TERT-BUTYL-(2-IODO-ETHOXY)-DIMETHYL-SILANE
- Product Name
- TERT-BUTYL-(2-IODO-ETHOXY)-DIMETHYL-SILANE
- CAS No.
- 101166-65-8
- Chemical Name
- TERT-BUTYL-(2-IODO-ETHOXY)-DIMETHYL-SILANE
- Synonyms
- DK442;DKSI024;DKFELEX0093;tert-Butyl(2-iodoethoxy);Short-butyl-(2-iodoethoxy)dimethylsilane;TERT-BUTYL-(2-IODO-ETHOXY)-DIMETHYL-SILANE;1-Iodo-2-(tert-butyldimethylsilyloxy)ethane;1-(tert-Butyldimethylsilyloxy)-2-iodoethane;(1,1-DIMETHYLETHYL)(2-IODOETHOXY)DIMETHYL-SILANE;Silane,(1,1-dimethylethyl)(2-iodoethoxy)dimethyl-
- CBNumber
- CB62452890
- Molecular Formula
- C8H19IOSi
- Formula Weight
- 286.23
- MOL File
- 101166-65-8.mol
TERT-BUTYL-(2-IODO-ETHOXY)-DIMETHYL-SILANE Property
- Boiling point:
- 210℃
- Density
- 1.291
- refractive index
- 1.48
- Flash point:
- 81℃
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- clear liquid
- color
- Colorless to Yellow to Orange
- InChI
- InChI=1S/C8H19IOSi/c1-8(2,3)11(4,5)10-7-6-9/h6-7H2,1-5H3
- InChIKey
- CAAUZMMMFDVBFD-UHFFFAOYSA-N
- SMILES
- [Si](C(C)(C)C)(OCCI)(C)C
Safety
- HS Code
- 2931.90.9010
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H227Combustible liquid
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- B5885
- Product name
- tert-Butyl(2-iodoethoxy)dimethylsilane
- Packaging
- 1G
- Price
- $41
- Updated
- 2025/07/31
- Product number
- B810955
- Product name
- tert-Butyl(2-iodoethoxy)dimethylsilane
- Packaging
- 50mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- 214589
- Product name
- tert-Butyl(2-iodoethoxy)dimethylsilane
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $20
- Updated
- 2021/12/16
- Product number
- 089725
- Product name
- tert-Butyl(2-iodoethoxy)dimethylsilane
- Purity
- 95+%
- Packaging
- 1g
- Price
- $52
- Updated
- 2021/12/16
- Product number
- J94805
- Product name
- tert-Butyl(2-iodoethoxy)dimethylsilane
- Packaging
- 5g
- Price
- $160
- Updated
- 2021/12/16
TERT-BUTYL-(2-IODO-ETHOXY)-DIMETHYL-SILANE Chemical Properties,Usage,Production
Synthesis
624-76-0
18162-48-6
101166-65-8
(i) Preparation of tert-butyl-(2-iodoethoxy)dimethylsilane To a stirred solution of 2-iodoethanol (17.2 g, 100 mmol) and imidazole (8.17 g, 120 mmol) in dichloromethane (100 mL) was slowly added tert-butyldimethylmethylsilyl chloride (15.83 g, 105 mmol) at a controlled rate of addition to maintain the reaction temperature at no more than 30 °C. The reaction was carried out by stirring the mixture for 17 hours. After addition, the reaction mixture was continued to be stirred for 17 hours. Upon completion of the reaction, the organic phase was washed sequentially with water (2 x 50 mL) and brine (50 mL), followed by drying with anhydrous magnesium sulfate. The solvent was evaporated under reduced pressure to afford the colorless liquid-like product tert-butyl-(2-iodoethoxy)dimethylsilane (28.0 g, 97.8 mmol, 98% yield). 1H-NMR (400 MHz, CDCl3): δ = 3.83 (t, 2H, J = 7.0 Hz), 3.20 (t, 2H, J = 7.0 Hz), 0.90 (s, 9H), 0.08 (s, 6H) ppm.
References
[1] Chemistry - A European Journal, 2017, vol. 23, # 5, p. 1157 - 1165
[2] Analytical Chemistry, 2003, vol. 75, # 21, p. 6002 - 6010
[3] Patent: US2013/59970, 2013, A1. Location in patent: Paragraph 0311; 0312; 0313
[4] Patent: US2014/249162, 2014, A1. Location in patent: Paragraph 0234
[5] Patent: EP2781519, 2014, A1. Location in patent: Paragraph 0232
TERT-BUTYL-(2-IODO-ETHOXY)-DIMETHYL-SILANE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from TERT-BUTYL-(2-IODO-ETHOXY)-DIMETHYL-SILANE manufacturers
- Product
- TERT-BUTYL-(2-IODO-ETHOXY)-DIMETHYL-SILANE 101166-65-8
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.00%
- Supply Ability
- 1000KG /month
- Release date
- 2021-11-26
- Product
- TERT-BUTYL-(2-IODO-ETHOXY)-DIMETHYL-SILANE 101166-65-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 97%
- Supply Ability
- 200kg
- Release date
- 2020-02-01