ChemicalBook > CAS DataBase List > 1,3,5-Tris(4-bromophenyl)benzene

1,3,5-Tris(4-bromophenyl)benzene

Product Name
1,3,5-Tris(4-bromophenyl)benzene
CAS No.
7511-49-1
Chemical Name
1,3,5-Tris(4-bromophenyl)benzene
Synonyms
Nsc30660;1,3,5-tri(4-bromophenyl)benzene;1,3,5-Tris(4-broMophenyl)benzen;1,3,5-Tris(4-bromophenyl)benzene;1,3,5-Tris(4-bromophenyc)-benzene;1,3,5-Tris(4'-bromophenyl)benzene;1,3,5-tri(4-broMobenzeneyl)benzene;4,4''-dibroMo-5'-(4-broMophenyl)-1,1':3',1''-terphenyl;1,1':3',1''-Terphenyl, 4,4''-dibromo-5'-(4-bromophenyl)-
CBNumber
CB5498862
Molecular Formula
C24H15Br3
Formula Weight
543.09
MOL File
7511-49-1.mol
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1,3,5-Tris(4-bromophenyl)benzene Property

Melting point:
261-265 °C
Boiling point:
574.9±45.0 °C(Predicted)
Density 
1.626±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
Crystalline Powder
color 
Yellow to pale brown
λmax
288nm(CHCl3)(lit.)
InChI
InChI=1S/C24H15Br3/c25-22-7-1-16(2-8-22)19-13-20(17-3-9-23(26)10-4-17)15-21(14-19)18-5-11-24(27)12-6-18/h1-15H
InChIKey
HJQRITCAXSBOPC-UHFFFAOYSA-N
SMILES
C1(C2=CC(C3=CC=C(Br)C=C3)=CC(C3=CC=C(Br)C=C3)=C2)=CC=C(Br)C=C1
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Safety

Hazard Codes 
Xi
Risk Statements 
41
Safety Statements 
26
WGK Germany 
3
HS Code 
29039990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H318Causes serious eye damage

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
648906
Product name
1,3,5-Tris(4-bromophenyl)benzene
Purity
97%
Packaging
5g
Price
$243
Updated
2025/07/31
Sigma-Aldrich
Product number
648906
Product name
1,3,5-Tris(4-bromophenyl)benzene
Purity
97%
Packaging
1g
Price
$70
Updated
2023/06/20
TCI Chemical
Product number
T2644
Product name
1,3,5-Tris(4-bromophenyl)benzene
Purity
>98.0%(HPLC)
Packaging
1g
Price
$51
Updated
2025/07/31
TCI Chemical
Product number
T2644
Product name
1,3,5-Tris(4-bromophenyl)benzene
Purity
>98.0%(HPLC)
Packaging
5g
Price
$173
Updated
2025/07/31
TRC
Product number
T895748
Product name
1,3,5-tris(4-Bromophenyl)benzene
Packaging
500mg
Price
$90
Updated
2021/12/16
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1,3,5-Tris(4-bromophenyl)benzene Chemical Properties,Usage,Production

Chemical Properties

White to tan solid

Uses

TBB can be used to synthesize porous aromatic frameworks for the development of adsorption membranes to treat organic pollutants. It can also be used in the fabrication of pyridine based high efficiency organic light emitting diodes(OLEDs).

General Description

1,3,5-Tris(4-bromophenyl)benzene (TBB) is a halogenated aromatic monomer that can be used in the formation of covalent aromatic frameworks(COF).

Synthesis

99-90-1

7511-49-1

General method: p-Bromoacetophenone (3 mmol) was mixed with sulfated tungstate (20 wt%) in a round-bottomed flask fitted with a condenser tube and the reaction was carried out with stirring at 130°C. The reaction was monitored by thin film chromatography (TLC). The reaction progress was monitored by thin layer chromatography (TLC). After complete consumption of p-bromoacetophenone, the reaction was continued for 2 hours. After the reaction mixture was cooled, it was diluted with 30 mL of ethyl acetate and filtered to recover the catalyst. The filtrate was sequentially washed with 10 mL of water, dried over anhydrous sodium sulfate and subsequently concentrated under reduced pressure. The residue was purified by column chromatography on silica gel (60-120 mesh) using petroleum ether: ethyl acetate (9:1, v/v) as eluent to give pure 1,3,5-tris(4-bromophenyl)benzene.

References

[1] Synthetic Communications, 2013, vol. 43, # 16, p. 2178 - 2190
[2] RSC Advances, 2015, vol. 5, # 27, p. 21206 - 21214
[3] Journal of the Iranian Chemical Society, 2012, vol. 9, # 5, p. 791 - 798
[4] European Journal of Organic Chemistry, 2014, vol. 2014, # 14, p. 2907 - 2916
[5] Synthetic Communications, 2005, vol. 35, # 24, p. 3167 - 3171

1,3,5-Tris(4-bromophenyl)benzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1,3,5-Tris(4-bromophenyl)benzene Suppliers

Tikslioji sinteze (finesynthesis)
Tel
--
Fax
--
Email
ardan@micro.lt
Country
Lithuania
ProdList
206
Advantage
30
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View Lastest Price from 1,3,5-Tris(4-bromophenyl)benzene manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
1,3,5-Tris(4-bromophenyl)benzene 7511-49-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-27
Shanghai UCHEM Inc.
Product
1,3,5-Tris(4-bromophenyl)benzene 7511-49-1
Price
US $7.00-97.00/g
Min. Order
1g
Purity
0.98
Supply Ability
25kg
Release date
2024-10-25
Shaanxi Dideu Medichem Co. Ltd
Product
1,3,5-Tris(4-bromophenyl)benzene 7511-49-1
Price
US $0.10/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000 tons
Release date
2024-08-15

7511-49-1, 1,3,5-Tris(4-bromophenyl)benzeneRelated Search:


  • 1,3,5-Tris(4-bromophenyl)benzene
  • Nsc30660
  • 4,4''-dibroMo-5'-(4-broMophenyl)-1,1':3',1''-terphenyl
  • 1,3,5-tri(4-broMobenzeneyl)benzene
  • 1,3,5-Tris(4-broMophenyl)benzen
  • 1,3,5-tri(4-bromophenyl)benzene
  • 1,3,5-Tris(4-bromophenyc)-benzene
  • 1,1':3',1''-Terphenyl, 4,4''-dibromo-5'-(4-bromophenyl)-
  • 1,3,5-Tris(4'-bromophenyl)benzene
  • 7511-49-1
  • Organic Electronics and Photonics
  • Synthetic Intermediates
  • Synthetic Tools and Reagents