ChemicalBook > CAS DataBase List > (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER

(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER

Product Name
(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER
CAS No.
176980-36-2
Chemical Name
(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER
Synonyms
3-(BOC-AMino)benzaldehyde;tert-butyl 3-formylphenylcarbamate;tert-butylN-(3-formylphenyl)carbamate;3-(tert-Butoxycarbonylamino)benzaldehyde;(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER;Carbamic acid, N-(3-formylphenyl)-, 1,1-dimethylethyl ester
CBNumber
CB6153719
Molecular Formula
C12H15NO3
Formula Weight
221.25
MOL File
176980-36-2.mol
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(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER Property

Melting point:
88℃
Boiling point:
291℃
Density 
1.163
Flash point:
130℃
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
solid
pka
13.50±0.70(Predicted)
color 
Beige
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Safety

RIDADR 
UN2811
HS Code 
2913000090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B601520
Product name
3-(BOC-Amino)benzaldehyde
Packaging
500mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB142378
Product name
tert-Butyl (3-formylphenyl)carbamate
Packaging
1g
Price
$61
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB142378
Product name
tert-Butyl (3-formylphenyl)carbamate
Packaging
2g
Price
$106
Updated
2021/12/16
AK Scientific
Product number
V3840
Product name
tert-Butyl(3-formylphenyl)carbamate
Packaging
1g
Price
$114
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB142378
Product name
tert-Butyl (3-formylphenyl)carbamate
Packaging
5G
Price
$212
Updated
2021/12/16
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(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER Chemical Properties,Usage,Production

Synthesis

118684-31-4

176980-36-2

General procedure for the synthesis of tert-butyl (3-formylphenyl)-carbamate from tert-butyl (3-(hydroxymethyl)phenyl)carbamate: activated manganese dioxide (7.8 g, 90 mmol) was added to a solution of dichloromethane (50 mL) containing 3-(tert-butoxycarbonylamino)-benzyl alcohol (2.0 g, 9.0 mmol). The resulting suspension was stirred and reacted at room temperature for 16 hours. Upon completion of the reaction, the mixture was filtered through a diatomaceous earth pad and the filtrate was concentrated under reduced pressure to give 1.7 g (85% yield) of the target product. The product was characterized by 1H NMR (400 MHz, CDCl3): δ 9.97 (s, 1H), 7.92 (t, J = 1.8 Hz, 1H), 7.63 (dd, J = 8.0,1.1 Hz, 1H), 7.55 (ddd, J = 7.6,1.4,1.1 Hz, 1H), 7.44 (t, J = 7.6 Hz, 1H), and 1.53 (s, 9H).

References

[1] Chemistry - A European Journal, 2016, vol. 22, # 26, p. 8814 - 8822
[2] Angewandte Chemie - International Edition, 2017, vol. 56, # 49, p. 15746 - 15750
[3] Angew. Chem., 2017, vol. 129, p. 15952 - 15957,6
[4] Patent: WO2018/114965, 2018, A1. Location in patent: Page/Page column 27
[5] Chemistry of Materials, 2011, vol. 23, # 21, p. 4844 - 4856

(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER Suppliers

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View Lastest Price from (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER manufacturers

Career Henan Chemical Co
Product
(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER 176980-36-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-11

176980-36-2, (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTERRelated Search:

1-N-BOC-1-N-Methyl-1,3-DIAMINOPROPANE-HCl tert-butyl 2-bromoethylmethylcarbamate TERT-BUTYL 2-IODOETHYLCARBAMATE tert-Butyl (2-chlorothiazol-4-yl)carbamate BOC-3-AMINOBENZOIC ACID 3-AMINO-5-CARBOXYBENZENEBORONIC ACID, N-BOC PROTECTED 98 BOC-3-AMINO-2-METHYLBENZOIC ACID N-BOC-3-AMINO-4-CHLOROBENZOIC ACID 4-(3-BOC-AMINO-PHENYL)-2,4-DIOXO-BUTYRIC ACID METHYL ESTER 3-[(tert-Butoxycarbonyl)amino]-5-hydroxybenzoic acid N-BOC-5-AMINO-2-CHLOROBENZOIC ACID BOC-5-AMINO-2-METHOXYBENZOIC ACID 5-(N-TERT-BUTOXYCARBONYLAMINO)SALICYLIC ACID (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER BOC-3-AMINO-4-METHYLBENZOIC ACID Benzoic acid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-4-methoxy- (9CI) 3-(BOC-AMINO)-4-HYDROXYBENZOIC ACID BOC-2-AMINOBENZENE-1,4-DICARBOXYLIC ACID

  • tert-butyl 3-formylphenylcarbamate
  • (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER
  • tert-butylN-(3-formylphenyl)carbamate
  • 3-(tert-Butoxycarbonylamino)benzaldehyde
  • 3-(BOC-AMino)benzaldehyde
  • Carbamic acid, N-(3-formylphenyl)-, 1,1-dimethylethyl ester
  • 176980-36-2