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1-Bromo-2-nitrobenzene

Product Name
1-Bromo-2-nitrobenzene
CAS No.
577-19-5
Chemical Name
1-Bromo-2-nitrobenzene
Synonyms
2-BROMONITROBENZENE;O-NITROBROMOBENZENE;1-BroMo-2-;2-Nitrophenyl bromide;1-Bromo-2-Nitrobenene;Benzene,1-bromo-2-nitro-;AURORA KA-1883;2-Nitrobromobenzene;O-BROMONITROBENZENE;Sucrose Impurity 10
CBNumber
CB5379602
Molecular Formula
C6H4BrNO2
Formula Weight
202.01
MOL File
577-19-5.mol
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1-Bromo-2-nitrobenzene Property

Melting point:
40-42 °C (lit.)
Boiling point:
261 °C (lit.)
Density 
1.7 g/cm3 (20℃)
refractive index 
1.6060 (estimate)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
powder to crystal
color 
Light yellow to Amber to Dark green
Water Solubility 
insoluble
BRN 
2044109
Stability:
Stable. Combustible. Incompatible with strong bases, strong oxidizing agents.
InChI
1S/C6H4BrNO2/c7-5-3-1-2-4-6(5)8(9)10/h1-4H
InChIKey
ORPVVAKYSXQCJI-UHFFFAOYSA-N
SMILES
[O-][N+](=O)c1ccccc1Br
CAS DataBase Reference
577-19-5(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-bromo-2-nitro-(577-19-5)
EPA Substance Registry System
o-Bromonitrobenzene (577-19-5)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38-22
Safety Statements 
36/37-36/37/39-26-22
RIDADR 
UN 3459 6.1/PG 3
WGK Germany 
3
RTECS 
CY9040450
Hazard Note 
Irritant
TSCA 
TSCA listed
HazardClass 
6.1
PackingGroup 
III
HS Code 
29049085
Storage Class
11 - Combustible Solids
Hazard Classifications
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

H335May cause respiratory irritation

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
365424
Product name
1-Bromo-2-nitrobenzene
Purity
98%
Packaging
25g
Price
$235.2
Updated
2025/07/31
Sigma-Aldrich
Product number
365424
Product name
1-Bromo-2-nitrobenzene
Purity
98%
Packaging
100g
Price
$526
Updated
2025/07/31
TCI Chemical
Product number
B0622
Product name
1-Bromo-2-nitrobenzene
Purity
>99.0%(GC)
Packaging
25g
Price
$64
Updated
2025/07/31
TCI Chemical
Product number
B0622
Product name
1-Bromo-2-nitrobenzene
Purity
>99.0%(GC)
Packaging
100g
Price
$201
Updated
2025/07/31
TCI Chemical
Product number
B0622
Product name
1-Bromo-2-nitrobenzene
Purity
>99.0%(GC)
Packaging
500g
Price
$801
Updated
2025/07/31
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1-Bromo-2-nitrobenzene Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powder

Uses

1-Bromo-2-nitrobenzene is used in organic synthesis. It also can react with 2-methylamino-benzoic acid to get N-methyl-N-(2-nitro-phenyl)-anthranilic acid. And it is also used in the preparation of 4-methoxy-2?-nitrodiphenyl ether, 1-methoxy-3,5-bis-(2-nitro-phenoxy)benzene.

Uses

1-Bromo-2-nitrobenzene may be used in the preparation of:

  • 4-methoxy-2′-nitrodiphenyl ether
  • 1-methoxy-3,5-bis-(2-nitro-phenoxy)benzene
  • 5-hydroxy-3-methoxy-2′-nitrodiphenyl ether

General Description

1-Bromo-2-nitrobenzene undergoes palladium[0]-mediated Ullmann cross-coupling reaction with a range of β-halo-enals, -enones or -esters to afford the corresponding β-aryl derivatives. Palladium[0]-mediated Ullmann cross-coupling reaction of 1-bromo-2-nitrobenzene with β-bromo-α,β-unsaturated aldehydes is reported.

Purification Methods

Crystallise it twice from pet ether, using charcoal before the first crystallisation. [Beilstein 5 III 618, 5 IV 728.]

1-Bromo-2-nitrobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Bromo-2-nitrobenzene Suppliers

Shanghai Hao Yun Chemical Science Co.,Ltd.
Tel
021-68367562 15002147577;
Fax
021-68369562
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sales@haoyunchem.com
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China
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Shanghai Macklin Biochemical Co.,Ltd.
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15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
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China
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Hangzhou J&H Chemical Co., Ltd.
Tel
0571-87396432
Fax
0571-87396431
Email
sales@jhechem.com
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China
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Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
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China
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Shijiazhuang Yesheng Chemical Technology Co., Ltd
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18031147013 18031147013;
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0311-68030586
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yeshengchemical@163.com
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China
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Xi'an Kaixiang Photoelectric Technology Co., Ltd.
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15332313370 18592059708
Fax
029-87871708
Email
sales@kxmaterials.com
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China
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CD Chemical Group Limited
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+8615986615575
Fax
0086-13651442114
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info@codchem.com
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China
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Huai'an Chenhui Technology Co., Ltd.
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13056011912
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jianshen1977@126.com
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China
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Wuhan Hongde Yuexin Pharmaceutical Technology Co., Ltd
Tel
02783850058 15377551550
Fax
027-83850058
Email
whhdyxchem027@sina.com
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China
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978
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Hubei Zhonglong Kangsheng fine chemical Co.,Ltd
Tel
027-027-82752821 18186694582
Fax
027-82752821
Email
323495346@qq.com
Country
China
ProdList
990
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View Lastest Price from 1-Bromo-2-nitrobenzene manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
1-Bromo-2-nitrobenzene 577-19-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-05-28

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