ChemicalBook > CAS DataBase List > 2,2'-Bipyridine-3,3'-dicarboxylic acid

2,2'-Bipyridine-3,3'-dicarboxylic acid

Product Name
2,2'-Bipyridine-3,3'-dicarboxylic acid
CAS No.
4433-01-6
Chemical Name
2,2'-Bipyridine-3,3'-dicarboxylic acid
Synonyms
2,2'-Binicotinic Acid;2'-Bipyridyl-3,3'-dicarboxylic acid;2,2Bipyridyl-3,3'-dicarboxylic acid;2,2'-Bipyridine-3,3'-dicarboxylicAci;2,2'-Bipyridine-3,3'-dicarboxylic acid;2, 2'-Bipyridyl-3, 3'-dicarboxylic acid;3,3'-bis(hydroxycarbonyl)-2,2'-bipyridine;2-(3-carboxypyridin-2-yl)pyridine-3-carboxylic acid;Butanoic acid, 4-amino-4-(2,6-dioxocyclohexylidene)-;2,2′-Bipyridine-3,3′-dicarboxylic acid, CAS 4433-01-6
CBNumber
CB5499344
Molecular Formula
C12H8N2O4
Formula Weight
244.2
MOL File
4433-01-6.mol
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2,2'-Bipyridine-3,3'-dicarboxylic acid Property

Melting point:
261°C(dec.)(lit.)
Boiling point:
454.1±40.0 °C(Predicted)
Density 
1.469±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
powder to crystal
pka
1.40±0.36(Predicted)
color 
White to Almost white
InChI
1S/C12H8N2O4/c15-11(16)7-3-1-5-13-9(7)10-8(12(17)18)4-2-6-14-10/h1-6H,(H,15,16)(H,17,18)
InChIKey
KNVZVRWMLMPTTJ-UHFFFAOYSA-N
SMILES
OC(=O)c1cccnc1-c2ncccc2C(O)=O
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29333990
Storage Class
11 - Combustible Solids
Hazard Classifications
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
457191
Product name
2,2′-Bipyridine-3,3′dicarboxylic acid
Purity
97%
Packaging
1g
Price
$190
Updated
2023/06/20
TCI Chemical
Product number
B3622
Product name
2,2'-Bipyridine-3,3'-dicarboxylic Acid
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$96
Updated
2025/07/31
TRC
Product number
B399318
Product name
2,2′-Bipyridine-3,3′dicarboxylic acid
Packaging
100mg
Price
$60
Updated
2021/12/16
TRC
Product number
B399318
Product name
2,2′-Bipyridine-3,3′dicarboxylic acid
Packaging
50mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
6102AB
Product name
2,2′-Bipyridine-3,3′dicarboxylic acid
Packaging
5g
Price
$47
Updated
2021/12/16
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2,2'-Bipyridine-3,3'-dicarboxylic acid Chemical Properties,Usage,Production

Definition

ChEBI: 2-(3-carboxy-2-pyridinyl)-3-pyridinecarboxylic acid is a member of bipyridines.

Synthesis

2942-59-8

4433-01-6

Example 4: 9.50 g of 2-chloronicotinic acid and 5.30 g of sodium hydroxide were dissolved in a solvent mixture of 40 mL of water and 40 mL of methanol. After the addition of 4 g of palladium/activated carbon catalyst with 5% palladium loading, the reaction mixture was stirred at 80-85°C and 0.1 MPa for 30 hours. Upon completion of the reaction, the catalyst was removed by filtration. Subsequently, the filtrate was acidified to pH 1 with hydrochloric acid to precipitate the target product 2,2'-bipyridine-3,3'-dicarboxylic acid as a white solid. A final 3.5 g of product was obtained in 48% yield.

References

[1] Patent: US6500956, 2002, B1

2,2'-Bipyridine-3,3'-dicarboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2'-Bipyridine-3,3'-dicarboxylic acid Suppliers

Americas 1 China 117 Europe 1 Germany 1 India 3 Japan 1 Switzerland 2 United Kingdom 4 United States 8 Global 138
J & K SCIENTIFIC LTD.
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View Lastest Price from 2,2'-Bipyridine-3,3'-dicarboxylic acid manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
2,2'-Bipyridine-3,3'-dicarboxylic acid 4433-01-6
Price
US $0.00/g/Bag
Min. Order
1g
Purity
98%min
Supply Ability
10kg
Release date
2021-12-06
Henan Aochuang Chemical Co.,Ltd.
Product
2,2'-Bipyridine-3,3'-dicarboxylic acid 4433-01-6
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-19
Shanghai UCHEM Inc.
Product
2,2'-Bipyridyl-3,3'-dicarboxylic acid 4433-01-6
Price
US $13.00-132.00/g
Min. Order
1g
Purity
0.98
Supply Ability
25kg
Release date
2024-04-12

4433-01-6, 2,2'-Bipyridine-3,3'-dicarboxylic acidRelated Search:

2,2'-Bipyridine OXALIC ACID 4,4'-Bipyridine 2,6-Lutidine Ethyl 2-(Chlorosulfonyl)acetate Quinolinic acid DIPIPERIDINOMETHANE 2,5-PYRIDINEDICARBOXYLIC ACID Folic acid Pyridine-2,6-dicarboxylic acid Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Citric acid Ascoric Acid 2,2'-Bipyridine-4,4'-dicarboxylic acid dimethyl ester 2,2'-BIPYRIDINE-4,4'-DICARBOXYLIC ACID,98 %,2,2'-BIPYRIDINE-4,4'-DICARBOXYLIC ACID, TECH., 90%,2,2'-BIPYRIDINE-4,4'-DICARBOXYLIC ACID 2,2''-BIPYRIDINE-5,5''-DICARBOXYLIC ACID 97% N719 [2,2':6',2''-TERPYRIDINE]-3',4'-DICARBOXYLIC ACID

  • Butanoic acid, 4-amino-4-(2,6-dioxocyclohexylidene)-
  • 2,2'-Bipyridine-3,3'-dicarboxylic acid
  • 2,2Bipyridyl-3,3'-dicarboxylic acid
  • 2,2'-Binicotinic Acid
  • 3,3'-bis(hydroxycarbonyl)-2,2'-bipyridine
  • 2'-Bipyridyl-3,3'-dicarboxylic acid
  • 2,2'-Bipyridine-3,3'-dicarboxylicAci
  • 2,2'-Bipyridine-3,3'-dicarboxylic acid ISO 9001：2015 REACH
  • 2-(3-carboxypyridin-2-yl)pyridine-3-carboxylic acid
  • 2, 2'-Bipyridyl-3, 3'-dicarboxylic acid
  • 2,2′-Bipyridine-3,3′-dicarboxylic acid, CAS 4433-01-6
  • 4433-01-6
  • 925167
  • 4433-10-6
  • 433-01-6
  • Heterocyclic Compounds
  • C9 to C46
  • Heterocyclic Building Blocks
  • Pyridines