ChemicalBook > CAS DataBase List > Bis(2-oxo-3-oxazolidinyl)phosphinic chloride

Bis(2-oxo-3-oxazolidinyl)phosphinic chloride

Product Name
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride
CAS No.
68641-49-6
Chemical Name
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride
Synonyms
BOP-CL;BOP-CI;BOP-C;BOPDC;idinyL;BIS(2-OXO-3-OX;Phosphoric acid bi;Bis(2-oxo-3-oxazoL;Bis(2-oxo-3-oxazolid;bis(2-oxo-3-oxazolidinyl)-phosphinicchlorid
CBNumber
CB6177768
Molecular Formula
C6H8ClN2O5P
Formula Weight
254.56
MOL File
68641-49-6.mol
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Bis(2-oxo-3-oxazolidinyl)phosphinic chloride Property

Melting point:
191 °C (dec.)(lit.)
Boiling point:
332.8±25.0 °C(Predicted)
Density 
1.71±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
slightly sol CH2Cl2, MeCN, THF, DMF; dec H2O
pka
-2.47±0.20(Predicted)
form 
Crystalline Powder
color 
White to off-white
Water Solubility 
Hydrolyzes with water.
Sensitive 
Moisture Sensitive
BRN 
3654596
InChIKey
KLDLRDSRCMJKGM-UHFFFAOYSA-N
CAS DataBase Reference
68641-49-6(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45-27
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
RTECS 
SZ5871000
F 
10-21
HazardClass 
8
PackingGroup 
II
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
15140
Product name
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride
Purity
≥97.0% (AT)
Packaging
5g
Price
$90.8
Updated
2024/03/01
Sigma-Aldrich
Product number
15140
Product name
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride
Purity
≥97.0% (AT)
Packaging
25g
Price
$355
Updated
2024/03/01
TCI Chemical
Product number
B1213
Product name
Bis(2-oxo-3-oxazolidinyl)phosphinic Chloride
Purity
>97.0%(T)
Packaging
5g
Price
$25
Updated
2024/03/01
TCI Chemical
Product number
B1213
Product name
Bis(2-oxo-3-oxazolidinyl)phosphinic Chloride
Purity
>97.0%(T)
Packaging
25g
Price
$84
Updated
2024/03/01
Alfa Aesar
Product number
L08775
Product name
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride, 97%
Packaging
5g
Price
$51.65
Updated
2024/03/01
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Bis(2-oxo-3-oxazolidinyl)phosphinic chloride Chemical Properties,Usage,Production

Description

Bis(2-oxo-3-oxazolidinyl)phosphinic chloride is a reagent for activating carboxyl groups, converting acids to esters (including thioesters and phosphoesters), amides (including peptides and β-lactams), and anhydrides; reagent for kinetic resolution of racemic carboxylic acids and alcohols.

Chemical Properties

White solid

Uses

Bis(2-oxo-3-oxazolidinyl)phosphinic chloride was used in the preparation of hexadepsipeptide.

storage

Bis(2-oxo-3-oxazolidinyl)phosphinic chloride should store in a cool dry place under nitrogen to preclude contact with moisture  and oxygen. Use only in a chemical fume hood. Wear suitable protective clothing and eye/face protection.  Causes burns and is harmful if swallowed, inhaled, or absorbed through skin.

Purification Methods

the outcome of reactions can be greatly affected by the purity of the reagent; commercial samples may require to be washed with cold water and recrystallized from MeCN prior to use.

Bis(2-oxo-3-oxazolidinyl)phosphinic chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis(2-oxo-3-oxazolidinyl)phosphinic chloride Suppliers

Americas 1 Belgium 3 China 200 Europe 2 Germany 7 India 8 Japan 5 Switzerland 2 United Kingdom 11 United States 32 Global 271
Suzhou Highfine Biotech Co., Ltd
Tel
0512-68311833 13962195826
Fax
0512-68417696
Email
wuhao@highfine.com
Country
China
ProdList
498
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75
Shanghai Birch Chemical Technology Co., Ltd.
Tel
00-18017263450 18017263450
Email
sales@birchchem.com
Country
China
ProdList
517
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2338
Advantage
56
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
Advantage
57
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
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View Lastest Price from Bis(2-oxo-3-oxazolidinyl)phosphinic chloride manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride 68641-49-6
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-02-22
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride 68641-49-6
Price
US $0.00/G
Min. Order
100G
Purity
98%min
Supply Ability
30kg/month
Release date
2023-02-08
Henan Aochuang Chemical Co.,Ltd.
Product
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride 68641-49-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-26

68641-49-6, Bis(2-oxo-3-oxazolidinyl)phosphinic chlorideRelated Search:

Phosphorus oxychloride Potassium chloride Choline chloride Phosphorus oxybromide Calcium chloride Sodium chloride Ammonium chloride Acetyl chloride Polyvinyl chloride Benzyl chloride Bicyclo[1.1.1]pentane-1,3-dicarboxylic acid, MonoMethyl ester DIMETHYL-P-NITROPHENYLPHOSPHATE Methylene Chloride PARAOXON Ammonium carbonate additive AMMONIUM CARBAMATE BIS(DIMETHYLAMINO)PHOSPHORYL CHLORIDE BIS(DIMETHYLAMINO)CHLOROPHOSPHINE

  • bis(2-oxo-3-oxazolidinyl)-phosphinicchlorid
  • PHOSPHORIC ACID BIS(2-OXOOXAZOLIDIDE) CHLORIDE
  • N,N-BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHINIC CHLORIDE
  • N,N-BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHONIC CHLORIDE
  • N,N-BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHORODIAMIDIC CHLORIDE
  • Bis(2-oxo-3-oxazolid
  • Phosphoric acid bi
  • Phosphoric acid bis(2-oxooxazolidide) chloride(BOP-Cl)
  • BIS(2-OXO-3-OX
  • Bis(2-oxo-1,3-oxazolidin-3-yl)phosphinic chloride
  • N,N-Bis(2-oxo-3-oxazolidinyl)phosphinic chloride≥ 98% (Assay)
  • Bis(2-oxooxazolidin-3-yl)phosphinic chloride
  • Double(2-oxo -3-oxazolaM)phosphinic chloride
  • Bis(2-oxo-3-oxazolidinyl)phosphinic chloride >=97.0% (AT)
  • BOP-Cl Bis(2-oxo-3-oxazolidinyl)phosphonic chloride
  • Bis(2-oxo-3-oxazolidinyl)phosphinic chloride, 97% 5GR
  • Phosphinic chloride,P,P-bis(2-oxo-3-oxazolidinyl)-
  • BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHINIC CHLORIDE
  • BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHONIC CHLORIDE
  • BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHORODIAMIDIC CHLORIDE
  • BOP-CI
  • BOP-CL
  • BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHINIC CHLORIDE (BOP-CL)
  • N,N-BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHORAMIDIC CHLORIDE
  • BOP-CL BIS(2-OXO-3-OXAZOLIDINYL)PHOSPHINIC CHLORIDE
  • Bis-(2-oxo-3-oxazolidinyl)-phosphinyl chloride
  • 3,3'-(Chlorophosphinylidene)bis(oxazolidine-2-one)
  • 3,3'-(Chlorophosphonoyl)bis(oxazolidine-2-one)
  • 3,3'-(Oxochlorophosphoranylidene)bis(oxazolidine-2-one)
  • 3,3'-Chlorophosphinylidenebis(oxazolidine-2-one)
  • Bis(2-oxo-3-oxazolidinyl)chlorophosphine oxide
  • Bis(2-oxo-3-oxazolidinyl)phosphinic acidchloride
  • BOP-Cl, Phosphoric acid bis(2-oxooxazolidide) chloride
  • 3-[Chloro-(2-oxo-1,3-oxazolidin-3-yl)phosphoryl]-1,3-oxazolidin-2-one
  • BOP-C
  • BOPDC
  • Bis(2-oxo-3-oxazolidinyl)phosphinic chloride ,97%
  • Bis(2-oxo-3-oxazolidinyl)phosphinic chloride, 97%, for synthesis
  • Bis(2-oxo-3-oxazolidinyl)phosphinic Chloride &gt
  • Bis(2-oxo-3-oxazoL
  • idinyL
  • Bis(2-oxo-3-oxazolidinyl)phosphinic chloride USP/EP/BP
  • 3-[chloro-(2-oxooxazolidin-3-yl)phosphoryl]oxazolidin-2-one
  • 68641-49-6
  • C8H8ClN2O5P
  • C6H8ClN2O5P
  • Building Blocks
  • Heterocyclic Building Blocks
  • Oxazolines/Oxazolidines
  • Coupling Reactions (Peptide Synthesis)
  • Peptide Synthesis
  • Condensation & Active Esterification
  • Coupling Reagent
  • Peptide coupling agents
  • Biochemistry
  • Condensation & Active Esterification
  • Coupling Reactions (Peptide Synthesis)
  • Peptide Synthesis