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Dichloro(1,5-cyclooctadiene)palladium(II)

Product Name
Dichloro(1,5-cyclooctadiene)palladium(II)
CAS No.
12107-56-1
Chemical Name
Dichloro(1,5-cyclooctadiene)palladium(II)
Synonyms
PdCl2(cod);1,5-CYCLOOCTADIENEPALLADIUM(II) DICHLORIDE;adium(Ⅱ);NSC 169973;ooctadiene)paL;Dichloro(1,5-cyclooctadience;DICHLORO(CYCLOOCTA-1,5-DIENE)PAL;Dichloro-(1,5-cyclooctadiene)-palladium;Dichloro(1,5-cyclooctadiene)palladium(Ⅱ);(1,5-CYCLOOCTADIENE)PALLADIUM(II)CHLORIDE
CBNumber
CB5488849
Molecular Formula
C8H12Cl2Pd
Formula Weight
285.51
MOL File
12107-56-1.mol
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Dichloro(1,5-cyclooctadiene)palladium(II) Property

Melting point:
210 °C (dec.) (lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble in dichloromethane
form 
crystal
color 
yellow
Water Solubility 
insoluble
Sensitive 
Hygroscopic
InChI
InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
InChIKey
NEKYMUKEOUDFPP-XRGHXPOKSA-L
SMILES
C1CC=CCCC=C1.[Pd](Cl)Cl |c:2,6|
CAS DataBase Reference
12107-56-1(CAS DataBase Reference)
EPA Substance Registry System
Palladium, dichloro[(1,2,5,6-.eta.)-1,5-cyclooctadiene]- (12107-56-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
TSCA 
Yes
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
275891
Product name
Dichloro(1,5-cyclooctadiene)palladium(II)
Purity
99%
Packaging
2g
Price
$251
Updated
2024/03/01
TCI Chemical
Product number
D2604
Product name
Dichloro(1,5-cyclooctadiene)palladium(II)
Purity
>98.0%(T)
Packaging
1g
Price
$336
Updated
2024/03/01
TCI Chemical
Product number
D2604
Product name
Dichloro(1,5-cyclooctadiene)palladium(II)
Purity
>98.0%(T)
Packaging
5g
Price
$1226
Updated
2024/03/01
Alfa Aesar
Product number
010493
Product name
Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7%
Packaging
1g
Price
$133
Updated
2023/06/20
Alfa Aesar
Product number
010493
Product name
Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7%
Packaging
5g
Price
$628
Updated
2023/06/20
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Dichloro(1,5-cyclooctadiene)palladium(II) Chemical Properties,Usage,Production

Chemical Properties

yellow

Uses

Dichloro(1,5-cyclooctadiene)palladium(II) is used as catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes, Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate and methoxycarbonylation of iodobenzene.

Uses

Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation. It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes; the synthesis of benzo[b]thiophenes from thioenols and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.

Dichloro(1,5-cyclooctadiene)palladium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Dichloro(1,5-cyclooctadiene)palladium(II) Suppliers

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View Lastest Price from Dichloro(1,5-cyclooctadiene)palladium(II) manufacturers

henan kanbei chemical co.,ltd
Product
Dichloro(1,5-cyclooctadiene)palladium(II) 12107-56-1
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-23
Career Henan Chemical Co
Product
Dichloro(1,5-cyclooctadiene)palladium(II) 12107-56-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2019-07-02

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  • 12107-56-1
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