ChemicalBook > CAS DataBase List > Perfluorobutyl iodide

Perfluorobutyl iodide

Product Name
Perfluorobutyl iodide
CAS No.
423-39-2
Chemical Name
Perfluorobutyl iodide
Synonyms
NONAFLUOROBUTYL IODIDE;NONAFLUORO-1-IODOBUTANE;1,1,1,2,2,3,3,4,4-NONAFLUORO-4-IODOBUTANE;C1014NH3;uorobutyL;Perfluoroiodobutane;PERFLUOROBUTYL IODODE;PERFLUOROBUTYL IODIDE;1-Iodoperfluorobutane;1-IODONONAFLUOROBUTANE
CBNumber
CB9474482
Molecular Formula
C4F9I
Formula Weight
345.93
MOL File
423-39-2.mol
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Perfluorobutyl iodide Property

Melting point:
-88 °C
Boiling point:
66-67 °C
Density 
2.01 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.3285(lit.)
Flash point:
None
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
Liquid
Specific Gravity
2.010
color 
Clear purple
Water Solubility 
immiscible
Sensitive 
Light Sensitive
BRN 
1777546
Exposure limits
ACGIH: TWA 0.01 ppm
Stability:
Stable. Incompatible with bases.
InChIKey
PGRFXXCKHGIFSV-UHFFFAOYSA-N
CAS DataBase Reference
423-39-2(CAS DataBase Reference)
NIST Chemistry Reference
1-Iodononafluorobutane(423-39-2)
EPA Substance Registry System
Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo- (423-39-2)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
RIDADR 
2810
WGK Germany 
3
RTECS 
EK5360000
F 
8
Hazard Note 
Irritant/Light Sensitive
TSCA 
T
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29034700
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
317845
Product name
Nonafluoro-1-iodobutane
Purity
98%
Packaging
25g
Price
$70.9
Updated
2024/03/01
Sigma-Aldrich
Product number
317845
Product name
Nonafluoro-1-iodobutane
Purity
98%
Packaging
100g
Price
$182
Updated
2024/03/01
TCI Chemical
Product number
N0499
Product name
Nonafluorobutyl Iodide
Purity
>98.0%(GC)
Packaging
25g
Price
$42
Updated
2024/03/01
TCI Chemical
Product number
N0499
Product name
Nonafluorobutyl Iodide
Purity
>98.0%(GC)
Packaging
100g
Price
$120
Updated
2024/03/01
Alfa Aesar
Product number
A16671
Product name
Nonafluoro-1-iodobutane, 97%
Packaging
5g
Price
$29.65
Updated
2024/03/01
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Perfluorobutyl iodide Chemical Properties,Usage,Production

Description

Perfluorobutyl iodide (PFBI) is a promising alternative to chlorofluorocarbon solvents used in aircraft ground maintenance operations and other military and commercial operations because it cleans well, has zero ozone depletion potential, and has extremely low global warming properties. Perfluorobutyl iodides also could used as gain media for a solar-pumped laser amplifier. This compound is usually utilized as perfluoroalkyl radical precursors[1–3].

Chemical Properties

clear colourless liquid with pungent odour

Uses

Perfluorobutyl Iodide is used as an organocatalyst in some polymerization reactions.

Synthesis

Add 10 mol of triphenylphosphine chloride and 50 mol of N-methylimidazole hydrochloride to methanol and stir to dissolve. Heat to 50°C, add 65 moles of aluminum chloride, stir and dissolve, continue the reaction for 2 hours, raise the temperature to 80°C, evaporate the solvent, and filter to remove the insoluble matter to obtain quaternary ammonium salt and N-alkyl imidazole salt composite aluminum acid. Salt ionic liquid. Add 2 kg of the aluminate ionic liquid prepared in step S1 to the reaction kettle equipped with a reflux device, then add 264 g of perfluoropentanoic acid and raise the temperature to 80°C. Slowly add 2.5 mol of iodine ethanol solution dropwise within 5 hours. After the dropwise addition is completed, heat to 100°C for 8 hours. The reaction solution was allowed to stand and separated into layers to separate the aluminate ionic liquid and product layers. The product layer was purified by distillation to obtain 336g of Perfluorobutyl iodide.

References

[1] Darol Dodd, Colin Hardy, Gary Hoffman. "Perfluoro-n-butyl iodide: acute toxicity, subchronic toxicity and genotoxicity evaluations. " International Journal of Toxicology 23 4 (2004): 249–58.
[2] J. Lee, B. Tabibi, W. Weaver. "Perfluorobutyl iodides as gain media for a solar-pumped laser amplifier." Optics Communications 67 1 (1988): 435–440.
[3] Zhang, Juan et al. "Perfluorobutyl iodide-assisted direct cyanomethylation of azoles and phenols with acetonitrile?." RSC Advances 26 (2015): 20562–20565.

Perfluorobutyl iodide Preparation Products And Raw materials

Raw materials

Preparation Products

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Perfluorobutyl iodide Suppliers

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View Lastest Price from Perfluorobutyl iodide manufacturers

Henan Fengda Chemical Co., Ltd
Product
Perfluorobutyl iodide 423-39-2
Price
US $5.00-0.50/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-13
Wuhan Silworld Chemical Co.,Ltd
Product
Perfluorobutyl iodide 423-39-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000
Release date
2023-04-28
Hebei Guanlang Biotechnology Co,.LTD
Product
Perfluorobutyl iodide 423-39-2
Price
US $49.60/KG
Min. Order
1KG
Purity
99%
Supply Ability
5000kg
Release date
2021-07-13

423-39-2, Perfluorobutyl iodideRelated Search:

Potassium iodide 2-Chloro-2-methylpropane Heptafluoroisopropyl iodide 1-Chlorobutane Trifluoromethyl iodide 2-Iodo-1,1,1-trifluoroethane 1-Bromobutane Propidium iodide 2-Bromo-2-methylpropane 1-Chloro-2-methylpropane 1H,1H,2H,2H-Perfluorohexyl iodide 1H,1H,2H-Perfluoro-1-decene Perfluoro-1-iodohexane 1H,1H,2H,2H-Perfluorooctyl acrylate 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane 1H,1H,2H,2H-Perfluorooctanesulfonic acid Perfluoroalkyl Ethylenes (Perfluorobutyl)ethylene

  • PERFLUOROBUTYL IODODE
  • Nonafluoro-1-iodobutane,1-Iodoperfluorobutane, Perfluorobutyl iodide
  • 1-Iodoperfluorobutane, 1,1,1,2,2,3,3,4,4-Nonafluoro-4-iodobutane
  • 1-Iodoperfluorobutane, Perfluorobutyl iodide
  • Perfluorobutyl iodide,99%
  • PERFLUOROBUTYL IODIDE (STABILISED WITH S
  • Nonafluoro-1-iodobutane 98%
  • Perfluorobutyl iodide (stabilised with silver platelets) for synthesis
  • C1014NH3
  • uorobutyL
  • 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo-butan
  • Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo-
  • m-Nonafluorobutyl iodide
  • 1,1,1,2,2,3,3,4,4-NONAFLUORO-4-IODOBUTANE
  • 1-IODONONAFLUOROBUTANE
  • PERFLUOROBUTYL IODIDE
  • PERFLUORO-N-BUTYL IODIDE
  • N-NONAFLUOROBUTYLIODIDE
  • NONAFLUOROBUTYL IODIDE
  • NONAFLUORO-1-IODOBUTANE
  • NONAFLUORO-N-BUTYL IODIDE
  • 1,1,2,2,3,3,4,4,4-Nonafluoro-1-iodobutane
  • NONAFLUORO-1-IODOBUTANE, STAB.
  • PERFLUOROBUTYL IODIDE 95%
  • 1-Iodoperfluorobutane
  • 1-Iodononafluorobutane,97%
  • n-Nonafluorobutyliodide,98%
  • 1-Iodononafluorobutane 98%
  • 1-Iodononafluorobutane98%
  • Nonafluorobutyl Iodide &gt
  • Nonafluoro-1-iodobutane, 99%, for synthesis
  • Perfluoroiodobutane
  • 423-39-2
  • CF3CF23I
  • C4F9I
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