ChemicalBook > CAS DataBase List > 6-(Z-AMINO)-1-HEXANOL

6-(Z-AMINO)-1-HEXANOL

Product Name: 6-(Z-AMINO)-1-HEXANOL
CAS No.: 17996-12-2
Chemical Name: 6-(Z-AMINO)-1-HEXANOL
Synonyms: Z-ACP(6)-OL;Z-NH-(CH2)6-OH;Carbamic acid, (6-hy;6-(2-Amino)-1-hexanol;6-(Z-AMINO)-1-HEXANOL;CBZ-6-AMINO-HEXAN-1-OL;Benzyl (6-hydroxyhexyl);6-(Cbz-amino)-1-hexanol;N-CBZ-6-AMINO-HEXAN-1-OL;N-Cbz-6-hydroxyhexylamine
CBNumber: CB5752618
Molecular Formula: C14H21NO3
Formula Weight: 251.32
MOL File: 17996-12-2.mol

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6-(Z-AMINO)-1-HEXANOL Property

Melting point:: 80-82 °C
Boiling point:: 419.6±38.0 °C(Predicted)
Density: 1.087±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 12.71±0.46(Predicted)
form: powder
Appearance: White to off-white Solid
BRN: 2121987
InChI: InChI=1S/C14H21NO3/c16-11-7-2-1-6-10-15-14(17)18-12-13-8-4-3-5-9-13/h3-5,8-9,16H,1-2,6-7,10-12H2,(H,15,17)
InChIKey: JMOQYRXPJQMWRQ-UHFFFAOYSA-N
SMILES: C(OCC1=CC=CC=C1)(=O)NCCCCCCO

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Safety

Safety Statements: 22-24/25
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 95895
Product name: 6-(Z-Amino)-1-hexanol
Purity: ≥98.0%
Packaging: 1g
Price: $130
Updated: 2023/06/20

TCI Chemical

Product number: B6075
Product name: 6-(N-Benzyloxycarbonylamino)-1-hexanol
Packaging: 1G
Price: $67
Updated: 2025/07/31

TCI Chemical

Product number: B6075
Product name: 6-(N-Benzyloxycarbonylamino)-1-hexanol
Packaging: 5G
Price: $213
Updated: 2025/07/31

Biosynth Carbosynth

Product number: FC45807
Product name: Cbz-6-aminohexan-1-ol
Packaging: 25g
Price: $325
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC45807
Product name: Cbz-6-aminohexan-1-ol
Packaging: 2g
Price: $80
Updated: 2021/12/16

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6-(Z-AMINO)-1-HEXANOL Chemical Properties,Usage,Production

reaction suitability

reagent type: cross-linking reagent

Synthesis

4048-33-3

501-53-1

17996-12-2

General procedure: 6-amino-1-hexanol (5.0 g, 42.7 mmol) was dissolved in a solvent mixture of tetrahydrofuran (50 mL) and water (15 mL), and benzyl chloroformate (7.3 mL, 51.2 mmol) was added slowly and dropwise at 0°C. The pH of the reaction solution was adjusted to 8-9 by adding 1N sodium hydroxide solution (12 mL). Under the condition of maintaining the temperature of the reaction system at 0 °C, 1N sodium hydroxide solution (12 mL) was slowly added to adjust the pH of the reaction solution to 8-9, a process that took about 30 min. Subsequently, the reaction mixture was continued to be stirred at room temperature for 30 minutes. Upon completion of the reaction, the reaction was extracted with ether (30 mL x 3), the organic phases were combined, dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting crude product was recrystallized by solvent recrystallization of a mixture of dichloromethane and hexane to afford N-Cbz-6-amino-1-hexanol as a white crystalline solid (3.85 g, 90% yield). The structure of the product was confirmed by 1H NMR and 13C NMR: 1H NMR (400 MHz, CDCl3): δ7.34 (m, 5H, Ar-H), 5.07 (s, 2H, PhCH2), 4.73 (br, 1H, NH), 3.61 (t, J=6.4Hz, 2H, CH2O), 3.16 (dt, J=6.8,6.8 Hz, 2H, NCH2), 1.61-1.32 (m, 8H, CH2); 13C NMR (100 MHz, CDCl3): δ 156.4 (C=O), 136.6,128.5,128.1 (Ar-C), 66.6 (PhCH2), 62.7 (CH2OH), 40.9 (NHCH2), 32.5 ( CH2CH2OH), 29.9 (NHCH2CH2), 26.3 (CH2CH2CH2OH), 25.3 (NCH2CH2CH2).

References

[1] Organic and Biomolecular Chemistry, 2016, vol. 14, # 41, p. 9716 - 9719
[2] Canadian Journal of Chemistry, 1988, vol. 66, p. 1651 - 1655
[3] Chemistry - An Asian Journal, 2011, vol. 6, # 7, p. 1800 - 1810
[4] Bioorganic and Medicinal Chemistry, 2013, vol. 21, # 4, p. 912 - 921
[5] Organic and Biomolecular Chemistry, 2018, vol. 16, # 8, p. 1343 - 1350

6-(Z-AMINO)-1-HEXANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 6-(Z-AMINO)-1-HEXANOL manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 6-(Z-AMINO)-1-HEXANOL 17996-12-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-07-07

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Benzyl (6-Hydroxyhexyl)carbamate 17996-12-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-21

Hebei Chuanghai Biotechnology Co., Ltd

Product: 6-(Z-AMINO)-1-HEXANOL 17996-12-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-29

17996-12-2, 6-(Z-AMINO)-1-HEXANOLRelated Search:

H-LYS(Z)-OME HCL N6-Cbz-L-Lysine Z-Lys(Z)-OH H-LYS(Z)-OBZL HCL N-Boc-N'-(2-chlorobenzyloxycarbonyl)-L-lysine N-Boc-N'-Cbz-L-lysine N,N'-Dibenzyloxycarbonyl-D-lysine N-Benzyloxycarbonyl-6-aminohexanoic acid 6-Amino-1-hexanol Z-LYS(Z)-ONP H-D-LYS(Z)-OH H-D-LYS(Z)-OBZL HCL NEPSILON-CARBOBENZOXY-NALPHA-TOSYL-L-LYSINE Z-LYS(Z)-OSU BOC-LYS(Z)-OSU H-Lys(Z)-OtBu.HCl BOC-D-LYS(Z)-OH Z-D-VAL-LYS(Z)-OH

6-(Z-AMINO)-1-HEXANOL

CBZ-6-AMINO-HEXAN-1-OL

BENZYL N-(6-HYDROXYHEXYL)CARBAMATE

Z-NH-(CH2)6-OH

Z-ACP(6)-OL

N-CARBOBENZOXY-6-AMINO-1-HEXANOL

N-CARBOBENZOXY-DELTA-AMINOHEXYL ALCOHOL

Carbamic acid, (6-hydroxyhexyl)-, phenylmethyl ester

N-CBZ-6-AMINO-HEXAN-1-OL

6-(2-Amino)-1-hexanol

Carbamic acid, (6-hy

Benzyl (6-hydroxyhexyl)carbamate

N-Cbz-6-hydroxyhexylamine

Benzyl (6-hydroxyhexyl)

Carbamic acid, N-(6-hydroxyhexyl)-, phenylmethyl ester

6-(N-Benzyloxycarbonylamino)-1-hexanol

6-(Carbobenzoxyamino)-1-hexanol

6-(Cbz-amino)-1-hexanol

N-benzyloxycarbonyl-6-amino-1-hexanol

17996-12-2

C6H5CH2O2CNHCH25OH

Oxygen Compounds

Organic Building Blocks

Building Blocks

Amino Alcohols

Other