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Phenylselenenyl chloride

Product Name
Phenylselenenyl chloride
CAS No.
5707-04-0
Chemical Name
Phenylselenenyl chloride
Synonyms
enenyL;chloroselenobenzene;Phenylchloroselenium;Phenylseleno chloride;PHENYLSELENYL CHLORIDE;PHENYLSELENIUM CHLORIDE;BENZENESELENYL CHLORIDE;PHENYLSELENENYL CHLORIDE;BENZENESELENENYL CHLORIDE;phenyl selenohypochlorite
CBNumber
CB6128896
Molecular Formula
C6H5ClSe
Formula Weight
191.52
MOL File
5707-04-0.mol
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Phenylselenenyl chloride Property

Melting point:
59-62 °C (lit.)
Boiling point:
120 °C/20 mmHg (lit.)
Flash point:
120°C/20mm
storage temp. 
Store below +30°C.
solubility 
Soluble in methanol.
form 
crystal
color 
red
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Sensitive 
Moisture Sensitive
BRN 
1237091
Exposure limits
ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3
Stability:
Stable, but may be air or moisture sensitive. Incompatible with strong bases, strong oxidizing agents.
InChI
InChI=1S/C6H5ClSe/c7-8-6-4-2-1-3-5-6/h1-5H
InChIKey
WJCXADMLESSGRI-UHFFFAOYSA-N
SMILES
C1([Se]Cl)=CC=CC=C1
CAS DataBase Reference
5707-04-0(CAS DataBase Reference)
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Safety

Hazard Codes 
T,N
Risk Statements 
23/25-33-50/53
Safety Statements 
20/21-28-45-60-61
RIDADR 
UN 2928 6.1/PG 2
WGK Germany 
3
10-21
TSCA 
No
HazardClass 
6.1
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
183342
Product name
Phenylselenyl chloride
Purity
98%
Packaging
1g
Price
$53.1
Updated
2024/03/01
Sigma-Aldrich
Product number
183342
Product name
Phenylselenyl chloride
Purity
98%
Packaging
10g
Price
$294
Updated
2024/03/01
TCI Chemical
Product number
P1091
Product name
Phenylselenenyl Chloride
Purity
>97.0%(T)
Packaging
5g
Price
$74
Updated
2024/03/01
TCI Chemical
Product number
P1091
Product name
Phenylselenenyl Chloride
Purity
>97.0%(T)
Packaging
25g
Price
$253
Updated
2024/03/01
Alfa Aesar
Product number
A12751
Product name
Phenylselenenyl chloride, 98%
Packaging
5g
Price
$83.6
Updated
2024/03/01
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Phenylselenenyl chloride Chemical Properties,Usage,Production

Chemical Properties

crystalline solid

Uses

Phenylselenenyl chloride is used in the preparation of (cyclobut-1-enylselanyl)benzene. It is an important versatile reagent used in organic synthesis. Further, it serves as a useful synthon for 2-amino alcohols.

Application

Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins[1].

General Description

Phenylselenyl chloride is a synthon for 2-amino alcohols. It is a versatile reagent in organic synthesis.

Purification Methods

Purify it by distillation in a vacuum, and recrystallisation (orange needles) from hexane [Foster J Am Chem Soc 55 822 1933, Foster et al. Recl Trav Chim, Pays-Bas 53 405, 408 1934, Behaghel & Seibert Chem Ber 66 714 1933]. [Beilstein 6 III 1110.] HIGHLY TOXIC.

References

[1] S. Uemura. “Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins.” Tetrahedron Letters 21 1 (1980): 1533–1536.

Phenylselenenyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Phenylselenenyl chloride Suppliers

Molekula Limited
Tel
--
Fax
--
Email
o@molekula.com
Country
United Kingdom
ProdList
6127
Advantage
58
Fisher Scientific Uk Ltd.
Tel
--
Fax
--
Email
.international@thermofisher.com
Country
United Kingdom
ProdList
2932
Advantage
58
Manchester Organics
Tel
--
Fax
--
Email
info@manchesterorganics.com
Country
United Kingdom
ProdList
6834
Advantage
67
MOLEKULA Ltd.
Tel
--
Fax
--
Email
kevinbanks@molekula.com
Country
United Kingdom
ProdList
6140
Advantage
66
Fluorochem Ltd
Tel
--
Fax
--
Email
vernam@fluorochem.co.uk
Country
United Kingdom
ProdList
6375
Advantage
65
Eurolabs Limited
Tel
--
Fax
--
Country
United Kingdom
ProdList
6309
Advantage
46
VWR International
Tel
--
Fax
--
Email
solutions@vwr.com
Country
United Kingdom
ProdList
6548
Advantage
82
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View Lastest Price from Phenylselenenyl chloride manufacturers

Career Henan Chemical Co
Product
PHENYLSELENENYL CHLORIDE 5707-04-0
Price
US $2.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100g , 1kg, 5kg , 50kg
Release date
2020-01-07

5707-04-0, Phenylselenenyl chlorideRelated Search:


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  • C6H5ClSe
  • C6H5SeCl
  • Classes of Metal Compounds
  • Semimetal Compounds
  • Se (Selenium) Compounds
  • Building Blocks
  • Selenium Compounds
  • Organic Building Blocks
  • Classes of Metal Compounds
  • Se (Selenium) Compounds
  • Semimetal Compounds
  • organoselenides