Methyl 3-methyl-2-nitrobenzoate

Product Name: Methyl 3-methyl-2-nitrobenzoate
CAS No.: 5471-82-9
Chemical Name: Methyl 3-methyl-2-nitrobenzoate
Synonyms: Methyl 3-me;Methyl 3-methyl-2-ni;Methyl?3-methyl-2-nitrobenzoat;METHYL 3-METHYL-2-NITROBENZOATE;Methyl 2-Nitro-3-Methyl benzoate;Methyl3-Methyl-2-nitrobenzoate>Methyl 3-methyl-2-nitrobenzoate?New;Methyl 3-methyl-2-nitrobenzoate ,98%;3-Methyl-2-nitrobenzoate Methyl ester;3-Methyl-2-nitrobenzoicacidmethylester
CBNumber: CB5395165
Molecular Formula: C9H9NO4
Formula Weight: 195.17
MOL File: 5471-82-9.mol

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Methyl 3-methyl-2-nitrobenzoate Property

Melting point:: 72-73°C
Boiling point:: 286.3±20.0 °C(Predicted)
Density: 1?+-.0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
solubility: soluble in Methanol
form: Solid
color: White to Almost white
InChI: InChI=1S/C9H9NO4/c1-6-4-3-5-7(9(11)14-2)8(6)10(12)13/h3-5H,1-2H3
InChIKey: NJHDBIXFFZVJGZ-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=CC(C)=C1[N+]([O-])=O
CAS DataBase Reference: 5471-82-9(CAS DataBase Reference)
EPA Substance Registry System: Benzoic acid, 3-methyl-2-nitro-, methyl ester (5471-82-9)

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Safety

Hazard Codes: Xi
Safety Statements: 24/25
TSCA: Yes
HazardClass: IRRITANT
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: M2213
Product name: Methyl 3-Methyl-2-nitrobenzoate
Purity: >98.0%(GC)
Packaging: 5g
Price: $32
Updated: 2025/07/31

TCI Chemical

Product number: M2213
Product name: Methyl 3-Methyl-2-nitrobenzoate
Purity: >98.0%(GC)
Packaging: 25g
Price: $113
Updated: 2025/07/31

TRC

Product number: M339028
Product name: Methyl 3-Methyl-2-nitrobenzoate
Packaging: 5g
Price: $60
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4654-1-W1
Product name: Methyl 3-methyl-2-nitrobenzoate
Packaging: 25g
Price: $100
Updated: 2021/12/16

ChemScene

Product number: CS-M3738
Product name: Methyl 3-Methyl-2-nitrobenzoate
Purity: 99.66%
Packaging: 500g
Price: $110
Updated: 2021/12/16

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Methyl 3-methyl-2-nitrobenzoate Chemical Properties,Usage,Production

Chemical Properties

Light brown crystalline powder

Uses

Methyl 3-methyl-2-nitrobenzoate is used as a raw material for the synthesis of pesticide intermediate 2-amino-5-chloro-N,3-dimethylbenzamide, and is hydrogenated to produce 2-amino-3-methylbenzoic acid methyl ester.

Synthesis

67-56-1

5437-38-7

5471-82-9

Acetyl chloride (20 mL) was slowly added dropwise to a suspension of commercially available 3-methyl-2-nitrobenzoic acid (13.45 g, 74.25 mmol) in methanol (200 mL) at 0 °C. The reaction mixture was then heated to reflux temperature with continuous stirring for 20 hours. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure. The residue was dissolved in ethyl acetate (800 mL) and washed sequentially with saturated aqueous NaHCO3 (200 mL) and brine (150 mL). The organic phase was dried over anhydrous Na2SO4 and concentrated under reduced pressure to afford methyl 3-methyl-2-nitrobenzoate as a white solid (12.35 g, 85% yield). The product was characterized by 1H NMR (CDCl3): δ 2.36 (s, 3H), 3.89 (s, 3H), 7.40-7.51 (m, 2H), 7.84 (m, 1H).

References

[1] Tetrahedron, 2013, vol. 69, # 32, p. 6679 - 6686
[2] Tetrahedron, 2004, vol. 60, # 10, p. 2235 - 2246
[3] Patent: WO2005/66136, 2005, A1. Location in patent: Page/Page column 87-88
[4] Patent: CN106467513, 2017, A. Location in patent: Paragraph 0009; 0036; 0037; 0038; 0039
[5] Chemische Berichte, 1907, vol. 40, p. 4413

Methyl 3-methyl-2-nitrobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

1H-Indole-7-carboxylic acid

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Methyl 3-methyl-2-nitrobenzoate Suppliers

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View Lastest Price from Methyl 3-methyl-2-nitrobenzoate manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: Methyl 3-methyl-2-nitrobenzoate 5471-82-9
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 10000KGS
Release date: 2025-05-13

Asia Chem I and E (Jiangsu) Co Ltd

Product: Methyl 3-methyl-2-nitrobenzoate 5471-82-9
Price: US $36.28/Kg/Drum
Min. Order: 25Kg/Drum
Purity: 98.00%HPLC
Supply Ability: 9tons/month
Release date: 2021-09-23

Career Henan Chemical Co

Product: Methyl 3-methyl-2-nitrobenzoate 5471-82-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 10KG
Release date: 2019-08-05

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5471-82-9

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