ChemicalBook > CAS DataBase List > Stannous chloride

Stannous chloride

Product Name
Stannous chloride
CAS No.
7772-99-8
Chemical Name
Stannous chloride
Synonyms
SnCl2;STANNOUS CHLORIDE;TIN CHLORIDE;TIN(II) CHLORIDE;TIN DICHLORIDE;Anhydrous stannous chloride;Stannous chloride hydrate;Tin(II) chloride, anhydrous, 99% min;ci77864;Tin salt
CBNumber
CB6190048
Molecular Formula
Cl2Sn
Formula Weight
189.62
MOL File
7772-99-8.mol
More
Less

Stannous chloride Property

Melting point:
246 °C(lit.)
Boiling point:
652 °C(lit.)
Density 
3.95
vapor pressure 
0Pa at 20℃
Flash point:
652°C
storage temp. 
Store below +30°C.
solubility 
H2O: soluble
form 
powder
color 
White
Specific Gravity
3.95
PH
2.0 (100g/l, H2O, 20℃)
Water Solubility 
Soluble in water, alkalies, alcohol, methyl ethyl ketone, methyl acetate and acetone.
Sensitive 
Air Sensitive & Hygroscopic
Crystal Structure
PbCl2 type
crystal system
Nogata
Merck 
14,8783
Space group
Pnma
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.7790.4430.9219090900.318
Exposure limits
ACGIH: TWA 2 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 2 mg/m3
Stability:
Stable, but moisture sensitive. Incompatible with strong bases, strong oxidizing agents, reactive metals, hydrogen peroxide, water.
InChIKey
AXZWODMDQAVCJE-UHFFFAOYSA-L
LogP
-2.15 at 20℃
CAS DataBase Reference
7772-99-8(CAS DataBase Reference)
EPA Substance Registry System
Tin dichloride (7772-99-8)
More
Less

Safety

Hazard Codes 
C,Xi,N
Risk Statements 
22-34-36/37/38-37-68-50/53-48/22-43-20-63
Safety Statements 
26-36/37/39-45-61-60-53
RIDADR 
UN 3260 8/PG 3
WGK Germany 
1
RTECS 
XP8700000
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
28273990
Hazardous Substances Data
7772-99-8(Hazardous Substances Data)
Toxicity
LD50 in mice, rats (mg/kg): 1710.0, 2000.0 orally; 271.0, 316.0 i.p.; 34.8, 43.0 i.v. (Singh, Junnarkar)
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H335May cause respiratory irritation

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
204722
Product name
Tin(II) chloride
Purity
≥99.99% trace metals basis
Packaging
10g
Price
$204
Updated
2024/03/01
Sigma-Aldrich
Product number
204722
Product name
Tin(II) chloride
Purity
≥99.99% trace metals basis
Packaging
50g
Price
$742
Updated
2024/03/01
Sigma-Aldrich
Product number
908924
Product name
Tin(II) chloride
Purity
free-flowing, Redi-Dri?, reagent grade, 98%
Packaging
100G
Price
$82.9
Updated
2022/05/15
Sigma-Aldrich
Product number
908924
Product name
Tin(II) chloride
Purity
free-flowing, Redi-Dri?, reagent grade, 98%
Packaging
500G
Price
$233
Updated
2022/05/15
Sigma-Aldrich
Product number
8.18150
Product name
Tin(II) chloride
Purity
anhydrous for synthesis
Packaging
100G
Price
$73.3
Updated
2022/05/15
More
Less

Stannous chloride Chemical Properties,Usage,Production

Chemical Properties

Stannous chloride is a white crystalline solid.

Chemical Properties

Also known as tin chloride, tin crystals, tin dichloride and tin salts, SnCl2 is white crystals, soluble in water, alcohol, and alkalies, oxidized in air to the oxychloride, that melt at 247°C. Used as a chemical intermediate, reducing agent, and ink-stain remover, and for silvering mirrors.

Physical properties

White orthogonal crystal; density 3.90 g/cm3; melts at 247°C; vaporizes at 623°C; vapor pressure 1 torr at 316°C, 5 torr at 366°C and 20 torr at 420°C; soluble in water, ethanol, acetone and ether; insoluble in xylene and mineral spirits.
TIN(II) CHLORIDE 937The dihydrate, SnCl2•2H2O, is a white monoclinic crystalline substance; density 2.71 g/cm3; absorbs oxygen from air forming an oxychloride; melts at 37°C on rapid heating; decomposes on strong heating; very soluble in water; forms an insoluble basic salt with excess water; very soluble in hydrochloric acid; soluble in caustic soda solution, ethanol and ethyl acetate.

Uses

Tin (II) chloride is a strong reducing agent and is used in many industrial processes, such as manufacturing dyes, phosphors, and polymers. The compound is a major ingredient in acid tin plating baths. Other uses are a mordant in dyeing; an additive to lubricating oil to prevent sludging; a stablizier for perfume in soaps; in removing ink stains; a sensitizing agent for glass, paper, and plastics; and a soldering flux. Tin(II) chloride is used for preparing a number of tin(II) salts. It is a catalyst in many organic reactions. It is a common laboratory reagent.

Uses

Stannous Chloride is an antioxidant and preservative that exists as white or colorless crystals, being very soluble in water. it reacts read- ily with oxygen, preventing its combination with chemicals and foods which would otherwise result in discoloration and undesirable odors. it is used for color retention in asparagus at less than 20 ppm. it is also used in carbonated drinks.

Uses

Synthesis of tin(IV) octaethylcorroles was accomplished with this reagent. These new compounds exhibit reversible oxidation only at the conjugated ring system, not at the metal center.1

Definition

ChEBI: An inorganic chloride that has formula Cl2Sn.

Preparation

Tin(II) chloride is prepared by dissolving tin in hydrochloric acid followed by evaporation of the solution and crystallization.

General Description

Crystalline mass or flaky solid with a fatty appearance. Density 3.95 g / cm3. Melting point 247°C. Burns, but may be difficult to ignite. Toxic by ingestion. Irritates skin and eyes. Used in the manufacture of dyes, pharmaceuticals and as a tanning agent.

Air & Water Reactions

Water soluble.

Reactivity Profile

STANNOUS CHLORIDE is a powerful reducing agent. Can react violently with oxidizing agents. Undergoes flaming reaction with bromine trifluoride [Mellor 2 Supp. 1:164 1956]. Catalyzes the exothermic rearrangement and polymerization of ethylene oxide [J. Soc. Chem. Ind. 68:179 1949]. Mixtures with calcium carbide can be ignited with a match, and the reaction proceeds with incandescence [Mellor 7:430 1946-47]. Reacts with hydrazine hydrate to give stannous dihydrazine chloride which decomposes explosively when heated [Mellor 7:430 1946-47]. Undergoes a strongly exothermic reaction with aqueous solutions of hydrogen peroxide having concentration exceeding 3%) [Chem. & Ind., 1949, 657].

Hazard

Irritant to skin, use in foods restricted to 0.0015%, as tin.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Safety Profile

Poison by ingestion, intraperitoneal, intravenous, and subcutaneous routes. Experimental reproductive effects. Human mutation data reported. Potentially explosive reaction with metal nitrates. Violent reactions with hydrogen peroxide, ethylene oxide, hydrazine hydrate, nitrates, K, Na. Ignition on contact with bromine trifluoride. A vigorous reaction with calcium acetylide is initiated by flame. When heated to decomposition it emits toxic fumes of Cl-. See also TIN COMPOUNDS.

Potential Exposure

Stannous chloride is used as a dye, pigment, and printing ink; in making chemicals; chemical preservatives; food additives; polymers, textiles, glass, silvering mirrors.

Shipping

UN3260 Corrosive solid, acidic, inorganic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.

Purification Methods

Analytical reagent grade stannous chloride dihydrate is dehydrated by adding it slowly to vigorously stirred, redistilled acetic anhydride (120g salt per 100g of anhydride) in a fume cupboard. After ca an hour, the anhydrous SnCl2 is filtered on to a sintered-glass or Büchner funnel, washed free from acetic acid with dry Et2O (2 x 30mL), and dried under vacuum. It is stored in a sealed container. [Stephen J Chem Soc 2786 1930, Williams Org Synth Coll Vol III 627 1955.]

Incompatibilities

A strong reducing agent. Reacts violently with oxidants. Reacts violently with bromine trifluoride; potassium, hydrazine hydrate, sodium, sodium peroxide; ethylene oxide; and nitrates. Keep away from moisture, sources of oxygen, and combustible materials.

Stannous chloride Preparation Products And Raw materials

Raw materials

Tin Chlorine Hydrochloric acid

Preparation Products

2-Aminoquinoline 5-Amino-2,3-dichloropyridine Stannous octoate Oxibendazole PYRIDAZINE-3,4-DIAMINE 5-AMINO-4,6-DIHYDROXYPYRIMIDINE 4-Aminobenzotrifluoride Rhodamine 6G 2-[3-(2-FURYL)PHENYL]-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE 4-(4-AMINOPHENYL)MORPHOLIN-3-ONE 3-AMINO-6-CHLORO-4-PICOLINE 4-Aminobenzamidine dihydrochloride H-GLY-AMC HBR Bathophenanthroline Dimidium bromide 5-BROMO-2-BENZOXAZOLINONE 97 3-Amino-6-chloropyridine-2-carboxylic acid Disodium stannous citrate 5-AMINO-2-CHLORO-NICOTINIC ACID Stannous sulfate 3,6-DICHLORO-4-HYDROXYPYRIDINE-2-CARBOXYLIC ACID 2,3-DIAMINO-6-CHLOROPYRIDINE 7-Hydroxygranisetron 3-HYDRAZINOPYRIDINE Dihydrochloride 5-ACETYLAMINO-2-CHLORO-4-PICOLINE 5-AMINO-1-(4-CHLOROPHENYL)-1H-PYRAZOLE-4-CARBONITRILE 2-Amino-4-bromophenol 2-CHLORO-5-FLUOROISONICOTINIC ACID
More
Less

Stannous chloride Suppliers

Belgium 1 China 309 Europe 3 France 1 Germany 4 India 37 Japan 6 Singapore 1 Slovakia 1 Switzerland 1 United Kingdom 9 United States 46 USA 1 Global 420
HBCChem, Inc.
Tel
+1-510-219-6317
Fax
+1-650-486-1361
Email
sales@hbcchem.com
Country
United States
ProdList
10648
Advantage
60
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
52925
Advantage
58
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
United States Biological
Tel
--
Fax
--
Email
sales@advtechind.com
Country
United States
ProdList
6075
Advantage
58
Alfa Chemistry
Tel
--
Fax
--
Email
info@Alfa-Chemistry.com
Country
United States
ProdList
6814
Advantage
0
CarboMer, Inc.
Tel
--
Fax
--
Email
sales@carbomer.com
Country
United States
ProdList
4026
Advantage
67
Abblis Chemicals LLC
Tel
--
Fax
--
Email
info@abblis.com
Country
United States
ProdList
1272
Advantage
0
Miles Chemical
Tel
--
Fax
--
Email
cs@mileschemical.com
Country
United States
ProdList
402
Advantage
58
Allan Chemical Corporation
Tel
--
Fax
--
Email
info@allanchem.com
Country
United States
ProdList
147
Advantage
58
Sarchem Laboratories, Inc.
Tel
--
Fax
--
Email
info@sarchemlabs.com
Country
United States
ProdList
736
Advantage
58
Skyline Chemical Corp.
Tel
--
Fax
--
Email
sales@skylinechemical.com
Country
United States
ProdList
52
Advantage
58
Noah Chemicals
Tel
--
Fax
--
Email
solutions@noahtech.com
Country
United States
ProdList
881
Advantage
58
Combi-Blocks Inc.
Tel
--
Fax
--
Email
sales@combi-blocks.com
Country
United States
ProdList
6618
Advantage
69
GFS Chemicals Inc
Tel
--
Fax
--
Email
service@gfschemicals.com
Country
United States
ProdList
2329
Advantage
58
Strem Chemicals, Inc.
Tel
--
Fax
--
Email
info@strem.com
Country
United States
ProdList
4910
Advantage
86
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
Santa Cruz Biotechnology, Inc.
Tel
--
Fax
--
Email
scbt@scbt.com
Country
United States
ProdList
3597
Advantage
60
Labseeker Inc
Tel
--
Fax
--
Email
marketing@labseeker.com
Country
United States
ProdList
1495
Advantage
55
Sisco Research Laboratories Pvt. Ltd.
Tel
--
Fax
--
Email
srlmarketing@dishnetdsl.net
Country
United States
ProdList
1905
Advantage
64
HBCChem Inc.
Tel
--
Fax
--
Email
sales@hbcchem-inc.com
Country
United States
ProdList
4569
Advantage
30
ProChem, Inc.
Tel
--
Fax
--
Email
prochem1@aol.com
Country
United States
ProdList
1691
Advantage
66
Advanced Synthesis Technologies
Tel
--
Fax
--
Email
sales@advancedsynthesis.com
Country
United States
ProdList
4775
Advantage
61
Gelest, Inc.
Tel
--
Fax
--
Email
info@gelest.com
Country
United States
ProdList
3973
Advantage
84
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
United States
ProdList
6814
Advantage
81
Chem-Impex International, Inc.
Tel
--
Fax
--
Country
United States
ProdList
6730
Advantage
64
Naugra Export
Tel
--
Fax
--
Country
United States
ProdList
1332
Advantage
47
Advance Scientific & Chemical
Tel
--
Fax
--
Email
sales@advance-scientific.com
Country
United States
ProdList
6419
Advantage
71
City Chemical LLC
Tel
--
Fax
--
Email
sales@citychemical.com
Country
United States
ProdList
6708
Advantage
72
Lab Express
Tel
--
Fax
--
Email
sales@labexpress.com
Country
United States
ProdList
1577
Advantage
67
Loba Chemie Pvt. Ltd.
Tel
--
Fax
--
Country
United States
ProdList
1945
Advantage
71
Charkit Chemical Corporation
Tel
--
Fax
--
Email
sales@charkit.com
Country
United States
ProdList
2993
Advantage
65
Pfaltz & Bauer, Inc.
Tel
--
Fax
--
Email
sales@pfaltzandbauer.com
Country
United States
ProdList
6828
Advantage
72
GFS Chemicals
Tel
--
Fax
--
Email
gfschem@gfschemicals.com
Country
United States
ProdList
3403
Advantage
75
City Chemicals Corporation
Tel
--
Fax
--
Country
United States
ProdList
6460
Advantage
72
Penta Manufacturing Company
Tel
--
Fax
--
Email
sales@pentamfg.com
Country
United States
ProdList
5076
Advantage
65
Eastern Chemical Corp.
Tel
--
Fax
--
Email
eastern@u-g.com
Country
United States
ProdList
2786
Advantage
34
Ricca Chemical Company
Tel
--
Fax
--
Country
United States
ProdList
363
Advantage
68
Fisher Scientific
Tel
--
Fax
--
Email
sales@fishersci.com
Country
United States
ProdList
2337
Advantage
86
Aithaca Chemical Corp.
Tel
--
Fax
--
Email
sales@aithaca.com
Country
United States
ProdList
1684
Advantage
30
Anilax Enterprises Incorporated
Tel
--
Fax
--
Country
United States
ProdList
712
Advantage
68
MATERION Inc.
Tel
--
Fax
--
Email
AdvancedMaterials@Materion.com
Country
United States
ProdList
1079
Advantage
74
MV Laboratories, Inc.
Tel
--
Fax
--
Email
info@mvlaboratories.com
Country
United States
ProdList
581
Advantage
42
Pechiney
Tel
--
Fax
--
Email
chemicals@pechiney.com
Country
United States
ProdList
606
Advantage
55
Spectrum Chemicals & Laboratory Products
Tel
--
Fax
--
Email
sales@spectrumchemical.com
Country
United States
ProdList
6699
Advantage
77
MP Biomedicals, Inc.
Tel
--
Fax
--
Country
United States
ProdList
6561
Advantage
81
Hach Company, Inc.
Tel
--
Fax
--
Email
orders@hach.com
Country
United States
ProdList
404
Advantage
81
More
Less

View Lastest Price from Stannous chloride manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
STANNOUS CHLORIDE 7772-99-8
Price
US $58.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000kg/week
Release date
2024-05-22
Hebei Chuanghai Biotechnology Co,.LTD
Product
STANNOUS CHLORIDE 7772-99-8
Price
US $5.60/KG
Min. Order
1KG
Purity
99%
Supply Ability
5000kg
Release date
2024-08-09
Hebei Weibang Biotechnology Co., Ltd
Product
STANNOUS CHLORIDE 7772-99-8
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-11-16

7772-99-8, Stannous chlorideRelated Search:

SCANDIUM CHLORIDE BARIUM BROMIDE Calcium chloride Sodium tetraborate CALCIUM SULFATE Chromium(III) chloride Lithium iodide Magnesium sulfate Potassium silicate Magnesium bromide Citric acid RUTHENIUM (III) IODIDE Sodium sulfite Trisodium phosphate Sodium phosphate monobasic Lithium chloride Magnesium chloride Lithium bromide

  • Anhydrous stannous chloride
  • C.I. 77864
  • c.i.77864
  • STANNOUS CHLORIDE ANHYDROUS, 99.99+%
  • tin atomic spectroscopy standard concentrate 1.00 g sn
  • tin(ii) chloride solution
  • tin(ii) chloride, ultra dry
  • STANNOUSCHLORIDE,ANHYDROUS,REAGENT
  • STANNOUS(II)CHLORIDE
  • Zinn(II)-chlorid
  • Tin(II) chloride, anhydrous, 99% min
  • Tin(II) chloride hydrate, Puratronic(R), 99.995% (metals basis)
  • Stannous chloride: (Tin(II) chloride (1:2))
  • STANNOUS CHLORIDE pure
  • Dichlorotin(II)
  • Stannous Chloride, Dihydrate, Crystal, Reagent
  • Tin dichloride, anhydrous
  • Tin(II) chloride,98%,anhydrous
  • Tin atomic spectroscopy standard concentrate 1.00 g Sn,Tin(II) chloride solution
  • Niklad 261
  • Stannum dichloride
  • Tin(II) chloride, anhydrous, 98% 100GR
  • Tin(II) chloride, anhydrous, 98% 25GR
  • Tin(II) chloride, anhydrous, 98% 500GR
  • Tin(Ⅱ)Chloride
  • Stannous Chloride anhydrous (SnCl2)
  • Tin(II) chloride, anhydrous 98%
  • chlorured’etain(ii)
  • ci77864
  • dichlorotin
  • Fascat 2004
  • NCI-C02722
  • nci-co2722
  • Single muriate of tin
  • SnCl2
  • stannouschloride(anhydrous)
  • Stannouschloride,anhydrous
  • stannouschloride,solid
  • stannousdichloride
  • Tin (II) chloride anhydrous
  • Tin chloride (SnCl2)
  • Tin crystals
  • Tin protochloride
  • Tin salt
  • Tin salts
  • Tin(ii) chloride (1:2)
  • tin(ii)chloride(1:2)
  • tinchloride(sncl2)
  • tinprotochloride
  • unistoncr-ht200
  • STANNOUS CHLORIDE
  • STANNOUS CHLORIDE, ACID, STRONGER
  • STANNOUS CHLORIDE REAGENT I
  • STANNOUS CHLORIDE REAGENT II
  • TIN(+2)CHLORIDE
  • TIN CHLORIDE
  • TIN DICHLORIDE
  • TIN(II) CHLORIDE