Perfluorobutyl iodide

Product Name: Perfluorobutyl iodide
CAS No.: 423-39-2
Chemical Name: Perfluorobutyl iodide
Synonyms: NONAFLUOROBUTYL IODIDE;NONAFLUORO-1-IODOBUTANE;1,1,1,2,2,3,3,4,4-NONAFLUORO-4-IODOBUTANE;C1014NH3;uorobutyL;Perfluoroiodobutane;PERFLUOROBUTYL IODODE;PERFLUOROBUTYL IODIDE;1-Iodoperfluorobutane;1-IODONONAFLUOROBUTANE
CBNumber: CB9474482
Molecular Formula: C4F9I
Formula Weight: 345.93
MOL File: 423-39-2.mol

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Perfluorobutyl iodide Property

Melting point:: -88 °C
Boiling point:: 66-67 °C
Density: 2.01 g/mL at 25 °C(lit.)
refractive index: n20/D 1.3285(lit.)
Flash point:: None
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: Liquid
Specific Gravity: 2.010
color: Clear purple
Water Solubility: immiscible
Sensitive: Light Sensitive
BRN: 1777546
Exposure limits: ACGIH: TWA 0.01 ppm
Stability:: Stable. Incompatible with bases.
InChIKey: PGRFXXCKHGIFSV-UHFFFAOYSA-N
CAS DataBase Reference: 423-39-2(CAS DataBase Reference)
NIST Chemistry Reference: 1-Iodononafluorobutane(423-39-2)
EPA Substance Registry System: Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo- (423-39-2)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39
RIDADR: 2810
WGK Germany: 3
RTECS: EK5360000
F: 8
Hazard Note: Irritant/Light Sensitive
TSCA: T
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29034700

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 317845
Product name: Nonafluoro-1-iodobutane
Purity: 98%
Packaging: 25g
Price: $70.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: 317845
Product name: Nonafluoro-1-iodobutane
Purity: 98%
Packaging: 100g
Price: $182
Updated: 2024/03/01

TCI Chemical

Product number: N0499
Product name: Nonafluorobutyl Iodide
Purity: >98.0%(GC)
Packaging: 25g
Price: $42
Updated: 2024/03/01

TCI Chemical

Product number: N0499
Product name: Nonafluorobutyl Iodide
Purity: >98.0%(GC)
Packaging: 100g
Price: $120
Updated: 2024/03/01

Alfa Aesar

Product number: A16671
Product name: Nonafluoro-1-iodobutane, 97%
Packaging: 5g
Price: $29.65
Updated: 2024/03/01

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Perfluorobutyl iodide Chemical Properties,Usage,Production

Description

Perfluorobutyl iodide (PFBI) is a promising alternative to chlorofluorocarbon solvents used in aircraft ground maintenance operations and other military and commercial operations because it cleans well, has zero ozone depletion potential, and has extremely low global warming properties. Perfluorobutyl iodides also could used as gain media for a solar-pumped laser amplifier. This compound is usually utilized as perfluoroalkyl radical precursors[1–3].

Chemical Properties

clear colourless liquid with pungent odour

Uses

Perfluorobutyl Iodide is used as an organocatalyst in some polymerization reactions.

Synthesis

Add 10 mol of triphenylphosphine chloride and 50 mol of N-methylimidazole hydrochloride to methanol and stir to dissolve. Heat to 50°C, add 65 moles of aluminum chloride, stir and dissolve, continue the reaction for 2 hours, raise the temperature to 80°C, evaporate the solvent, and filter to remove the insoluble matter to obtain quaternary ammonium salt and N-alkyl imidazole salt composite aluminum acid. Salt ionic liquid. Add 2 kg of the aluminate ionic liquid prepared in step S1 to the reaction kettle equipped with a reflux device, then add 264 g of perfluoropentanoic acid and raise the temperature to 80°C. Slowly add 2.5 mol of iodine ethanol solution dropwise within 5 hours. After the dropwise addition is completed, heat to 100°C for 8 hours. The reaction solution was allowed to stand and separated into layers to separate the aluminate ionic liquid and product layers. The product layer was purified by distillation to obtain 336g of Perfluorobutyl iodide.

References

[1] Darol Dodd, Colin Hardy, Gary Hoffman. "Perfluoro-n-butyl iodide: acute toxicity, subchronic toxicity and genotoxicity evaluations. " International Journal of Toxicology 23 4 (2004): 249–58.
[2] J. Lee, B. Tabibi, W. Weaver. "Perfluorobutyl iodides as gain media for a solar-pumped laser amplifier." Optics Communications 67 1 (1988): 435–440.
[3] Zhang, Juan et al. "Perfluorobutyl iodide-assisted direct cyanomethylation of azoles and phenols with acetonitrile?." RSC Advances 26 (2015): 20562–20565.

Perfluorobutyl iodide Preparation Products And Raw materials

Raw materials

Preparation Products

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Perfluorobutyl iodide Suppliers

Americas 1 Australia 1 Belgium 4 China 186 Europe 1 France 1 Germany 7 India 6 Japan 6 Russia 1 Slovakia 1 Switzerland 3 The Netherlands 2 United Kingdom 12 United States 35 Global 267

Weihai Zhaochuan Biotechnology Co., Ltd.

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Shangfluoro

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Alfa Aesar

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TCI (Shanghai) Development Co., Ltd.

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Energy Chemical

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View Lastest Price from Perfluorobutyl iodide manufacturers

Hebei Chuanghai Biotechnology Co,.LTD

Product: Perfluorobutyl iodide 423-39-2
Price: US $49.60/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5000kg
Release date: 2024-08-09

Shaanxi Dideu Medichem Co. Ltd

Product: Perfluorobutyl iodide 423-39-2
Price: US $0.10/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000 tons
Release date: 2020-04-20

Henan Fengda Chemical Co., Ltd

Product: Perfluorobutyl iodide 423-39-2
Price: US $5.00-0.50/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-01-13

423-39-2, Perfluorobutyl iodideRelated Search:

Potassium iodide 2-Chloro-2-methylpropane Heptafluoroisopropyl iodide 1-Chlorobutane Trifluoromethyl iodide 2-Iodo-1,1,1-trifluoroethane 1-Bromobutane Propidium iodide 2-Bromo-2-methylpropane 1-Chloro-2-methylpropane 1H,1H,2H,2H-Perfluorohexyl iodide 1H,1H,2H-Perfluoro-1-decene Perfluoro-1-iodohexane 1H,1H,2H,2H-Perfluorooctyl acrylate 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane 1H,1H,2H,2H-Perfluorooctanesulfonic acid Perfluoroalkyl Ethylenes (Perfluorobutyl)ethylene

PERFLUOROBUTYL IODODE

Nonafluoro-1-iodobutane,1-Iodoperfluorobutane, Perfluorobutyl iodide

1-Iodoperfluorobutane, 1,1,1,2,2,3,3,4,4-Nonafluoro-4-iodobutane

1-Iodoperfluorobutane, Perfluorobutyl iodide

Perfluorobutyl iodide,99%

PERFLUOROBUTYL IODIDE (STABILISED WITH S

Nonafluoro-1-iodobutane 98%

Perfluorobutyl iodide (stabilised with silver platelets) for synthesis

C1014NH3

uorobutyL

1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo-butan

Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo-

m-Nonafluorobutyl iodide

1,1,1,2,2,3,3,4,4-NONAFLUORO-4-IODOBUTANE

1-IODONONAFLUOROBUTANE

PERFLUOROBUTYL IODIDE

PERFLUORO-N-BUTYL IODIDE

N-NONAFLUOROBUTYLIODIDE

NONAFLUOROBUTYL IODIDE

NONAFLUORO-1-IODOBUTANE

NONAFLUORO-N-BUTYL IODIDE

1,1,2,2,3,3,4,4,4-Nonafluoro-1-iodobutane

NONAFLUORO-1-IODOBUTANE, STAB.

PERFLUOROBUTYL IODIDE 95%

1-Iodoperfluorobutane

1-Iodononafluorobutane,97%

n-Nonafluorobutyliodide,98%

1-Iodononafluorobutane 98%

1-Iodononafluorobutane98%

Nonafluorobutyl Iodide &gt

Nonafluoro-1-iodobutane, 99%, for synthesis

Perfluoroiodobutane

423-39-2

CF3CF23I

C4F9I

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