2'-Methoxycinnamaldehyde
Uses- Product Name
- 2'-Methoxycinnamaldehyde
- CAS No.
- 1504-74-1
- Chemical Name
- 2'-Methoxycinnamaldehyde
- Synonyms
- FEMA 3181;AKOS BBS-00003213;o-MethoxycinnamaL;3-(o-Anisyl)propenal;2-Methoxyciamaldehyde;O-Ethoxycinnamaldehyde;2′-Methoxycinnamaldehyd;2-methoxycimnamaldehyde;o-methoxy-cinnamaldehyd;2-METHOXYCINNAMALDEHYDE
- CBNumber
- CB5356650
- Molecular Formula
- C10H10O2
- Formula Weight
- 162.19
- MOL File
- 1504-74-1.mol
2'-Methoxycinnamaldehyde Property
- Melting point:
- 44-48 °C(lit.)
- Boiling point:
- 160-161 °C12 mm Hg(lit.)
- Density
- 1.0281 (rough estimate)
- refractive index
- 1.6000 (estimate)
- FEMA
- 3181 | O-METHOXYCINNAMALDEHYDE
- Flash point:
- >230 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform (Slightly), DMSO (Sparingly)
- form
- Solid
- color
- Yellow
- Odor
- at 100.00 %. sweet cinnamon cassia oily woody paper
- Odor Type
- spicy
- biological source
- synthetic
- JECFA Number
- 688
- InChIKey
- KKVZAVRSVHUSPL-GQCTYLIASA-N
- LogP
- 2.13
- CAS DataBase Reference
- 1504-74-1(CAS DataBase Reference)
- NIST Chemistry Reference
- 2-Propenal, 3-(2-methoxyphenyl)-(1504-74-1)
- EPA Substance Registry System
- o-Methoxycinnamaldehyde (1504-74-1)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- W318101
- Product name
- 2-Methoxycinnamaldehyde
- Purity
- natural, 98%, FG
- Packaging
- 1 unit
- Price
- $57.47
- Updated
- 2025/07/31
- Product number
- W318101
- Product name
- 2-Methoxycinnamaldehyde
- Purity
- natural, 98%, FG
- Packaging
- 1 unit
- Price
- $57.47
- Updated
- 2025/07/31
- Product number
- W318101
- Product name
- 2-Methoxycinnamaldehyde
- Purity
- natural, 98%, FG
- Packaging
- 100g
- Price
- $86.1
- Updated
- 2025/07/31
- Product number
- W318101
- Product name
- 2-Methoxycinnamaldehyde
- Purity
- natural, 98%, FG
- Packaging
- 1kg
- Price
- $222
- Updated
- 2025/07/31
- Product number
- W318101
- Product name
- 2-Methoxycinnamaldehyde
- Purity
- natural, 98%, FG
- Packaging
- 10Kg
- Price
- $1660
- Updated
- 2025/07/31
2'-Methoxycinnamaldehyde Chemical Properties,Usage,Production
Uses
o-Methoxycinnamaldehyde is a food flavoring permitted for use according to GB2760-1997.
Description
o-Methoxycinnamaldehyde has a sweet, warm, spicy-floral odor with fruity undertones. It has a sweet, spicy, warm flavor, somewhat pungent above 200 - 300 ppm. It is formed after a long contact period between salicylaldehyde and acetaldehyde in diluted alkaline solution; it can be formed by condensation of salicylaldehyde methylether with acetaldehyde under alkaline conditions; from the corresponding oxime.
Chemical Properties
o-Methoxycinnamaldehyde has a sweet, warm, spicy-floral odor with fruity undernotes. It has a sweet, spicy, warm flavor and is somewhat pungent above 200 to 300?ppm.
Occurrence
Reported found in cinnamon oil (Cinnamomum cassia Nees ex Bl.) from which it is separated as stearoptene; in cinnamon bark and leaf.
Preparation
It is formed after a long contact period between salicylaldehyde and acetaldehyde in diluted alkaline solution; it may also be formed by condensation of salicylaldehyde methylether with acetaldehyde under alkaline conditions; from the corresponding oxime. It may be isolated and purified from powdered cinnamon.
Definition
ChEBI: Cassiastearoptene is a member of cinnamaldehydes.
Taste threshold values
Taste characteristics at 50 ppm: warm, spicy, cinnamon and clove-like.
General Description
Yellow crystals.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Aldehydes, such as 2'-Methoxycinnamaldehyde, are frequently involved in self-condensation or polymerization reactions. These reactions are exothermic; they are often catalyzed by acid. Aldehydes are readily oxidized to give carboxylic acids. Flammable and/or toxic gases are generated by the combination of aldehydes with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. Aldehydes can react with air to give first peroxo acids, and ultimately carboxylic acids. These autoxidation reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). The addition of stabilizers (antioxidants) to shipments of aldehydes retards autoxidation.
Fire Hazard
2'-Methoxycinnamaldehyde is flammable.
Synthesis
1504-61-6
1504-74-1
The general procedure for the synthesis of 2'-methoxycinnamaldehyde from the compound (CAS:1504-61-6) is as follows: alcohol (5.0 mmol), copper acetate (Cu(OAc)2, 9.1 mg, 0.05 mmol), and TEMPO (7.8 mg, 0.05 mmol) were mixed in a mixture of acetonitrile (CH3CN, 5 mL) and water (H2O, 10 mL) in a mixed solvents at room temperature with stirring for the indicated times. The progress of the reaction was monitored by thin-layer chromatography (TLC) with the eluent ratio of petroleum ether/ethyl acetate = 4/1. After completion of the reaction, the reaction mixture was extracted by adding dichloromethane (10 mL) to the reaction mixture. The organic phase was separated and the aqueous phase was extracted twice more with dichloromethane (10 mL x 2). All organic layers were combined, dried with anhydrous sodium sulfate and concentrated to obtain the crude product. The crude product was purified by column chromatography with the eluent ratio of petroleum ether/ethyl acetate=10/1, and the target product 2'-methoxycinnamaldehyde was finally obtained.
target
P450 (e.g. CYP17)
References
[1] Tetrahedron Letters, 2014, vol. 55, # 10, p. 1677 - 1681
[2] European Journal of Organic Chemistry, 2016, vol. 2016, # 20, p. 3401 - 3407
[3] Bioorganic and Medicinal Chemistry Letters, 1997, vol. 7, # 19, p. 2473 - 2476
2'-Methoxycinnamaldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2'-Methoxycinnamaldehyde manufacturers
- Product
- 2'-Methoxycinnamaldehyde 1504-74-1
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-07
- Product
- 2-Methoxycimnamaldehyde 1504-74-1
- Price
- US $50.00/kg
- Min. Order
- 1kg
- Purity
- 99
- Supply Ability
- 5000
- Release date
- 2024-12-16
- Product
- 2′-Methoxycinnamaldehyde 1504-74-1
- Price
- US $5.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-20