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ChemicalBook > CAS DataBase List > 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride

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Product Name
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
CAS No.
29964-62-3
Chemical Name
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
Synonyms
PDCI2(DPPB);PdCl2(dppb);adium(II) DichL;[1,4-Bis(diphenyL;phosphino)butane]paL;Palladium(ii) chloride 1,4-b;[(C6H5)2PCH2CH2CCH2H2P(C6H5)2]PdCl2;Bisdiphenylphosphinobutanepalladiumdichloride;[1,4-bis(diphenylphosphino)butane] palladium(II);4-diphenylphosphiniumylbutyl(diphenyl)phosphonium
CBNumber
CB6185262
Molecular Formula
C28H28P2.Cl2Pd
Formula Weight
603.8
MOL File
29964-62-3.mol
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1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Property

Melting point:
285-305 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Soluble in ethanol, benzene, and ethereal solvents.
form 
Powder
color 
light-yellow
InChIKey
JQXJBXVWVPVTOO-UHFFFAOYSA-L
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Safety

Hazard Codes 
Xn
Risk Statements 
36/37/38
Safety Statements 
24/25-36-27
WGK Germany 
3
F 
1-10
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B2031
Product name
[1,4-Bis(diphenylphosphino)butane]palladium(II) Dichloride
Purity
>96.0%(T)
Packaging
1g
Price
$125
Updated
2024/03/01
TCI Chemical
Product number
B2031
Product name
[1,4-Bis(diphenylphosphino)butane]palladium(II) Dichloride
Purity
>96.0%(T)
Packaging
5g
Price
$401
Updated
2024/03/01
Alfa Aesar
Product number
044971
Product name
Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II), Pd 17.6%
Packaging
1g
Price
$197
Updated
2024/03/01
Alfa Aesar
Product number
044971
Product name
Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II), Pd 17.6%
Packaging
5g
Price
$709.65
Updated
2024/03/01
Strem Chemicals
Product number
46-0468
Product name
Dichloro[1,4-bis(diphenylphosphino)butane]palladium(II), 99%
Packaging
1g
Price
$120
Updated
2024/03/01
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1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Chemical Properties,Usage,Production

Reaction

  1. Catalyst for the Grignard coupling for regioand stereoselective monoalkylation and arylation of 1,1-dichloro-1-alkenes
  2. Synthetic pyrethriods: catalyst for the Negishi coupling of (2,2-dihaloethenyl)cyclopropanecarboxylates

Chemical Properties

yellow solid

Uses

Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II) is used for the catalysis of styrene carbonylation, coupling of alkyl Grignard reagents with organic halides, selective monoalkylation of organic polyhalides, and modification of the dihalovinyl moiety of synthetic pyrethroids.

Preparation

Dichloro[1,4-bis(diphenylphosphino)butane]palladium(II) (1,4-Bis(diphenylphosphino)butane-palladium(II) chloride) can be prepared conveniently in situ by mixing the bidentate phosphine ligand and (PhCN)2PdCl2 in either benzene or chloroform.[1] The preparation of (dppb)PdCl2 is also possible through the reaction of PdCl2 with dppb in acetone, a process that slowly forms the catalyst as a white precipitate which can be isolated in 51% yield.[2] Preparation of the hydrate complex is possible via the reaction of Na2[PdCl4] with dppb in a mixture of CH2Cl2 and water.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

References

1. Sugi, Y.; Bando, K.-I. CL 1976, 727.
2. Sanger, A. R. JCS(D) 1977, 1971.

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride manufacturers

Wuhan LPBchem Technology Co.,Ltd
Product
Dichloro[1,4-bis(diphenylphosphino)butane]palladium(II) 29964-62-3
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2020-12-01
Longyan Tianhua Biological Technology Co., Ltd
Product
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride 29964-62-3
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-11
Career Henan Chemical Co
Product
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride 29964-62-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100
Release date
2019-06-28

29964-62-3, 1,4-Bis(diphenylphosphino)butane-palladium(II) chlorideRelated Search:

Sodium chloride Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Diphenylphosphine Chlorodiphenylphosphine tert-Butylchlorodiphenylsilane Palladium Palladium chloride N-(Carboxymethyl)-N-(phosphonomethyl)-glycine Methylene Chloride 1,4-Bis(diphenylphosphino)butane (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE Phenyl phosphine N-BUTANE DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride CIS-DICHLOROBIS(DIMETHYLPHENYLPHOSPHINE)PALLADIUM(II) 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile

  • Palladium(ii) chloride 1,4-b
  • 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride,98+%
  • Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II), Palladium(II) chloride 1,4-bis(diphenylphosphino)butane complex
  • Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II), Pd 17.6%
  • 1,4-Butylenebis(diphenylphosphine)-palladium dichloride
  • Dichloro[1,4-bis(diphenylphosphino)butane]palladium (II) ,98%
  • 4-Bis(diphenylphosphino)butane-palladiuM(II) chloride
  • PDCI2(DPPB)
  • 1,4- double(twophenyl phosphinebutane)twopalladiuM chloride
  • [(C6H5)2PCH2CH2CCH2H2P(C6H5)2]PdCl2
  • 1,4-bis (diphenylphosphino butane) palladiuM dichloride
  • 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II)
  • [1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride
  • [1,4-Bis(diphenylphosphino) butane]dichloropalladium(II)
  • PdCl2(dppb) / dichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane
  • 4-diphenylphosphiniumylbutyl(diphenyl)phosphonium
  • PdCl2(dppb)
  • dichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane
  • DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]PALLADIUM(II)
  • 1,4-BIS(DIPHENYLPHOSPHINE)BUTANE PALLADIUM(II) CHLORIDE
  • 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE-PALLADIUM(II) CHLORIDE
  • [1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]PALLADIUM(II) DICHLORIDE
  • PALLADIUM(II) CHLORIDE 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE COMPLEX
  • Bisdiphenylphosphinobutanepalladiumdichloride
  • PDCL2(DPPB)/ 1,4-BIS(DIPHENYLPHOSPHINE)BUTANE PALLADIUM(II)CHLORIDE
  • Palladium(II)chloride-1,4-bis(diphenylphosphine)butane
  • Dichloro 1,4-bis(diphenylphosphino)butane palladium (II) For use in coupling reactions
  • Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II),PdCl2(DPPB)
  • Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II)
  • [1,4-Bis(diphenylphosphino)butane]palladium(II) Dichloride &gt
  • [1,4-Bis(diphenylphosphino)butane]dichloropalladium(Ⅱ)
  • [1,4-bis(diphenylphosphino)butane] palladium(II)
  • [1,4-Bis(diphenyL
  • adium(II) DichL
  • phosphino)butane]paL
  • 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride ISO 9001：2015 REACH
  • TIANFU-CHEM --1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
  • ichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane
  • 29964-62-3
  • C28H28Cl2P2Pd
  • C28H28Cl2P2Pd2
  • C28H28P2Cl2Pd
  • Homogeneous Pd Catalysts
  • Catalysis and Inorganic Chemistry
  • Homogeneous Catalysts
  • Pd (Palladium) Compounds
  • Metal Complexes
  • Classes of Metal Compounds
  • Catalysts for Organic Synthesis
  • Transition Metal Compounds
  • Pd (Palladium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Metal Compounds