PSEUDOJERVINE

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Product Name: PSEUDOJERVINE
CAS No.: 36069-05-3
Chemical Name: PSEUDOJERVINE
Synonyms: PSEUDOJERVINE;Spiro[9H-benzo[a]fluorene-9,2'(3'H)-furo[3,2-b]pyridin]-11(1H)-one, 3-(β-D-glucopyranosyloxy)-2,3,3'a,4,4',5',6,6',6a,6b,7,7',7'a,8,11a,11b-hexadecahydro-3',6',10,11b-tetramethyl-, (2'R,3S,3'R,3'aS,6'S,6aS,6bS,7'aR,11aS,11bR)-
CBNumber: CB61424850
Molecular Formula: C33H49NO8
Formula Weight: 587.749
MOL File: 36069-05-3.mol

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PSEUDOJERVINE Property

Melting point:: 300-301° (dec)
alpha: D25 -133° (c = 0.48 in 1:3 ethanol-chloroform)
Boiling point:: 643.44°C (rough estimate)
Density: 1.1485 (rough estimate)
refractive index: 1.5960 (estimate)
pka: 12.91±0.70(Predicted)

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

American Custom Chemicals Corporation

Product number: PXT0001972
Product name: PSEUDOJERVINE
Purity: 95.00%
Packaging: 5MG
Price: $504.44
Updated: 2021/12/16

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PSEUDOJERVINE Chemical Properties,Usage,Production

Description

This alkaloid has been found in both Veratrum album and V. viride Ait. It crystallizes from EtOH in hexagonal tablets and has [α]²⁰_D - 139° (CHC13). The hydrochloride dihydrate has m.p. 254-6°C (dry, dec.); the sulphate is also crystalline but the aurichloride is amorphous. Poethke has shown that the alkaloid is a secondary base, gives a nitro so derivative, m.p. 261°C, and contains five replaceable hydrogen atoms. On boiling with dilute HCl it is hydrolyzed to (+)- glucose and isojervine, an isomer of jervine. This latter base crystallizes with solvent, e.g. the CHC13 adduct softens at 135-1500 C; the crystallizate with EtOH has m.p. 114-6°C (dec.) and that with Me2CO has m.p. 110-4°C; [α]²⁰_D - 32° (EtOH).

Definition

ChEBI: Pseudojervine is a steroid saponin.

References

Wright, Luff., J. Chem. Soc., 35,405,421 (1879)
Salzberger., Arch. Pharm., 228,462 (1890)
Poethke., ibid, 275,357,571 (1937)
Poethke., ibid, 276, 170 (1938)
Jacobs, Craig.,J. Biol. Chem., 155,564 (1944)

PSEUDOJERVINE Preparation Products And Raw materials

Raw materials

Preparation Products

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36069-05-3, PSEUDOJERVINERelated Search:

VERATRINE veratramine 3,4-Dimethoxybenzoic acid PROTOVERATRINE A VERATROSINE 3,4-Dimethoxybenzyl alcohol CYCLOPAMINE VERATRIDINE (Z)-6-HENICOSEN-11-ONE 3,7-DIMETHYL-2-METHYLENE-OCT-6-ENAL 3-(ALLYLOXY)PIPERIDINE 2-Isopropyl-5-methyl-2-hexenal 3-(3-ALLYL)-5-HEXEN-1-AL JERVINE PSEUDOJERVINE

PSEUDOJERVINE

Spiro[9H-benzo[a]fluorene-9,2'(3'H)-furo[3,2-b]pyridin]-11(1H)-one, 3-(β-D-glucopyranosyloxy)-2,3,3'a,4,4',5',6,6',6a,6b,7,7',7'a,8,11a,11b-hexadecahydro-3',6',10,11b-tetramethyl-, (2'R,3S,3'R,3'aS,6'S,6aS,6bS,7'aR,11aS,11bR)-

36069-05-3