octadienyl acetate
  • 3,7-dimethyl-,acetate,(e)-6-octadien-
  • Geranyl acetate >=97%
  • 3,7-dimethyl-2-trans,6-octadienylacetate
  • 3,7-dimethyl-2-trans-6-octadienylacetate
  • 3,7-dimethyl-trans-2,6-octadien-1-yl-acetate,mixtureofisomers
  • 6-Octadien-1-ol,3,7-dimethyl-,acetate,(E)-2
  • Acetic acid, geraniol ester
  • aceticacid,geraniolester
  • aceticacidtrans-3,7-dimethyl-oct-2,6-dien-1-ylester
  • aceticacidtrans-3,7-dimethyl-octa-2,6-dienylester
  • Bay pine (oyster) oil
  • baypine(oyster)oil
  • femanumber2509.
  • Geranyl ethanoate
  • Meraneine
  • NCI-C54728
  • trans-1-acetoxy-3,7-dimethyl-octa-2,6-diene
  • trans-2,6-Dimethyl-2,6-octadien-8-yl ethanoate
  • trans-2,6-dimethyl-2,6-octadien-8-ylethanoate
  • trans-3,7-Dimethyl-2,6-octadien-1-ol, acetate
  • GERANYL ACETATE EXTRA FCC
  • GERANYL ACETATE 90+% NATURAL FCC
  • GERANYL ACETATE 98+% FCC
  • geranylacetate,(E)-3,7-dimethyl-2,6-octadien-1-ylacetate
  • 2,6-Octadien-1-ol, 3,7-dimethyl-, acetate, (2E)-
  • Geranylacetat
  • Geranyl acetate,trans-3,7-Dimethyl-2,6-octadien-1-yl acetate, trans-3,7-Dimethyl-2,6-octadienyl acetate
  • (E)-3,7-diMethylocta-2,6-dien-1-yl acetate
  • Geranyl acetate Trans-3,7-dimethyl-2,6-octadien-1-yl ethanoate
  • Geranyl ethanonte