(2-METHYLAMINO-PHENYL)-METHANOL
- Product Name
- (2-METHYLAMINO-PHENYL)-METHANOL
- CAS No.
- 29055-08-1
- Chemical Name
- (2-METHYLAMINO-PHENYL)-METHANOL
- Synonyms
- 2-(Methylamino)benzyl alcohol;o-(Methylamino)benzenemethanol;2-(Methylamino)benzenemethanol;(2-METHYLAMINO-PHENYL)-METHANOL;Benzenemethanol, 2-(methylamino)-
- CBNumber
- CB5839423
- Molecular Formula
- C8H11NO
- Formula Weight
- 137.18
- MOL File
- 29055-08-1.mol
(2-METHYLAMINO-PHENYL)-METHANOL Property
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- Appearance
- Yellow to brown Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M288228
- Product name
- [2-(methylamino)phenyl]methanol
- Packaging
- 10mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- CHM0098034
- Product name
- (2-METHYLAMINO-PHENYL)-METHANOL
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $1266.14
- Updated
- 2021/12/16
- Product number
- 7076BA
- Product name
- (2-(Methylamino)phenyl)methanol
- Packaging
- 2.5g
- Price
- $1996
- Updated
- 2021/12/16
- Product number
- CD12088008
- Product name
- (2-(Methylamino)phenyl)methanol
- Purity
- 95+%
- Packaging
- 10g
- Price
- $1664
- Updated
- 2021/12/16
- Product number
- 29055081
- Product name
- (2-(Methylamino)phenyl)methanol
- Packaging
- 10g
- Price
- $1730.4
- Updated
- 2021/12/16
(2-METHYLAMINO-PHENYL)-METHANOL Chemical Properties,Usage,Production
Synthesis
119-68-6
29055-08-1
a) Preparation of 2-(N-methylamino)benzyl alcohol Lithium aluminum hydride (0.76 g, 0.02 mol) was suspended in anhydrous tetrahydrofuran (40 mL) under argon protection. To this suspension, an anhydrous tetrahydrofuran solution of N-methylphthalamic acid (1.51 g, 0.01 mol) was slowly added. The reaction mixture was refluxed for 1 hour and then the reaction was quenched by the addition of ice water (50 mL). The mixture was filtered through a diatomaceous earth pad and the filter cake was washed thoroughly with dichloromethane (50 mL). The organic layer was separated and the aqueous layer was further extracted with dichloromethane (50 mL). All organic layers were combined, washed with brine (30 mL), dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting pale yellow oil was purified by silica gel column chromatography (Wakogel C-200, 50 g, eluent n-hexane:ethyl acetate=2:1) to afford the colorless oil (2-(methylamino)phenyl)methanol (1.18 g, 86% yield). 1H-NMR (270 MHz, CDCl3): δ 2.87 (3H, s), 3.00-3.10 (1H, br.s), 4.64 (2H, s), 6.65-6.69 (2H, m), 7.05 (1H, d, J=7.2 Hz), 7.23-7.29 (1H, m).
References
[1] Patent: US6812238, 2004, B1. Location in patent: Page/Page column 21; 31-32
[2] Organic Letters, 2016, vol. 18, # 21, p. 5572 - 5575
(2-METHYLAMINO-PHENYL)-METHANOL Preparation Products And Raw materials
Raw materials
Preparation Products
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