ChemicalBook > CAS DataBase List > 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE

2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE

Product Name
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
CAS No.
39085-59-1
Chemical Name
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
Synonyms
TPSH;TRISYLHYDRAZIDE;TPSH, Trisylhydrazide;TRIISOPROPYLBENZENE SULFONYLHYDRAZIDE;2,4,6-TRIISOPROPYLBENZENESULFONOHYDRAZINE;2,4,6-triisopropylbenzenesulphonohydrazide;2,4,6-TRIISOPROPYLBENZENESULFONO-HYDRAZIDE;2,4,6-Triisopropylphenylsulfonyl hydrazine;2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE;2,4,6-Triisopropyl benzenesulphonohydrazine
CBNumber
CB5753387
Molecular Formula
C15H26N2O2S
Formula Weight
298.44
MOL File
39085-59-1.mol
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2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Property

Melting point:
110-112 °C (dec.) (lit.)
Boiling point:
396.6±52.0 °C(Predicted)
Density 
1.075
storage temp. 
-20°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
9.51±0.10(Predicted)
form 
Solid
color 
Off-White
Sensitive 
Moisture Sensitive
BRN 
2145001
InChIKey
GBQCDUBJTLROBV-UHFFFAOYSA-N
CAS DataBase Reference
39085-59-1(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Safety Statements 
22-24/25
RIDADR 
UN 1325 4.1/PG III
WGK Germany 
3
F 
4.8-10
HazardClass 
4.1
PackingGroup 
III
HS Code 
29350090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
192198
Product name
2,4,6-Triisopropylbenzenesulfonyl hydrazide
Purity
90%
Packaging
1g
Price
$58.4
Updated
2024/03/01
Sigma-Aldrich
Product number
192198
Product name
2,4,6-Triisopropylbenzenesulfonyl hydrazide
Purity
90%
Packaging
5g
Price
$206
Updated
2024/03/01
TCI Chemical
Product number
T1591
Product name
2,4,6-Triisopropylbenzenesulfonyl Hydrazide
Purity
>95.0%(T)
Packaging
5g
Price
$154
Updated
2024/03/01
TCI Chemical
Product number
T1591
Product name
2,4,6-Triisopropylbenzenesulfonyl Hydrazide
Purity
>95.0%(T)
Packaging
25g
Price
$495
Updated
2024/03/01
Alfa Aesar
Product number
017976
Product name
2,4,6-Triisopropylbenzenesulfonyl hydrazide
Packaging
0.5g
Price
$40.65
Updated
2024/03/01
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2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Chemical Properties,Usage,Production

Chemical Properties

White crystal

Uses

As a reagent for generation of diimide

Uses

2,4,6-Triisopropylbenzenesulfonyl hydrazide (TPSH) is a best source of diazene. It can be used as a selective reducing agent for the reduction of alkenes and other double bonds via in situ formation of diazene (diimide) in the presence of base. TPSH reduction method is efficiently used in the synthesis of polymers and natural products as it tolerates sensitive groups such as esters, ketones, or organometal complexes. It also undergoes condensation reaction with ketones and aldehydes to produce corresponding hydrazones that can be converted into reactive intermediates such as diazoalkanes, carbenes, carbenium ions, and alkyllithiums.
It can be used as a reagent to synthesize:

  • Nitrogen-containing polycyclic compounds by intramolecular cyclopropanation of N-alkyl indoles/pyrroles.
  • Vinyl sulfones by sulfonylation reaction of vinyl bromides.
  • Nitrile derivatives from carbonyl compounds via formation of corresponding hydrazones.

2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Suppliers

China 107 France 1 Germany 2 India 2 Japan 1 Switzerland 1 The Netherlands 1 United Kingdom 8 United States 15 Global 138
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
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View Lastest Price from 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE manufacturers

Career Henan Chemical Co
Product
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE 39085-59-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2019-07-02

39085-59-1, 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDERelated Search:

2,4,6-Trimethylbenzenesulfonyl hydrazide 4-Ethylbenzenesulfonamide 2,4-Dimethylbenzenethiol 1,3,5-Triisopropylbenzene 2,4,6-TRIISOPROPYLBENZENESULFONAMIDE METHANESULFONYL HYDRAZIDE 2,6-DIMETHYLTHIOPHENOL Benzenesulfonyl hydrazide 4-Methylbenzenesulfonhydrazide 1,3,5-TRIETHYLBENZENE 2,4,6-TRIMETHYLTHIOPHENOL 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE (4-Isopropyl)thiophenol 2-Methylbenzene-1-sulfonamide antioxidant 1024 Benzenesulfonamide, 4-(1-methylethyl)- (9CI) TRIFLUOROACETYLTRIPHENYLSILANE 2,4,6-TRIISOPROPYLBENZENESULFONYLHYDRAZONE Benzenesulfonamide, 2,4,6-trimethyl- (9CI)

  • TRISYLHYDRAZIDE
  • TPSH
  • TRIISOPROPYLBENZENE SULFONYLHYDRAZIDE
  • 2,4,6-triisopropylbenzenesulphonohydrazide
  • 2,4,6-Triisopropyl benzenesulphonohydrazine
  • 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
  • 2,4,6-TRIISOPROPYL BENZENESULFONYL HYDRAZINE
  • 2,4,6-TRIISOPROPYLBENZENESULFONO-HYDRAZIDE
  • 2,4,6-TRIISOPROPYLBENZENESULFONOHYDRAZINE
  • 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE 96+%
  • TPSH, Trisylhydrazide
  • 2,4,6-Triisopropylbenzene-1-sulfonic acid hydrazide
  • 2,4,6-Triisopropylbenzenesulfonic acid hydrazide
  • 2,4,6-Tris(1-methylethyl)benzenesulfonic acid hydrazide
  • 2,4,6-Tris(isopropyl)benzenesulphonohydrazide 95%
  • 2,4,6-Tris(prop-2-yl)benzenesulphonohydrazide, TPSH
  • 2,4,6-Triisopropylphenylsulfonyl hydrazine
  • 2,4,6-Triisopropylbenzenesulphonohydrazide 95%
  • 2,4,6-Triisopropylbenzenesulfonyl hydrazide 90%
  • 2,4,6-Triisopropylbenzenesulfonyl hydrazide≥ 95%(Titration)
  • 2,4,6-tri(propan-2-yl)benzenesulfonohydrazide
  • Benzenesulfonic acid, 2,4,6-tris(1-methylethyl)-, hydrazide
  • 39085-59-1
  • CH32CH3C6H2SO2NHNH2
  • C15H26N2O2S
  • Building Blocks
  • Organic Building Blocks
  • Sulfonyl Hydrazides
  • Sulfur Compounds
  • Building Blocks
  • Chemical Synthesis
  • Organic Building Blocks
  • Sulfonyl Hydrazides
  • Sulfur Compounds