2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL

Uses Reactions

Product Name: 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL
CAS No.: 564483-19-8
Chemical Name: 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL
Synonyms: tBuXPhos;t-Bu XPhos;t-butyl-Xphos;tBuXPhos 97%;2‘98% tBuXPhos;di-t-Bu-XPhos;2-Di-tert-butyL;TERT-BUTYL X-PHOS;2-Di-t-butylphosphino-2',4',6'
CBNumber: CB5451245
Molecular Formula: C29H45P
Formula Weight: 424.64
MOL File: 564483-19-8.mol

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2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL Property

Melting point:: 148-151 °C(lit.)
Boiling point:: 493.5±45.0 °C(Predicted)
solubility: soluble in Toluene
form: Crystalline Powder
color: White
InChI: InChI=1S/C29H45P/c1-19(2)22-17-24(20(3)4)27(25(18-22)21(5)6)23-15-13-14-16-26(23)30(28(7,8)9)29(10,11)12/h13-21H,1-12H3
InChIKey: SACNIGZYDTUHKB-UHFFFAOYSA-N
SMILES: P(C(C)(C)C)(C(C)(C)C)C1=CC=CC=C1C1=C(C(C)C)C=C(C(C)C)C=C1C(C)C

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3
TSCA: No
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 901904
Product name: tBuXPhos
Purity: 95%
Packaging: 1G
Price: $61.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 638080
Product name: tBuXPhos
Purity: 97%
Packaging: 1g
Price: $57.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 901904
Product name: tBuXPhos
Purity: 95%
Packaging: 5G
Price: $142.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 638080
Product name: tBuXPhos
Purity: 97%
Packaging: 5g
Price: $184
Updated: 2024/03/01

Sigma-Aldrich

Product number: 901904
Product name: tBuXPhos
Purity: 95%
Packaging: 25G
Price: $420
Updated: 2024/03/01

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2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL Chemical Properties,Usage,Production

Uses

tBuXPhos [2-Di-tert-butylphosphino-2′,4′,6′-triisopropylbiphenyl] is an air-stable, electron-rich biaryl phosphine ligand developed by the Buchwald group to enhance the reactivity of palladium catalysis during cross-coupling reactions. tBuXPhos has been used in the preparation of [tBuXPhosAu(MeCN)]BAr4F, a gold catalyst for the intermolecular [2+2] cycloaddition of terminal arylalkynes with substituted alkenes to form functionalized cyclobutenes with high regioselectivity.
tBuXPhos is a ligand for Pd-catalyzed C-O and C-N bond formation.
It can be used in the following reactions:
• Palladium-catalyzed Tsuji-Trost substitution and cross-coupling of benzylic fluorides.
• Palladium-catalyzed C-N cross-coupling of sulfinamides and aryl halides.
• Palladium-catalyzed rapid methoxylation and deuteriomethoxylation of bromo-chalcones.

Reactions

Effective ligand for the Pd-catalyzed arylation of pyrazoles, indazoles and amino heterocycles.
Ligand used in the Pd-catalyzed synthesis of phenols from aryl halides and KOH.
Ligand used in the Pd-catalyzed of benzoic acids from aryl halides and CO2.
Ligand used in the Pd-catalyzed trifluoromethylation of vinyl sulfonates.
Ligand used in the Pd-catalyzed arylation of nitroacetates.
Ligand used in the Pd-catalyzed Suzuki−Miyaura cross-coupling of allylboronates and aryl halides.
Ligand used in the Pd-catalyzed cyanation of (hetero)arylchlorides and bromides.
Ligand used in the Pd-catalyzed C–N cross coupling of sulfinamides and aryl halides.
Ligand used in the Pd-catalyzed arylation of cyanamides.

Chemical Properties

White to pale yellow

Uses

Effective ligand for the Pd-catalyzed arylation of pyrazoles, indazoles and amino heterocycles

Uses

tBuXPhos is a ligand for Pd-catalyzed C-O and C-N bond formation.
It can be used in the following reactions:

Palladium-catalyzed Tsuji-Trost substitution and cross-coupling of benzylic fluorides.
Palladium-catalyzed C-N cross-coupling of sulfinamides and aryl halides.
Palladium-catalyzed rapid methoxylation and deuteriomethoxylation of bromo-chalcones.

Uses

suzuki reaction

General Description

tBuXPhos [2-Di-tert-butylphosphino-2′,4′,6′-triisopropylbiphenyl] is an air-stable, electron-rich biaryl phosphine ligand developed by the Buchwald group to enhance the reactivity of palladium catalysis during cross-coupling reactions.

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL Preparation Products And Raw materials

Raw materials

2-Bromopropane 2-Chloro-2-methylpropane Carbon tetrachloride Aluminum chloride Phosphorus trichloride 1,2-Dibromoethane Tetrahydrofuran 1,2-Dibromobenzene Benzene Ethyl acetate Copper(I) chloride Government regulation Dichloromethane Iron Magnesium

Preparation Products

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2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL Suppliers

Americas 1 Canada 1 CHINA 271 Europe 1 Germany 4 India 5 Italy 1 Japan 1 Norway 1 Russia 1 Switzerland 1 Ukraine 1 United Kingdom 4 United States 17 Global 310

DALCHEM

Tel: --
Fax: --
Email: info@dalchem.nnov.ru
Country: Russia
ProdList: 705
Advantage: 64

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View Lastest Price from 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL manufacturers

Speranza Chemical Co., Ltd.

Product: 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL 564483-19-8
Price: US $0.00-0.00/KG
Min. Order: 25KG
Purity: 98%
Supply Ability: 25KG
Release date: 2024-01-05

XINXIANG RUNYU MATERIAL CO., LTD.

Product: 2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl 564483-19-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 0.99
Supply Ability: 500kg
Release date: 2021-11-29

Shanghai UCHEM Inc.

Product: 2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl 564483-19-8
Price: US $11.20-184.00/g
Min. Order: 1g
Purity: 0.98
Supply Ability: 20kg
Release date: 2023-10-25

564483-19-8, 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYLRelated Search:

2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL 2-(Dicyclohexylphosphino)-2'-methylbiphenyl 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl 2-(Dicyclohexylphosphino)biphenyl 2'-(dicyclohexylphosphino)-6-methoxy-N,N-dimethylbiphenyl-2-amine 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl 2-(Dicyclohexylphosphino)-2'-methoxybiphenyl 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos X-PHOS 2-Dicyclohexylphosphino-2',6'-bis(diMethylaMino)-1,1'-biphenyl, Min. 98% Cphos Tri-tert-butylphosphine tetrafluoroborate 2-(Di-tert-butylphosphino)biphenyl 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL 2-(DI-T-BUTYLPHOSPHINO)-2'-METHYLBIPHENYL DI-TERT-BUTYLPHENYLPHOSPHINE 2-DI-TERT-BUTYLPHOSPHINO-3,4,5,6-TETRAM&

2-DI-T-BUTYLPHOSPHINO-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL

2-Di-tert-butylphosphino-2',4',6'-trisopropylbinphenyl

tBuXPhos 97%

2-Di-tert-butyL

phosphino-2',4',6'-triisopropyL

phosphine, bis(1,1-diMethylethyl)[2',4',6'-tris(1-Methylethyl)[1,1'-biphenyl]-2-yl]-

t-Bu XPhos

tBuXPhos

Bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL

TERT-BUTYL X-PHOS

2-DI-TERT-BUTYLPHOSPHINO-2',4', 6'-TRI-I-PROPYL-1,1'-BIPHENYL

2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl,min.98%

2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl,min.98%t-butylXPhos

2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl ,98%

2-Di-tert-butylphosphino-2′,4′,6′-triisopropylbiphenyl,tert-Butyl XPhos

2-DI-T-BUTYLPHOSPHINO-2'',4'',6''-TRI-I-PROPYL-1,1''-BIPHENYL, MIN. 98%

t-butyl-Xphos

2-di-tert-butylphosphino-2',4',6'-triisopropylbiph

98% tBuXPhos

Di-tert-butyl(2',4',6'-triisopropyl-[1,1'-biphenyl]-2-yl)phosphine

di-t-Bu-XPhos

Di-tert-butyl(2',4',6'-triisopropylbiphenyl-2-yl)phosphine

2-Di-t-butylphosphiNA-2',4',6'-tri-i-propyl-1,1'-biphenyl

2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl, t-butylXPhos

2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 98% t-Bu-X-PHOS

2-Di-t-butylphosphino-2',4',6'

2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl,98% tBuXPhos

2&lsquo

-DI-Tert-Butylphosphino-2,4,6-Triisopropylbiphenyl

phosphine, bis(1,1-diMethylethyl)[2',4',6'-tris(1-Methylethyl)[1,1'-biphenyl]

phosphine, bis(1,1-diMethylethyl)[2',4',6'-tris(1-Methylethyl)[1,1'-biphen

2-(Di-t-butylphosphino)-2',4',6'-tri- i-propyl-1,1'-biphenyl (tBu-Xphos)

Di-tert-butyl(2',4',6'-triisopropyl-[1,1'-biphenyl]-2-yl)phosphine 98%

tBuXPhos / 2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl

2-Di-t-butylphosphino-2',4',6'-tri-isopropyl-1,1'-biphenyl

2-Di-t-butylphosphino-2',4',6'-tri-i-propylbiphenyl

2-Di-tert-butyphosphino-2',4',6'-trisopropyl-1,1'-biphenyl

phosphine, bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethy...

564483-19-8 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL

di-tert-butyl(2',4',6'-triisopropyl-[1,1'-biphenyl]-2-yl)phosphane

2-Di-t-butylphosphino-2’,4’,6’-triisopropyl-1,1’-biphenyl (tBuXPhos)

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL

Di-tert-butyl(2',4',6'-triisopropyl-[1,1'-biphenyl]-2-yl)phosphine

Bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine

2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl

di-tert-butyl(2',4',6'-triisopropyl-[1,1'-biphenyl]-2-yl)phosphane

2-Di-tert-butylphosphino-2',4',6'-trisopropylbinphenyl

2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl, tBuXPhos

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIP

564483-19-8

C29H45P

Achiral Phosphine

Aryl Phosphine

Buchwald Ligands Series

Buchwald Ligands&Precatalysts