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PSEUDOJERVINE

Product Name
PSEUDOJERVINE
CAS No.
36069-05-3
Chemical Name
PSEUDOJERVINE
Synonyms
PSEUDOJERVINE;Spiro[9H-benzo[a]fluorene-9,2'(3'H)-furo[3,2-b]pyridin]-11(1H)-one, 3-(β-D-glucopyranosyloxy)-2,3,3'a,4,4',5',6,6',6a,6b,7,7',7'a,8,11a,11b-hexadecahydro-3',6',10,11b-tetramethyl-, (2'R,3S,3'R,3'aS,6'S,6aS,6bS,7'aR,11aS,11bR)-
CBNumber
CB61424850
Molecular Formula
C33H49NO8
Formula Weight
587.749
MOL File
36069-05-3.mol
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PSEUDOJERVINE Property

Melting point:
300-301° (dec)
alpha 
D25 -133° (c = 0.48 in 1:3 ethanol-chloroform)
Boiling point:
643.44°C (rough estimate)
Density 
1.1485 (rough estimate)
refractive index 
1.5960 (estimate)
pka
12.91±0.70(Predicted)
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
PXT0001972
Product name
PSEUDOJERVINE
Purity
95.00%
Packaging
5MG
Price
$504.44
Updated
2021/12/16
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PSEUDOJERVINE Chemical Properties,Usage,Production

Description

This alkaloid has been found in both Veratrum album and V. viride Ait. It crystallizes from EtOH in hexagonal tablets and has [α]20D - 139° (CHC13). The hydrochloride dihydrate has m.p. 254-6°C (dry, dec.); the sulphate is also crystalline but the aurichloride is amorphous. Poethke has shown that the alkaloid is a secondary base, gives a nitro so derivative, m.p. 261°C, and contains five replaceable hydrogen atoms. On boiling with dilute HCl it is hydrolyzed to (+)- glucose and isojervine, an isomer of jervine. This latter base crystallizes with solvent, e.g. the CHC13 adduct softens at 135-1500 C; the crystallizate with EtOH has m.p. 114-6°C (dec.) and that with Me2CO has m.p. 110-4°C; [α]20D - 32° (EtOH).

Definition

ChEBI: Pseudojervine is a steroid saponin.

References

Wright, Luff., J. Chem. Soc., 35,405,421 (1879)
Salzberger., Arch. Pharm., 228,462 (1890)
Poethke., ibid, 275,357,571 (1937)
Poethke., ibid, 276, 170 (1938)
Jacobs, Craig.,J. Biol. Chem., 155,564 (1944)

PSEUDOJERVINE Preparation Products And Raw materials

Raw materials

Preparation Products

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36069-05-3, PSEUDOJERVINERelated Search:


  • PSEUDOJERVINE
  • Spiro[9H-benzo[a]fluorene-9,2'(3'H)-furo[3,2-b]pyridin]-11(1H)-one, 3-(β-D-glucopyranosyloxy)-2,3,3'a,4,4',5',6,6',6a,6b,7,7',7'a,8,11a,11b-hexadecahydro-3',6',10,11b-tetramethyl-, (2'R,3S,3'R,3'aS,6'S,6aS,6bS,7'aR,11aS,11bR)-
  • 36069-05-3