1-Bromo-2-nitrobenzene
- Product Name
- 1-Bromo-2-nitrobenzene
- CAS No.
- 577-19-5
- Chemical Name
- 1-Bromo-2-nitrobenzene
- Synonyms
- 2-BROMONITROBENZENE;O-NITROBROMOBENZENE;1-BroMo-2-;2-Nitrophenyl bromide;1-Bromo-2-Nitrobenene;Benzene,1-bromo-2-nitro-;AURORA KA-1883;2-Nitrobromobenzene;O-BROMONITROBENZENE;Sucrose Impurity 10
- CBNumber
- CB5379602
- Molecular Formula
- C6H4BrNO2
- Formula Weight
- 202.01
- MOL File
- 577-19-5.mol
1-Bromo-2-nitrobenzene Property
- Melting point:
- 40-42 °C (lit.)
- Boiling point:
- 261 °C (lit.)
- Density
- 1.7 g/cm3 (20℃)
- refractive index
- 1.6060 (estimate)
- Flash point:
- >230 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- powder to crystal
- color
- Light yellow to Amber to Dark green
- Water Solubility
- insoluble
- BRN
- 2044109
- Stability:
- Stable. Combustible. Incompatible with strong bases, strong oxidizing agents.
- CAS DataBase Reference
- 577-19-5(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzene, 1-bromo-2-nitro-(577-19-5)
- EPA Substance Registry System
- o-Bromonitrobenzene (577-19-5)
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 20/21/22-36/37/38-22
- Safety Statements
- 36/37-36/37/39-26-22
- RIDADR
- UN 3459 6.1/PG 3
- WGK Germany
- 3
- RTECS
- CY9040450
- Hazard Note
- Irritant
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29049085
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H312Harmful in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H331Toxic if inhaled
H335May cause respiratory irritation
H373May cause damage to organs through prolonged or repeated exposure
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 365424
- Product name
- 1-Bromo-2-nitrobenzene
- Purity
- 98%
- Packaging
- 25g
- Price
- $235.2
- Updated
- 2025/07/31
- Product number
- 365424
- Product name
- 1-Bromo-2-nitrobenzene
- Purity
- 98%
- Packaging
- 100g
- Price
- $526
- Updated
- 2025/07/31
- Product number
- B0622
- Product name
- 1-Bromo-2-nitrobenzene
- Purity
- >99.0%(GC)
- Packaging
- 25g
- Price
- $64
- Updated
- 2025/07/31
- Product number
- B0622
- Product name
- 1-Bromo-2-nitrobenzene
- Purity
- >99.0%(GC)
- Packaging
- 100g
- Price
- $201
- Updated
- 2025/07/31
- Product number
- B0622
- Product name
- 1-Bromo-2-nitrobenzene
- Purity
- >99.0%(GC)
- Packaging
- 500g
- Price
- $801
- Updated
- 2025/07/31
1-Bromo-2-nitrobenzene Chemical Properties,Usage,Production
Chemical Properties
white to light yellow crystal powder
Uses
1-Bromo-2-nitrobenzene is used in organic synthesis. It also can react with 2-methylamino-benzoic acid to get N-methyl-N-(2-nitro-phenyl)-anthranilic acid. And it is also used in the preparation of 4-methoxy-2?-nitrodiphenyl ether, 1-methoxy-3,5-bis-(2-nitro-phenoxy)benzene.
Uses
1-Bromo-2-nitrobenzene may be used in the preparation of:
- 4-methoxy-2′-nitrodiphenyl ether
- 1-methoxy-3,5-bis-(2-nitro-phenoxy)benzene
- 5-hydroxy-3-methoxy-2′-nitrodiphenyl ether
General Description
1-Bromo-2-nitrobenzene undergoes palladium[0]-mediated Ullmann cross-coupling reaction with a range of β-halo-enals, -enones or -esters to afford the corresponding β-aryl derivatives. Palladium[0]-mediated Ullmann cross-coupling reaction of 1-bromo-2-nitrobenzene with β-bromo-α,β-unsaturated aldehydes is reported.
Purification Methods
Crystallise it twice from pet ether, using charcoal before the first crystallisation. [Beilstein 5 III 618, 5 IV 728.]
1-Bromo-2-nitrobenzene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1-Bromo-2-nitrobenzene manufacturers
- Product
- 1-Bromo-2-nitrobenzene 577-19-5
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 10000KGS
- Release date
- 2025-05-28