Description
ChemicalBook > CAS DataBase List > Procymidone

Procymidone

Description
Product Name
Procymidone
CAS No.
32809-16-8
Chemical Name
Procymidone
Synonyms
ISO;BSI;PROCYMIDON;s7131;Sialex;PROMIX;Kenolex;SUMILEX;Procilex;sp751011
CBNumber
CB5447264
Molecular Formula
C13H11Cl2NO2
Formula Weight
284.14
MOL File
32809-16-8.mol
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Procymidone Property

Melting point:
166-167°C
Boiling point:
477.9±35.0 °C(Predicted)
Density 
d25 1.42-1.46
vapor pressure 
1.8 x 10-2 Pa (25 °C)
refractive index 
1.6100 (estimate)
Flash point:
>100 °C
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
pka
-2.67±0.60(Predicted)
Water Solubility 
4.5 mg l-1 (25 °C)
color 
Off-White to Pale Beige
BRN 
1539058
InChIKey
QXJKBPAVAHBARF-UHFFFAOYSA-N
CAS DataBase Reference
32809-16-8(CAS DataBase Reference)
NIST Chemistry Reference
3-Azabicyclo[3.1.0]hexane-2,4-dione, 3-(3,5-dichlorophenyl)-1,5-dimethyl-(32809-16-8)
EPA Substance Registry System
Procymidone (32809-16-8)
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Safety

WGK Germany 
2
RTECS 
GZ2150000
HS Code 
29251900
Toxicity
LD50 in male rats (mg/kg): 6800 orally, >10000 dermally (Jackson); LD50 in male, female rats (g/kg): 7.8, 9.1 orally (Mikami)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H332Harmful if inhaled

H360May damage fertility or the unborn child

H370Causes damage to organs

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P307+P311IF exposed: call a POISON CENTER or doctor/physician.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P314Get medical advice/attention if you feel unwell.

P321Specific treatment (see … on this label).

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
36640
Product name
Procymidone
Purity
PESTANAL?, analytical standard
Packaging
250mg
Price
$73
Updated
2024/03/01
Sigma-Aldrich
Product number
75120
Product name
Procymidone
Purity
certified reference material, TraceCERT
Packaging
50mg
Price
$225
Updated
2022/05/15
TRC
Product number
P755855
Product name
Procymidox
Packaging
50mg
Price
$75
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
PRO0004930
Product name
BANDEIREA SIMPLICIFOLIA AGGLUTININ
Purity
95.00%
Packaging
5MG
Price
$503.71
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
PST0000368
Product name
PROCYMIDONE
Purity
98.00%
Packaging
100MG
Price
$704.55
Updated
2021/12/16
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Procymidone Chemical Properties,Usage,Production

Description

Procymidone is a moderately systemic fungicide. It is used in horticulature as a seed-dressing, pre-harvest spray or post-harvest dip for the control of various fungal diseases, such as grey mold, neck rot, brown rot, blossom blight, and twig wilt. It is applied to vegetables including onions, fruits (including peaches, plums, grapes, stone fruit, strawberries, and cherries), and ornamentals.

Uses

Systemic agricultural fungicide.

Uses

Procymidone is a systemic fungcide with both protective and curative activities used to control plant diseases such as fruit rots, grey mould on top fruits, vines and vegetables, and Sclerotinia rot of kidney beans and vegetable crops.

Definition

ChEBI: An azabicycloalkane that is 1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione in which the amino hydrogen is replaced by a 3,5-dichlorophenyl group. A fungicide widely used in horticulture as a seed dressing, pre-harvest spray or post-harvest dip for the co trol of various diseases.

Metabolic pathway

The fungicides, chlozolinate, vinclozolin, and procymidone, are added to wine after fermentation and the degradation products are isolated and identified. Chlozolinate undergoes a rapid hydrolytic loss of the ethoxycarbonyl substituent to give an oxazolidine that further undergoes hydrolytic cleavage to give 3' ,5' -dichloro-2-hydroxypropanilide. The oxazolidine ring of vinclozolin undergoes a similar hydrolysis reaction to give the corresponding anilide, 3' ,5'-dichloro-2-hydroxy-2-methylbut-3-eneanilide. Both of these anilides are stable in wine for 150 days. A different degradation behavior is observed with procymidone and leads to the formation of 3,5- dichloroaniline, which, in turn, breaks down in wine.

Degradation

Procymidone (1) was stable in acidic conditions (pH 2) but hydrolysed rapidly in buffer solutions (pH 6 to 10) and in natural river and sea water at 15, 30 and 45 °C with DTm values from 30 min to 8 days. Degradation occurred mainly via cleavage of the cyclic imide linkage in alkaline conditions and via cleavage of the subsequent amide linkage in acidic conditions (Mikami and Miyamoto, 1981) to yield the intermediate acid [2-( 3,5-dichlorophenylcarbamoyl)- 1,2 -dimet hylcyclopropanecarboxylic acid (2) and 1,2-dimethylcyclopropane-1,2-dicarboxylica cid (3) and 3,5- dichloroaniline (4) as terminal products (Villedieu et al., 1994,1995). Pirisi et al. (1986) and Cabras et al. (1984) reported the formation of compound 4 and other polar decomposition products in wine during the fermentation process.
Photodegradation of procymidone was investigated in various solutions after exposure to sunlight. Major degradation pathways were cleavage of the cyclic imide and the subsequent cleavage of the amide linkage to yield compounds 3 and 4 (Mikami and Miyamoto, 1981).

Procymidone Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Procymidone manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
Procymidone 32809-16-8
Price
US $100.00-75.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000Ton
Release date
2024-08-13
qingdao trust agri chemical co.,ltd
Product
Procymidone 32809-16-8
Price
US $0.00/kg
Min. Order
1kg
Purity
99
Supply Ability
20tons
Release date
2024-07-25
Shaanxi Dideu Medichem Co. Ltd
Product
Procymidone 32809-16-8
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2024-08-01

32809-16-8, ProcymidoneRelated Search:


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