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Sodium bromate

Product Name
Sodium bromate
CAS No.
7789-38-0
Chemical Name
Sodium bromate
Synonyms
BROMIDE;dyetone;SODIUM BROMATE;bromatedesodium;SodiuM broMated;neutralizerk-126;neutralizerk-140;neutralizerk-938;BROMIDE STANDARD;SODIUM BROMIDE 40
CBNumber
CB6181002
Molecular Formula
BrNaO3
Formula Weight
150.89
MOL File
7789-38-0.mol
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Sodium bromate Property

Melting point:
755 °C(lit.)
Boiling point:
1390 °C
Density 
3.339 g/mL at 25 °C (lit.)
vapor pressure 
1 mm Hg ( 806 °C)
refractive index 
1.594
storage temp. 
Store below +30°C.
solubility 
H2O: 1 M at 20 °C, clear, colorless
form 
Powder/Solid
Specific Gravity
3.34
color 
White
PH Range
5 - 9
PH
5.0-9.0 (25℃, 50mg/mL in H2O)
Water Solubility 
364 g/L (20 ºC)
Merck 
14,8593
Stability:
Stable. Oxidizer. Incompatible with finely powdered metals, alcohols, strong acids, strong reducing agents.
InChIKey
XUXNAKZDHHEHPC-UHFFFAOYSA-M
CAS DataBase Reference
7789-38-0(CAS DataBase Reference)
EPA Substance Registry System
Sodium bromate (7789-38-0)
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Safety

Hazard Codes 
O,Xn,Xi
Risk Statements 
8-22-36/37/38-9-36/37
Safety Statements 
17-26-36-37/39
RIDADR 
UN 1494 5.1/PG 2
WGK Germany 
3
RTECS 
VZ3150000
3
Hazard Note 
Oxidising Agent/Harmful
TSCA 
Yes
HS Code 
2829 90 40
HazardClass 
5.1
PackingGroup 
II
Hazardous Substances Data
7789-38-0(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 400 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H271May cause fire or explosion; strong oxidiser

H301Toxic if swalloed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.14368
Product name
Sodium bromate
Purity
for synthesis
Packaging
250g
Price
$56.3
Updated
2024/03/01
Sigma-Aldrich
Product number
8.14368
Product name
Sodium bromate
Purity
for synthesis
Packaging
1kg
Price
$80
Updated
2024/03/01
Sigma-Aldrich
Product number
8.14368
Product name
Sodium bromate
Purity
for synthesis
Packaging
7.5kg
Price
$542
Updated
2024/03/01
Sigma-Aldrich
Product number
8.14368
Product name
Sodium bromate
Purity
for synthesis
Packaging
25kg
Price
$931
Updated
2024/03/01
Sigma-Aldrich
Product number
02151
Product name
Sodium bromate
Purity
≥99%
Packaging
250g
Price
$63.2
Updated
2024/03/01
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Sodium bromate Chemical Properties,Usage,Production

Chemical Properties

Sodium bromate is a colorless or white crystalline solid. Odorless.

Chemical Properties

White crystals or powder; odorless. Soluble in water; insoluble in alcohol.

Uses

As a mixture with sodium bromide for dissolving gold from its ores.

Uses

The bromates of chief industrial interest are those of sodium and potassium. Sodium bromate is used in mixtures with sodium bromide to extract gold from ore. It is also used as an analytical reagent, as a cleaning agent for boilers, and as a component in hair-waving formulations. Potassium bromate is used primarily as a conditioner for flour and dough; some of its nonfood uses include use as an oxidizing agent for analytic chemistry and as a brominating agent. The bromates of calcium and barium have limited use as oxidizers, maturing agents in flour, and analytic reagents.

Uses

Sodium bromate is used as an oxidant to convert tetrahydropyranyl ethers to carbonyl compounds. It acts as an analytical reagent. It is also used for dissolving gold from its ores, boiler cleaning, oxidation of sulfur and vat dyes. Further, it is used in hair treatment formulations as a hair-permanent.

Definition

ChEBI: An inorganic sodium salt having bromate as the counterion.

General Description

A white crystalline solid. May explode under prolonged exposure to heat or fire. Used in chemical analysis.

Air & Water Reactions

Water soluble.

Reactivity Profile

Sodium bromate is an oxidizing agent. May react violently with combustibles and reducing agents. Reacts with textiles, oil, fat, grease, sugar, sawdust and ammonium salts, carbon, phosphorus, metal powders and sulfides with hazard of fire and explosion [Handling Chemicals Safely 1980 p. 831]. A mixture of finely divided aluminum with finely divided Sodium bromate explodes by heat, percussion, and friction [Mellor 2:310 1946-47].

Hazard

Oxidizing material, dangerous fire risk near organic materials. Toxic by ingestion.

Health Hazard

Toxic by ingestion. Inhalation of dust is toxic. Fire may produce irritating, corrosive and/or toxic gases. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

These substances will accelerate burning when involved in a fire. May explode from heat or contamination. Some may burn rapidly. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.

Safety Profile

Poison by ingestion, intravenous, subcutaneous, and intraperitoneal routes. A powerful oxidizer. Violent reactions with Al, As, C, Cu, oil, F2, metal sulfides, organic matter, P, S. lxtures with grease are shock-sensitive explosives at 120’C. When heated to decomposition it emits toxic fumes of Na2O and Br-. See also BROMATES.

Potential Exposure

Used for research and development; as an analytical reagent; for separating gold from ores; making vat dyes; boiler cleaning.

Shipping

UN1494 Sodium bromate, Hazard Class: 5.1; Labels: 5.1-Oxidizer. UN1450 Bromates, inorganic, n.o.s., Hazard Class: 5.1; Labels: 5.1-Oxidizer, Technical Name Required.

Purification Methods

It is crystallised from hot water (1.1mL/g) to decrease contamination by NaBr, bromine and hypobromite. [Noszticzius et al. J Am Chem Soc 107 2314 1985.]

Incompatibilities

Dust may form explosive mixture with air. A strong oxidizer capable of increasing the intensity of an existing fire. Can react, possibly violently, with combustible, organic, or other oxidizable materials, alcohols, glycols, reducing agents, strong acids, finely divided metals, especially aluminum. Contamination with carbon, organic matter, and finely divided metal can cause sodium bromate become shock-sensitive. Decomposes at 381C. Sodium bromate may explode in heat of fire.

Waste Disposal

SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material’s impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations. See also Sigma-Aldridge data sheet (Sodium Bromate .99%).

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Sodium bromate Suppliers

Apollo Scientific Ltd.
Tel
--
Fax
--
Email
sales@apolloscientific.co.uk
Country
United Kingdom
ProdList
6084
Advantage
88
Avonchem/Chromos Express Ltd.
Tel
--
Fax
--
Email
info@avonchem.co.uk
Country
United Kingdom
ProdList
1189
Advantage
50
Whyte Chemicals
Tel
--
Fax
--
Email
sales@whytechemicals.co.uk
Country
United Kingdom
ProdList
3748
Advantage
50
Leancare Ltd.
Tel
--
Fax
--
Email
enquiry@leancare.co.uk
Country
United Kingdom
ProdList
6446
Advantage
42
MOLEKULA Ltd.
Tel
--
Fax
--
Email
kevinbanks@molekula.com
Country
United Kingdom
ProdList
6140
Advantage
66
Eurolabs Limited
Tel
--
Fax
--
Country
United Kingdom
ProdList
6309
Advantage
46
Lansdowne Chemicals Plc
Tel
--
Fax
--
Email
robert.moss@lansdownechemicals.com
Country
United Kingdom
ProdList
576
Advantage
51
VWR International
Tel
--
Fax
--
Email
solutions@vwr.com
Country
United Kingdom
ProdList
6548
Advantage
82
Albion Chemicals Group
Tel
--
Fax
--
Country
United Kingdom
ProdList
271
Advantage
66
Fisher Scientific UK
Tel
--
Fax
--
Email
sarahr@fisher.co.uk
Country
United Kingdom
ProdList
1157
Advantage
81
Vickers Laboratories Ltd.
Tel
--
Fax
--
Country
United Kingdom
ProdList
776
Advantage
42
Contract Chemicals, Ltd.
Tel
--
Fax
--
Country
United Kingdom
ProdList
89
Advantage
64
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View Lastest Price from Sodium bromate manufacturers

Hebei Jingbo New Material Technology Co., Ltd
Product
Sodium bromate 7789-38-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99.5%
Supply Ability
1000000
Release date
2023-11-12
Hebei Yanxi Chemical Co., Ltd.
Product
Sodium bromate 7789-38-0
Price
US $20.00-1.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-11-07
Hebei Chuanghai Biotechnology Co,.LTD
Product
Sodium Bromate 7789-38-0
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000kg
Release date
2024-08-22

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