(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER
- Product Name
- (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER
- CAS No.
- 176980-36-2
- Chemical Name
- (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER
- Synonyms
- 3-(BOC-AMino)benzaldehyde;tert-butyl 3-formylphenylcarbamate;tert-butylN-(3-formylphenyl)carbamate;3-(tert-Butoxycarbonylamino)benzaldehyde;(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER;Carbamic acid, N-(3-formylphenyl)-, 1,1-dimethylethyl ester
- CBNumber
- CB6153719
- Molecular Formula
- C12H15NO3
- Formula Weight
- 221.25
- MOL File
- 176980-36-2.mol
(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER Property
- Melting point:
- 88℃
- Boiling point:
- 291℃
- Density
- 1.163
- Flash point:
- 130℃
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- solid
- pka
- 13.50±0.70(Predicted)
- color
- Beige
Safety
- RIDADR
- UN2811
- HS Code
- 2913000090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B601520
- Product name
- 3-(BOC-Amino)benzaldehyde
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FB142378
- Product name
- tert-Butyl (3-formylphenyl)carbamate
- Packaging
- 2g
- Price
- $106
- Updated
- 2021/12/16
- Product number
- V3840
- Product name
- tert-Butyl(3-formylphenyl)carbamate
- Packaging
- 1g
- Price
- $114
- Updated
- 2021/12/16
- Product number
- V3840
- Product name
- tert-Butyl(3-formylphenyl)carbamate
- Packaging
- 10g
- Price
- $328
- Updated
- 2021/12/16
- Product number
- FB142378
- Product name
- tert-Butyl (3-formylphenyl)carbamate
- Packaging
- 10g
- Price
- $369
- Updated
- 2021/12/16
(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER Chemical Properties,Usage,Production
Synthesis
118684-31-4
176980-36-2
General procedure for the synthesis of tert-butyl (3-formylphenyl)-carbamate from tert-butyl (3-(hydroxymethyl)phenyl)carbamate: activated manganese dioxide (7.8 g, 90 mmol) was added to a solution of dichloromethane (50 mL) containing 3-(tert-butoxycarbonylamino)-benzyl alcohol (2.0 g, 9.0 mmol). The resulting suspension was stirred and reacted at room temperature for 16 hours. Upon completion of the reaction, the mixture was filtered through a diatomaceous earth pad and the filtrate was concentrated under reduced pressure to give 1.7 g (85% yield) of the target product. The product was characterized by 1H NMR (400 MHz, CDCl3): δ 9.97 (s, 1H), 7.92 (t, J = 1.8 Hz, 1H), 7.63 (dd, J = 8.0,1.1 Hz, 1H), 7.55 (ddd, J = 7.6,1.4,1.1 Hz, 1H), 7.44 (t, J = 7.6 Hz, 1H), and 1.53 (s, 9H).
References
[1] Chemistry - A European Journal, 2016, vol. 22, # 26, p. 8814 - 8822
[2] Angewandte Chemie - International Edition, 2017, vol. 56, # 49, p. 15746 - 15750
[3] Angew. Chem., 2017, vol. 129, p. 15952 - 15957,6
[4] Patent: WO2018/114965, 2018, A1. Location in patent: Page/Page column 27
[5] Chemistry of Materials, 2011, vol. 23, # 21, p. 4844 - 4856
(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER manufacturers
- Product
- (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER 176980-36-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2020-01-11