2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE

Product Name: 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
CAS No.: 39085-59-1
Chemical Name: 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
Synonyms: TPSH;TRISYLHYDRAZIDE;TPSH, Trisylhydrazide;TRIISOPROPYLBENZENE SULFONYLHYDRAZIDE;2,4,6-TRIISOPROPYLBENZENESULFONOHYDRAZINE;2,4,6-triisopropylbenzenesulphonohydrazide;2,4,6-TRIISOPROPYLBENZENESULFONO-HYDRAZIDE;2,4,6-Triisopropylphenylsulfonyl hydrazine;2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE;2,4,6-Triisopropyl benzenesulphonohydrazine
CBNumber: CB5753387
Molecular Formula: C15H26N2O2S
Formula Weight: 298.44
MOL File: 39085-59-1.mol

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2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Property

Melting point:: 110-112 °C (dec.) (lit.)
Boiling point:: 396.6±52.0 °C(Predicted)
Density: 1.075
storage temp.: -20°C
solubility: Chloroform (Slightly), Methanol (Slightly)
pka: 9.51±0.10(Predicted)
form: Solid
color: Off-White
Sensitive: Moisture Sensitive
BRN: 2145001
InChIKey: GBQCDUBJTLROBV-UHFFFAOYSA-N
CAS DataBase Reference: 39085-59-1(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Safety Statements: 22-24/25
RIDADR: UN 1325 4.1/PG III
WGK Germany: 3
F: 4.8-10
HazardClass: 4.1
PackingGroup: III
HS Code: 29350090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 192198
Product name: 2,4,6-Triisopropylbenzenesulfonyl hydrazide
Purity: 90%
Packaging: 1g
Price: $58.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 192198
Product name: 2,4,6-Triisopropylbenzenesulfonyl hydrazide
Purity: 90%
Packaging: 5g
Price: $206
Updated: 2024/03/01

TCI Chemical

Product number: T1591
Product name: 2,4,6-Triisopropylbenzenesulfonyl Hydrazide
Purity: >95.0%(T)
Packaging: 5g
Price: $154
Updated: 2024/03/01

TCI Chemical

Product number: T1591
Product name: 2,4,6-Triisopropylbenzenesulfonyl Hydrazide
Purity: >95.0%(T)
Packaging: 25g
Price: $495
Updated: 2024/03/01

Alfa Aesar

Product number: 017976
Product name: 2,4,6-Triisopropylbenzenesulfonyl hydrazide
Packaging: 0.5g
Price: $40.65
Updated: 2024/03/01

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2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Chemical Properties,Usage,Production

Chemical Properties

White crystal

Uses

As a reagent for generation of diimide

Uses

2,4,6-Triisopropylbenzenesulfonyl hydrazide (TPSH) is a best source of diazene. It can be used as a selective reducing agent for the reduction of alkenes and other double bonds via in situ formation of diazene (diimide) in the presence of base. TPSH reduction method is efficiently used in the synthesis of polymers and natural products as it tolerates sensitive groups such as esters, ketones, or organometal complexes. It also undergoes condensation reaction with ketones and aldehydes to produce corresponding hydrazones that can be converted into reactive intermediates such as diazoalkanes, carbenes, carbenium ions, and alkyllithiums.
It can be used as a reagent to synthesize:

Nitrogen-containing polycyclic compounds by intramolecular cyclopropanation of N-alkyl indoles/pyrroles.
Vinyl sulfones by sulfonylation reaction of vinyl bromides.
Nitrile derivatives from carbonyl compounds via formation of corresponding hydrazones.

2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Suppliers

China 107 France 1 Germany 2 India 2 Japan 1 Switzerland 1 The Netherlands 1 United Kingdom 8 United States 15 Global 138

Suzhou Highfine Biotech Co., Ltd

Tel: 0512-68311833 13962195826
Fax: 0512-68417696
Email: wuhao@highfine.com
Country: China
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J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
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Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
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Energy Chemical

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Shanghai Longsheng chemical Co.,Ltd.

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Nanjing Chemlin Chemical Co., Ltd

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Email: info@chemlin.com.cn
Country: China
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Shanghai Hanhong Scientific Co.,Ltd.

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Country: China
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Beijing Isomersyn Technology CO;LTD

Tel: 010-82954736 13391601435
Email: sales@isomersyn.com
Country: China
ProdList: 3295
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View Lastest Price from 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE manufacturers

Career Henan Chemical Co

Product: 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE 39085-59-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: Customized
Release date: 2019-07-02

39085-59-1, 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDERelated Search:

2,4,6-Trimethylbenzenesulfonyl hydrazide 4-Ethylbenzenesulfonamide 2,4-Dimethylbenzenethiol 1,3,5-Triisopropylbenzene 2,4,6-TRIISOPROPYLBENZENESULFONAMIDE METHANESULFONYL HYDRAZIDE 2,6-DIMETHYLTHIOPHENOL Benzenesulfonyl hydrazide 4-Methylbenzenesulfonhydrazide 1,3,5-TRIETHYLBENZENE 2,4,6-TRIMETHYLTHIOPHENOL 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE (4-Isopropyl)thiophenol 2-Methylbenzene-1-sulfonamide antioxidant 1024 Benzenesulfonamide, 4-(1-methylethyl)- (9CI) TRIFLUOROACETYLTRIPHENYLSILANE 2,4,6-TRIISOPROPYLBENZENESULFONYLHYDRAZONE Benzenesulfonamide, 2,4,6-trimethyl- (9CI)

TRISYLHYDRAZIDE

TPSH

TRIISOPROPYLBENZENE SULFONYLHYDRAZIDE

2,4,6-triisopropylbenzenesulphonohydrazide

2,4,6-Triisopropyl benzenesulphonohydrazine

2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE

2,4,6-TRIISOPROPYL BENZENESULFONYL HYDRAZINE

2,4,6-TRIISOPROPYLBENZENESULFONO-HYDRAZIDE

2,4,6-TRIISOPROPYLBENZENESULFONOHYDRAZINE

2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE 96+%

TPSH, Trisylhydrazide

2,4,6-Triisopropylbenzene-1-sulfonic acid hydrazide

2,4,6-Triisopropylbenzenesulfonic acid hydrazide

2,4,6-Tris(1-methylethyl)benzenesulfonic acid hydrazide

2,4,6-Tris(isopropyl)benzenesulphonohydrazide 95%

2,4,6-Tris(prop-2-yl)benzenesulphonohydrazide, TPSH

2,4,6-Triisopropylphenylsulfonyl hydrazine

2,4,6-Triisopropylbenzenesulphonohydrazide 95%

2,4,6-Triisopropylbenzenesulfonyl hydrazide 90%

2,4,6-Triisopropylbenzenesulfonyl hydrazide≥ 95%(Titration)

2,4,6-tri(propan-2-yl)benzenesulfonohydrazide

Benzenesulfonic acid, 2,4,6-tris(1-methylethyl)-, hydrazide

39085-59-1

CH32CH3C6H2SO2NHNH2

C15H26N2O2S

Building Blocks

Organic Building Blocks

Sulfonyl Hydrazides

Sulfur Compounds

Building Blocks

Chemical Synthesis

Organic Building Blocks

Sulfonyl Hydrazides

Sulfur Compounds