Description Reference
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Ammonium hexafluorophosphate

Description Reference
Product Name
Ammonium hexafluorophosphate
CAS No.
16941-11-0
Chemical Name
Ammonium hexafluorophosphate
Synonyms
AMMONIUM HEXAFLUOROPHOSPHATE: 99.5%;Ammonium hexafluorop;Six fluoride phosphate;Ammonium fluorophosphate;AMMONIUM HEXAFLUOPHOSPHATE;Azanium hexafluorophosphate;Ammonium hexafluorophosphat;AMMONIUM HEXAFLUOROPHOSPHATE;Ammoniumhexafluorophosphate99.;hexafluoro-phosphate(1-ammonium
CBNumber
CB5414082
Molecular Formula
F6P.H4N
Formula Weight
163
MOL File
16941-11-0.mol
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Ammonium hexafluorophosphate Property

Melting point:
58 °C (lit.)
Density 
2.18 g/mL at 25 °C (lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
H2O: 50 mg/mL, clear, colorless
form 
Crystalline Powder or Needles
Specific Gravity
2.180
color 
White to beige
Water Solubility 
74.8 g/100 mL (20 ºC)
Sensitive 
Hygroscopic
Merck 
14,526
Stability:
Stable. Incompatible with strong acids. Hygroscopic. Combustion may generate hydrogen fluoride, phosphorus oxides, phosphine or ammonia.
InChIKey
NIZXKAYXSNUDOU-UHFFFAOYSA-O
CAS DataBase Reference
16941-11-0(CAS DataBase Reference)
EPA Substance Registry System
Phosphate(1-), hexafluoro-, ammonium (16941-11-0)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
F 
3
Hazard Note 
Corrosive/Hygroscopic
TSCA 
T
HazardClass 
8
PackingGroup 
III
HS Code 
28269090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
201138
Product name
Ammonium hexafluorophosphate
Purity
≥95%
Packaging
25g
Price
$73
Updated
2024/03/01
Sigma-Aldrich
Product number
201138
Product name
Ammonium hexafluorophosphate
Purity
≥95%
Packaging
100g
Price
$212
Updated
2024/03/01
Alfa Aesar
Product number
011495
Product name
Ammonium hexafluorophosphate
Purity
99.5%
Packaging
25g
Price
$64.2
Updated
2024/03/01
Alfa Aesar
Product number
011495
Product name
Ammonium hexafluorophosphate
Purity
99.5%
Packaging
100g
Price
$190
Updated
2023/06/20
Strem Chemicals
Product number
93-1502
Product name
Ammonium hexafluorophosphate, 99%
Packaging
25g
Price
$54
Updated
2024/03/01
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Ammonium hexafluorophosphate Chemical Properties,Usage,Production

Description

Ammonium hexafluorophophate can be used to for the synthesis of non-aqueous polymer gel electrolytes based on polyethylene oxide (PEO), which show high conductivity above 10-2 S/cm at 25°C.1 It can be used to prepare other hexafluorophosphate.2 It is also used for the synthesis of ruthenium and palladium complexes.3

Reference

  • J. P. Sharma, S. S. Sekhon, Highly conductive non aqueous polymer gel electrolytes containing ammonium hexafluorophosphate (NH4PF6), Journal of Materials Science, 2006, vol. 41, pp. 3617-3622
  • C. Hiort, P. Lincoln, B. Norden, DAN binding of .DELTA.and .LAMBDA.-[Ru(phen)2DPPZ]2+, Journal of the American Chemical Society, 1993, vol. 115, pp. 3448-3454
  • D. Schmollinger, J. Kraft, C. Ewald, T. Ziegler, Synthesis of ruthenium and palladium complexes from glycosylated 2,2′-bipyridine and terpyridine ligands, 2017, vol. 58, pp. 3643-3645

Chemical Properties

off-white powder

Uses

Ammonium hexafluorophosphate is used as a preservative. It is used as a starting material in the preparation of other hexafluorophosphates. Further, it is used in synthesis of organometalic compounds, especially rhodicinium hexafluorophosphate, which has inert and non-coordinating counter ion.

Uses

Ammonium hexafluorophosphate is used to synthesize polyethylene oxide based highly conductive non aqueous polymer gel electrolytes exhibiting high conductivity (>10-2S/cm at 25oC)

Uses

Ammonium hexafluorophosphate (NH4PF6) can be used as a precursor for the preparation of:

  • Metal complexes, particularly iridium and rhodium complexes.???????
  • Flame retardant cellulose-based materials.???????
  • Cyclic amidinium and iminium ammonium hexafluorophosphate salts.????????
  • The polymer-supported iridium isomerization catalyst for the selective trans isomerization of aryl allylic derivatives.

General Description

Ammonium hexafluorophosphate decomposes on heating before melting. Solubility of ammonium hexafluorophosphate in H2O at 20oC is 74.8% w/v. Additionally, it is very soluble in Me2CO, MeOH, EtOH and MeOAc, and is decomposed by boiling mineral acids.

Purification Methods

It crystallises from H2O in square plates and decomposes on heating before melting. Its solublility in H2O at 20o is 74.8% w/v, and it is very soluble in Me2CO, MeOH, EtOH and MeOAc but is decomposed by boiling mineral acids. [Lange & Müller Chem Ber 63 1063 1930, Kwasnik in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 195 1963.]

Ammonium hexafluorophosphate Preparation Products And Raw materials

Raw materials

Preparation Products

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Ammonium hexafluorophosphate Suppliers

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View Lastest Price from Ammonium hexafluorophosphate manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Ammonium hexafluorophosphate 16941-11-0
Price
US $50.00-30.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 tons
Release date
2024-01-26
Hebei Chuanghai Biotechnology Co,.LTD
Product
Ammonium hexafluorophosphate 16941-11-0
Price
US $100.00-50.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-20
Zhuozhou Wenxi import and Export Co., Ltd
Product
Ammonium hexafluorophosphate 16941-11-0
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11

16941-11-0, Ammonium hexafluorophosphateRelated Search:

Ammonium sulfate TRI-AMMONIUM ORTHOPHOSPHATE Molybdic acid Ammonium carbonate Ammonium acetate Ammonium chloride Silver hexafluorophosphate Hexafluorophosphoric acid Lithium hexafluorophosphate Sodium hexafluorophosphate Ammonium hydroxide Ammonium formate Potassium hexafluorophosphate Hexamethylphosphoramide N-(2-Chloro-6-methylphenyl)-2-[(6-chloro-2-methyl-4-pyrimidinyl)amino]-5-thiazolecarboxamide Hexafluorobisphenol A Sodium hexafluoroantimonate Silver hexafluoroantimonate

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  • F6PH4N
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