4-Bromobenzylamine hydrochloride
- Product Name
- 4-Bromobenzylamine hydrochloride
- CAS No.
- 26177-44-6
- Chemical Name
- 4-Bromobenzylamine hydrochloride
- Synonyms
- 4-BBA X HCL;4-BROMOBENZYLAMINE HCL;p-Bromo Benzylamine Hcl;4-BROMOBENZYLAMINE HYDROCHLORIDE;P-BROMOBENZYLAMINE HYDROCHLORIDE;4-Bromobenzylamine Hydrochloride >4-Bromobenzylamine hydrochloride,98%;4-BROMOBENZYLAMINE HYDROCHLORIDE 98%;4-Bromobenzylamine hydrochloride 99+%;(4-Bromophenyl)methamine hydrochloride
- CBNumber
- CB6136325
- Molecular Formula
- C7H9BrClN
- Formula Weight
- 222.51
- MOL File
- 26177-44-6.mol
4-Bromobenzylamine hydrochloride Property
- Melting point:
- 274-276 °C(lit.)
- refractive index
- 1,5855-1,5875
- storage temp.
- Inert atmosphere,Room Temperature
- form
- powder to crystal
- color
- White to Almost white
- Water Solubility
- Soluble in water.
- Sensitive
- Hygroscopic
- BRN
- 3693458
- InChI
- InChI=1S/C7H8BrN.ClH/c8-7-3-1-6(5-9)2-4-7;/h1-4H,5,9H2;1H
- InChIKey
- BVYUYDBWQMSOKM-UHFFFAOYSA-N
- SMILES
- C1(CN)=CC=C(Br)C=C1.Cl
- CAS DataBase Reference
- 26177-44-6(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-21/22
- Safety Statements
- 26-37/39-36/37/39-36
- WGK Germany
- 3
- Hazard Note
- Irritant
- HS Code
- 29214900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 205214
- Product name
- 4-Bromobenzylamine hydrochloride
- Purity
- 98%
- Packaging
- 5g
- Price
- $153
- Updated
- 2025/07/31
- Product number
- B1841
- Product name
- 4-Bromobenzylamine Hydrochloride
- Purity
- >97.0%(N)(T)
- Packaging
- 5g
- Price
- $102
- Updated
- 2025/07/31
- Product number
- B1841
- Product name
- 4-Bromobenzylamine Hydrochloride
- Purity
- >97.0%(N)(T)
- Packaging
- 25g
- Price
- $473
- Updated
- 2025/07/31
- Product number
- B678305
- Product name
- 4-Bromobenzylamine Hydrochloride
- Packaging
- 10mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- J99793
- Product name
- 4-BromobenzylamineHCl
- Packaging
- 100g
- Price
- $185
- Updated
- 2021/12/16
4-Bromobenzylamine hydrochloride Chemical Properties,Usage,Production
Chemical Properties
OFF-WHITE TO BEIGE CRYSTALLINE POWDER
Uses
4-Bromobenzylamine hydrochloride is used to study the characteristics of C-terminal polyamine modification in the presence of protease and amine. Further, it is used to prepare 1-(4-Brombenzyl)-pyrrole by reacting with 2,5-dimethoxy-tetrahydro-furan.
Synthesis
623-00-7
26177-44-6
General procedure: in a glove box, to a flame-dried GLC vial fitted with a magnetic stirring bar was added [3a] + [BArF4]? (1.0 mol%) and Me2PhSiH(2a) (2.1 or 5.0 equivalents). The specified 4-bromobenzonitrile was added to the glove box (in case of solid material) or via a microsyringe outside the glove box. The resulting reaction mixture was kept at room temperature for the indicated time. Upon completion of the reaction, a mixture of cyclohexane and tert-butyl methyl ether (90:10) containing 4% Et3N (0.5 mL) was added to quench the reaction. The resulting solution was filtered through a diatomaceous earth pad coated with a small amount of silica gel, and a solution of cyclohexane and tert-butyl methyl ether (90:10) containing 4% Et3N (3-4 mL) was used as the eluent. The solvent was removed under reduced pressure and the residue was dissolved in Et2O (1 mL), followed by the addition of HCl (2M in Et2O, 1.0 mL, 2.0 mmol, 10 equiv). The resulting suspension was stirred for 1 h and filtered to give 4-bromobenzylamine hydrochloride as a white to yellow solid.
References
[1] Synlett, 2017, vol. 28, # 18, p. 2411 - 2414
[2] Tetrahedron, 2014, vol. 70, # 4, p. 975 - 983
[3] Tetrahedron Letters, 2009, vol. 50, # 50, p. 7005 - 7007
[4] Journal of the American Chemical Society, 2016, vol. 138, # 28, p. 8809 - 8814
[5] ACS Catalysis, 2018, vol. 8, # 10, p. 9125 - 9130
4-Bromobenzylamine hydrochloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Bromobenzylamine hydrochloride manufacturers
- Product
- 4-Bromobenzylamine hydrochloride 26177-44-6
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-04