Phenyl trifluoromethanesulfonate
- Product Name
- Phenyl trifluoromethanesulfonate
- CAS No.
- 17763-67-6
- Chemical Name
- Phenyl trifluoromethanesulfonate
- Synonyms
- Phenol triflate;PHENYL TRIFLATE;Phenol trifluoromethanesulfonate;PHENYL TRIFLUOROMETHANESULFONATE;Trifluoromethylsulfonyloxybenzene;Phenyl rifluoromehanesulfonae, 98%;PhenylTrifluoromethanesulfonate>Phenyl trifluoromethanesulfonate 98%;Trifluoromethanesulfonic acid phenyl ester;Methanesulfonic acid, 1,1,1-trifluoro-, phenyl ester
- CBNumber
- CB5369083
- Molecular Formula
- C7H5F3O3S
- Formula Weight
- 226.17
- MOL File
- 17763-67-6.mol
Phenyl trifluoromethanesulfonate Property
- Boiling point:
- 99-100 °C/60 mmHg (lit.)
- Density
- 1.396 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.435(lit.)
- Flash point:
- 160 °F
- storage temp.
- Inert atmosphere,Room Temperature
- form
- clear liquid
- color
- Colorless to Almost colorless
Safety
- Hazard Codes
- T
- Risk Statements
- 36/37/38-34-24/25
- Safety Statements
- 26-36-45-36/37/39
- RIDADR
- UN 2927 6.1/PG 2
- WGK Germany
- 3
- HS Code
- 29049090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 423939
- Product name
- Phenyl trifluoromethanesulfonate
- Purity
- 98%
- Packaging
- 5ml
- Price
- $178
- Updated
- 2024/03/01
- Product number
- P1829
- Product name
- Phenyl Trifluoromethanesulfonate
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $28
- Updated
- 2024/03/01
- Product number
- P1829
- Product name
- Phenyl Trifluoromethanesulfonate
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $102
- Updated
- 2024/03/01
- Product number
- P337555
- Product name
- Phenyl Trifluoromethanesulfonate
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- P337555
- Product name
- Phenyl Trifluoromethanesulfonate
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
Phenyl trifluoromethanesulfonate Chemical Properties,Usage,Production
Chemical Properties
Colorless Liquid.
Uses
Phenyl trifluoromethanesulfonate (phenyl triflate) may be used in the following studies:
As an arylating agent for the asymmetric α-arylation of ketones catalyzed by Pd(dba)2 and difluorphos.
As a reactant in the one pot synthesis of carbazoles by palladium-catalyzed N-arylation of anilines with phenyl triflate followed by oxidative coupling.
Synthesis of N-(2,6-diarylbenzoyl)anilines by diarylation of benzanilides with phenyl triflate in the presence of palladium-based catalyst.
As an arylating agent in the synthesis of (R)-2-phenyl-2,3-dihydrofuran by the arylation of 2,3-dihydrofuran.
Preparation
Synthesis of Phenyl trifluoromethanesulfonate: The reaction of phenol (1.00 g, 10.6 mmol) with triflic anhydride as outlined in the general procedure provided phenyl trifluoromethanesulfonate as colorless oil (0.73 g, 30%).
1H NMR (400 MHz, CDCl3) δ 7.50 – 7.42 (m, 2H), 7.41 – 7.36 (m, 1H), 7.32 – 7.24 (m, 2H).
General Description
Phenyl trifluoromethanesulfonate (phenyl triflate) is an aryl fluorosulphonate. It has been synthesized by the reaction of phenol with fluorosulphonic anhydride.
Phenyl trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Phenyl trifluoromethanesulfonate manufacturers
- Product
- PHENYL TRIFLUOROMETHANESULFONATE 17763-67-6
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2020-02-05