DIPHENYLIODONIUM TRIFLUOROMETHANESULFONATE
Uses- Product Name
- DIPHENYLIODONIUM TRIFLUOROMETHANESULFONATE
- CAS No.
- 66003-76-7
- Chemical Name
- DIPHENYLIODONIUM TRIFLUOROMETHANESULFONATE
- Synonyms
- DIPHENYLIODONIUM TRIFLATE;DPIT;DIPHENYLIODONIUM TRIFLATE , ELECTRO;DIPHENYLIODONIUM TRIFLATE, 99+%, ELECTRO;Diphenyliodonium trifluoromethansulfonate;DIPHENYLIODONIUM TRIFLUOROMETHANESULFONATE;DIPHENYLIODONIUM TRIFLUOROMETHANESULPHONATE;DiphenyliodoniumTrifluoromethanesulfonate>Diphenyliodoniumtrifluoromethanesulphonate98%;Diphenyliodonium trifluoromethanesulphonate 98%
- CBNumber
- CB5395554
- Molecular Formula
- C12H10I.CF3O3S
- Formula Weight
- 430.18
- MOL File
- 66003-76-7.mol
DIPHENYLIODONIUM TRIFLUOROMETHANESULFONATE Property
- Melting point:
- 180-181 °C (lit.)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- PGMEA: ~1%
- form
- Crystalline Powder
- color
- White to slightly yellow
- Sensitive
- Light Sensitive
- BRN
- 3582403
- InChI
- InChI=1S/C12H10I.CHF3O3S/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;2-1(3,4)8(5,6)7/h1-10H;(H,5,6,7)/q+1;/p-1
- InChIKey
- SBQIJPBUMNWUKN-UHFFFAOYSA-M
- SMILES
- C1(C=CC=CC=1)[I+]C1=CC=CC=C1.C(F)(F)(F)S([O-])(=O)=O
- CAS DataBase Reference
- 66003-76-7(CAS DataBase Reference)
- EPA Substance Registry System
- Iodonium, diphenyl-, 1,1,1-trifluoromethanesulfonate (1:1) (66003-76-7)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 530972
- Product name
- Diphenyliodonium triflate
- Purity
- electronic grade, ≥99%
- Packaging
- 1g
- Price
- $132.72
- Updated
- 2025/07/31
- Product number
- D2253
- Product name
- Diphenyliodonium Trifluoromethanesulfonate
- Purity
- >98.0%(T)
- Packaging
- 1g
- Price
- $84
- Updated
- 2025/07/31
- Product number
- D2253
- Product name
- Diphenyliodonium Trifluoromethanesulfonate
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $261
- Updated
- 2025/07/31
- Product number
- D2253
- Product name
- Diphenyliodonium Trifluoromethanesulfonate
- Purity
- >98.0%(T)
- Packaging
- 25g
- Price
- $859
- Updated
- 2025/07/31
- Product number
- D494955
- Product name
- Diphenyliodonium Trifluoromethanesulfonate
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
DIPHENYLIODONIUM TRIFLUOROMETHANESULFONATE Chemical Properties,Usage,Production
Uses
Diphenyliodonium Trifluoromethanesulfonate is a useful research chemical.
Uses
Reagent for phenylation.
Uses
Cationic photoinitiator. Photoacid generator.
Synthesis
591-50-4
1493-13-6
71-43-2
66003-76-7
5.5 mmol of m-chloroperoxybenzoic acid as an oxidizing agent was added to the reaction flask along with 5.5 mmol of iodobenzene, 15 mL of dichloromethane, 5 mmol of benzene, 10 mmol of trifluoromethanesulfonic acid, and a stirrer, and a condensation tube was installed to condense the reaction from the bottom to the top at room temperature. Subsequently, the reaction flask was heated in an oil bath at 40 °C for the condensation reflux reaction. The reaction was continued under magnetic stirring for 1 hour. Upon completion of the reaction, the reaction solution was rotary dried using a rotary evaporator (40 °C water bath). To the dried product, 20 mL of ether was added and stirred at room temperature for 30 min, after which the mixture was cooled in a 0-4 °C medical refrigerator for 15 min. After removal, the mixture was withdrawn and filtered through a Büchner funnel using ether as eluent. The solid product on the filter paper was collected and dried in an oven at 100 °C for 24 h. Diaryl iodonium trifluoromethanesulfonate was finally obtained in 88% yield. During rotary drying, the control conditions were 0.1 MPa and 40 °C.
References
[1] Organic Letters, 2011, vol. 13, # 13, p. 3462 - 3465
[2] Chemistry--A European Journal, 2012, vol. 18, # 44, p. 14140 - 14149,10
[3] Organic Letters, 2015, vol. 17, # 18, p. 4554 - 4557
[4] Organic Letters, 2015, vol. 17, # 11, p. 2688 - 2691
[5] Angewandte Chemie - International Edition, 2016, vol. 55, # 31, p. 8928 - 8932
DIPHENYLIODONIUM TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from DIPHENYLIODONIUM TRIFLUOROMETHANESULFONATE manufacturers
- Product
- DIPHENYLIODONIUM TRIFLUOROMETHANESULFONATE 66003-76-7
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 98.0%min
- Supply Ability
- 100kg
- Release date
- 2023-03-20
- Product
- DIPHENYLIODONIUM TRIFLUOROMETHANESULFONATE 66003-76-7
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 200KG
- Release date
- 2020-01-08