ChemicalBook > CAS DataBase List > 3-Chloro-4-methylaniline

3-Chloro-4-methylaniline

Product Name
3-Chloro-4-methylaniline
CAS No.
95-74-9
Chemical Name
3-Chloro-4-methylaniline
Synonyms
CPT;2-CHLORO-4-TOLUIDINE;3-CHLORO-4-METHYL-PHENYLAMINE;OCPT;3-cpt;cpt[qr];drc1347;2B oil;DKC 1347;DRC 1339
CBNumber
CB5854707
Molecular Formula
C7H8ClN
Formula Weight
141.6
MOL File
95-74-9.mol
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3-Chloro-4-methylaniline Property

Melting point:
25 °C
Boiling point:
237-238 °C(lit.)
Density 
1.17
vapor pressure 
4.973-8.666Pa at 25℃
refractive index 
n20/D 1.584(lit.)
Flash point:
212 °F
storage temp. 
2-8°C
solubility 
Chloroform, Methanol (Slightly)
form 
powder to lump to clear liquid
pka
pK1: 4.05(+1) (25°C)
color 
White or Colorless to Light orange to Yellow
Specific Gravity
1.167
Water Solubility 
1 g/L (20 ºC)
BRN 
636511
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, acid chlorides, acids, acid anhydrides, chloroformates, reducing agents.
LogP
2.27
CAS DataBase Reference
95-74-9(CAS DataBase Reference)
NIST Chemistry Reference
Benzenamine, 3-chloro-4-methyl-(95-74-9)
EPA Substance Registry System
3-Chloro-4-methylaniline (95-74-9)
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Safety

Hazard Codes 
T,N,Xn
Risk Statements 
24/25-36/38-43-50/53-36/37/38-22
Safety Statements 
36/37/39-45-61-60-36/37-26
RIDADR 
UN 2239 6.1/PG 3
WGK Germany 
2
RTECS 
XU5111000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29214300
Hazardous Substances Data
95-74-9(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
236322
Product name
2-Chloro-4-aminotoluene
Purity
98%
Packaging
50g
Price
$18.4
Updated
2024/03/01
TCI Chemical
Product number
C0538
Product name
3-Chloro-4-methylaniline
Purity
>97.0%(GC)
Packaging
25g
Price
$68
Updated
2024/03/01
TCI Chemical
Product number
C0538
Product name
3-Chloro-4-methylaniline
Purity
>97.0%(GC)
Packaging
500g
Price
$411
Updated
2024/03/01
Alfa Aesar
Product number
A15439
Product name
3-Chloro-4-methylaniline, 98%
Packaging
250g
Price
$48.65
Updated
2024/03/01
Alfa Aesar
Product number
A15439
Product name
3-Chloro-4-methylaniline, 98%
Packaging
1000g
Price
$115.65
Updated
2024/03/01
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3-Chloro-4-methylaniline Chemical Properties,Usage,Production

Chemical Properties

brown solid

Chemical Properties

The chloromethylanilines are colorless or white crystalline solids or liquids, some have a mild fishy odor.

Uses

2-Chloro-4-aminotoluene has been used in the preparation of 2-chloro-4-cyanotoluene by Sandmeyer reaction with cuprous cyanide.

Definition

ChEBI: A monochloroaniline that is p-toluidine in which one of the hydrogens that is meta to the amino group is replaced by a chlorine.

General Description

Brown solid with a mild odor.

Air & Water Reactions

May be sensitive to prolonged exposure to air and light. Insoluble in water.

Reactivity Profile

3-Chloro-4-methylaniline may be sensitive to prolonged exposure to air and light. 3-Chloro-4-methylaniline may react with oxidizing agents. 3-Chloro-4-methylaniline is incompatible with acids, acid chlorides, acid anhydrides and chloroformates. 3-Chloro-4-methylaniline is also incompatible with reducing agents.

Fire Hazard

3-Chloro-4-methylaniline is combustible.

Safety Profile

Poison by ingestion, intravenous, and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl and NOx. See also other chloro toluidme entries.

Potential Exposure

Most of the isomers are used in dyestuff manufacture. The 3-chloro-para isomer is used to kill birds. It is marketed as pelleted bait for control of bird populations.

Shipping

UN2239 Chlorotoluidines, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3429 Chlorotoluidines, liquid, Hazard Class: 6.1; Labels: 6.1- Poisonous materials

Incompatibilities

Incompatible with oxidizers, strong acids; chloroformates, and acid anhydrides, isocyanates, aldehydes forming fire and explosive hazards.

3-Chloro-4-methylaniline Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Chloro-4-methylaniline Suppliers

Weifang Mingran Chemical Co., Ltd.
Tel
15066331899,0536-2082396,117761326 15063661899
Fax
0536-2082397
Email
mingranchem@163.com
Country
China
ProdList
430
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35906
Advantage
56
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18217
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12426
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9984
Advantage
60
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View Lastest Price from 3-Chloro-4-methylaniline manufacturers

Hebei Guanlang Biotechnology Co,.LTD
Product
3-Chloro-4-methylaniline 95-74-9
Price
US $9.00/KG
Min. Order
1KG
Purity
99.9
Supply Ability
1 ton
Release date
2023-07-12
Career Henan Chemical Co
Product
3-Chloro-4-methylaniline 95-74-9
Price
US $1.00-2.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200kg
Release date
2019-08-30

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