Methyl 3-methyl-2-nitrobenzoate
- Product Name
- Methyl 3-methyl-2-nitrobenzoate
- CAS No.
- 5471-82-9
- Chemical Name
- Methyl 3-methyl-2-nitrobenzoate
- Synonyms
- Methyl 3-me;Methyl 3-methyl-2-ni;Methyl?3-methyl-2-nitrobenzoat;METHYL 3-METHYL-2-NITROBENZOATE;Methyl 2-Nitro-3-Methyl benzoate;Methyl3-Methyl-2-nitrobenzoate>Methyl 3-methyl-2-nitrobenzoate?New;Methyl 3-methyl-2-nitrobenzoate ,98%;3-Methyl-2-nitrobenzoate Methyl ester;3-Methyl-2-nitrobenzoicacidmethylester
- CBNumber
- CB5395165
- Molecular Formula
- C9H9NO4
- Formula Weight
- 195.17
- MOL File
- 5471-82-9.mol
Methyl 3-methyl-2-nitrobenzoate Property
- Melting point:
- 72-73°C
- Boiling point:
- 286.3±20.0 °C(Predicted)
- Density
- 1?+-.0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- soluble in Methanol
- form
- Solid
- color
- White to Almost white
- InChI
- InChI=1S/C9H9NO4/c1-6-4-3-5-7(9(11)14-2)8(6)10(12)13/h3-5H,1-2H3
- InChIKey
- NJHDBIXFFZVJGZ-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC=CC(C)=C1[N+]([O-])=O
- CAS DataBase Reference
- 5471-82-9(CAS DataBase Reference)
- EPA Substance Registry System
- Benzoic acid, 3-methyl-2-nitro-, methyl ester (5471-82-9)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- M2213
- Product name
- Methyl 3-Methyl-2-nitrobenzoate
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $32
- Updated
- 2025/07/31
- Product number
- M2213
- Product name
- Methyl 3-Methyl-2-nitrobenzoate
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $113
- Updated
- 2025/07/31
- Product number
- M339028
- Product name
- Methyl 3-Methyl-2-nitrobenzoate
- Packaging
- 5g
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 4654-1-W1
- Product name
- Methyl 3-methyl-2-nitrobenzoate
- Packaging
- 25g
- Price
- $100
- Updated
- 2021/12/16
- Product number
- CS-M3738
- Product name
- Methyl 3-Methyl-2-nitrobenzoate
- Purity
- 99.66%
- Packaging
- 500g
- Price
- $110
- Updated
- 2021/12/16
Methyl 3-methyl-2-nitrobenzoate Chemical Properties,Usage,Production
Chemical Properties
Light brown crystalline powder
Uses
Methyl 3-methyl-2-nitrobenzoate is used as a raw material for the synthesis of pesticide intermediate 2-amino-5-chloro-N,3-dimethylbenzamide, and is hydrogenated to produce 2-amino-3-methylbenzoic acid methyl ester.
Synthesis
67-56-1
5437-38-7
5471-82-9
Acetyl chloride (20 mL) was slowly added dropwise to a suspension of commercially available 3-methyl-2-nitrobenzoic acid (13.45 g, 74.25 mmol) in methanol (200 mL) at 0 °C. The reaction mixture was then heated to reflux temperature with continuous stirring for 20 hours. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure. The residue was dissolved in ethyl acetate (800 mL) and washed sequentially with saturated aqueous NaHCO3 (200 mL) and brine (150 mL). The organic phase was dried over anhydrous Na2SO4 and concentrated under reduced pressure to afford methyl 3-methyl-2-nitrobenzoate as a white solid (12.35 g, 85% yield). The product was characterized by 1H NMR (CDCl3): δ 2.36 (s, 3H), 3.89 (s, 3H), 7.40-7.51 (m, 2H), 7.84 (m, 1H).
References
[1] Tetrahedron, 2013, vol. 69, # 32, p. 6679 - 6686
[2] Tetrahedron, 2004, vol. 60, # 10, p. 2235 - 2246
[3] Patent: WO2005/66136, 2005, A1. Location in patent: Page/Page column 87-88
[4] Patent: CN106467513, 2017, A. Location in patent: Paragraph 0009; 0036; 0037; 0038; 0039
[5] Chemische Berichte, 1907, vol. 40, p. 4413
Methyl 3-methyl-2-nitrobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
Methyl 3-methyl-2-nitrobenzoate Suppliers
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View Lastest Price from Methyl 3-methyl-2-nitrobenzoate manufacturers
- Product
- Methyl 3-methyl-2-nitrobenzoate 5471-82-9
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 10000KGS
- Release date
- 2025-05-13
- Product
- Methyl 3-methyl-2-nitrobenzoate 5471-82-9
- Price
- US $36.28/Kg/Drum
- Min. Order
- 25Kg/Drum
- Purity
- 98.00%HPLC
- Supply Ability
- 9tons/month
- Release date
- 2021-09-23
- Product
- Methyl 3-methyl-2-nitrobenzoate 5471-82-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 10KG
- Release date
- 2019-08-05