ChemicalBook > CAS DataBase List > (-)-O-ACETYL-L-MALIC ANHYDRIDE

(-)-O-ACETYL-L-MALIC ANHYDRIDE

Product Name
(-)-O-ACETYL-L-MALIC ANHYDRIDE
CAS No.
59025-03-5
Chemical Name
(-)-O-ACETYL-L-MALIC ANHYDRIDE
Synonyms
(S)-Acetoxysuccinic Anhydride;L-O-Acetylmalic Anhydride;2-acetoxysuccinicanhydride;(S)-(-)-2-2-Acetoxysuccinic;(S)-2-O-Acetylmalic Anhydride;(-)-O-ACETYL-L-MALIC ANHYDRIDE;2-O-ACETYL-(S)-MALIC ANHYDRIDE;(-)-O-Acetyl-L-malic Anhydride;(S)-(-)-O-ACETYLMALIC ANHYDRIDE;(S)-2-ACETOXYSUCCINIC ANHYDRIDE
CBNumber
CB6114633
Molecular Formula
C6H6O5
Formula Weight
158.11
MOL File
59025-03-5.mol
More
Less

(-)-O-ACETYL-L-MALIC ANHYDRIDE Property

Melting point:
54-56 °C(lit.)
Boiling point:
296.6±33.0 °C(Predicted)
Density 
1.38±0.1 g/cm3(Predicted)
refractive index 
-25.5 ° (C=5, CHCl3)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Dichloromethane, DMF, Ethyl Acetate
form 
Powder
color 
White Crystalline
optical activity
[α]20/D 27°, c = 1 in chloroform
Water Solubility 
Reacts in water.
Sensitive 
Moisture Sensitive
BRN 
82504
Stability:
Stable. Incompatible with strong oxidizing agents. Sensitive to moisture.
CAS DataBase Reference
59025-03-5(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
10-21
HS Code 
2917.19.7050
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
422800
Product name
(S)-(?)-2-Acetoxysuccinic anhydride
Purity
98%
Packaging
5g
Price
$60.2
Updated
2023/01/07
TCI Chemical
Product number
A1101
Product name
(-)-O-Acetyl-L-malic Anhydride
Purity
>97.0%(T)
Packaging
5g
Price
$49
Updated
2024/03/01
TCI Chemical
Product number
A1101
Product name
(-)-O-Acetyl-L-malic Anhydride
Purity
>97.0%(T)
Packaging
25g
Price
$228
Updated
2024/03/01
Alfa Aesar
Product number
044366
Product name
(S)-(-)-2-Acetoxysuccinic anhydride, 98%
Packaging
2g
Price
$20.1
Updated
2021/12/16
Alfa Aesar
Product number
044366
Product name
(S)-(-)-2-Acetoxysuccinic anhydride, 98%
Packaging
10g
Price
$74.6
Updated
2021/12/16
More
Less

(-)-O-ACETYL-L-MALIC ANHYDRIDE Chemical Properties,Usage,Production

Chemical Properties

White Crystalline Solid

Uses

(S)-(-)-2-Acetoxysuccinic anhydride is used as intermediates for detergents via O-acetylmalic acid amides. Regioselective ring opening of malic acid anhydrides by carbon nucleophiles.

Uses

(-)-O-Acetyl-L-Malic Anhydride can be used as intermediates for detergents via O-acetylmalic acid amides. Regioselective ring opening of malic acid anhydrides by carbon nucleophiles

Purification Methods

Recrystallise it from Ac2O and dry it in a vacuum over KOH, or by washing it with dry Et2O due to its deliquescent nature. [Jones J Chem Soc 788 1933, Henrot et al. Synth Commun 16 183 1986, Shiuey et al. J Org Chem 52 1040 1988, RS: Cohen et al. J Am Chem Soc 88 5306 1966.]

(-)-O-ACETYL-L-MALIC ANHYDRIDE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(-)-O-ACETYL-L-MALIC ANHYDRIDE Suppliers

Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Alichem Inc.
Tel
--
Fax
--
Email
sales@alichem.com
Country
United States
ProdList
6167
Advantage
58
TCI America, Inc. (Tokyo Chemical Industry Co., Ltd.)
Tel
--
Fax
--
Email
.Crew@tcichemicals.com
Country
United States
ProdList
3164
Advantage
58
MilliporeSigma (Sigma-Aldrich Corp.)
Tel
--
Fax
--
Email
@sial.com
Country
United States
ProdList
5414
Advantage
58
VWR International, LLC.
Tel
--
Fax
--
Email
@sargentwelch.com
Country
United States
ProdList
6262
Advantage
58
Combi-Blocks Inc.
Tel
--
Fax
--
Email
sales@combi-blocks.com
Country
United States
ProdList
6618
Advantage
69
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6962
Advantage
56
Waterstone Technology, LLC
Tel
--
Fax
--
Email
sales@waterstonetech.com
Country
United States
ProdList
6786
Advantage
30
Medical Isotopes
Tel
--
Fax
--
Email
stohler@medicalisotopes.com
Country
United States
ProdList
6181
Advantage
68
Advanced Asymmetrics, Inc.
Tel
--
Fax
--
Email
sales@advancedasymmetrics.com
Country
United States
ProdList
521
Advantage
42
AK Scientific, Inc.
Tel
--
Fax
--
Email
sales@aksci.com
Country
United States
ProdList
6347
Advantage
65
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
United States
ProdList
6814
Advantage
81
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
ASDI Incorporated
Tel
--
Fax
--
Email
customerservice@asdi.net
Country
United States
ProdList
6922
Advantage
67
More
Less

View Lastest Price from (-)-O-ACETYL-L-MALIC ANHYDRIDE manufacturers

Career Henan Chemical Co
Product
(-)-O-ACETYL-L-MALIC ANHYDRIDE 59025-03-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-03

59025-03-5, (-)-O-ACETYL-L-MALIC ANHYDRIDERelated Search:


  • 2-O-ACETYL-(S)-MALIC ANHYDRIDE
  • (-)-O-ACETYL-L-MALIC ANHYDRIDE
  • (S)-(-)-O-ACETYLMALIC ANHYDRIDE
  • (S)-(-)-2-ACETOXYSUCCINIC ANHYDRIDE
  • (S)-2-ACETOXYSUCCINIC ANHYDRIDE
  • L-O-Acetylmalic Anhydride
  • (S)-3-Acetoxy-dihydro-2,5-furandione, O-Acetyl-L-malic anhydride
  • (2S)-2-Acetoxysuccinic anhydride
  • (3S)-3-Acetoxyfuran-2,5(3H,4H)-dione
  • 2-acetoxysuccinicanhydride
  • (s)-3-acetoxy-dihydro-2,5-furandione
  • (3S)-3-(Acetyloxy)dihydro-2,5-furandione
  • (S)-2-O-Acetylmalic Anhydride
  • (S)-Acetoxysuccinic Anhydride
  • (S)-3β-Acetoxy-3,4-dihydro-2,5-furandione
  • [S,(-)]-2-(Acetyloxy)succinic anhydride
  • Acetic acid (S)-2,5-dioxotetrahydrofuran-3β-yl ester
  • (S)-(-)-2-2-Acetoxysuccinic
  • (-)-<i>O</i>-Acetyl-<small>L</small>-malic Anhydride
  • (-)-O-Acetyl-L-malic Anhydride &gt
  • 2,5-Furandione, 3-(acetyloxy)dihydro-, (3S)-
  • [(3S)-2,5-dioxooxolan-3-yl] acetate
  • (-)-O-Acetyl-L-malic Anhydride
  • (S)-2,5-dioxotetrahydrofuran-3-yl acetate
  • 59025-03-5
  • C6H6O5
  • Organic Building Blocks
  • Carboxylic Acid Anhydrides
  • Asymmetric Synthesis
  • Carboxylic Acids (Chiral)
  • Chiral Building Blocks
  • ANHYDRIDE
  • Chiral Reagents
  • Carboxylic Acids (Chiral)
  • Chiral Building Blocks
  • Synthetic Organic Chemistry
  • Chiral Compound
  • Heterocycles
  • Miscellaneous Reagents