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Tert-Butyl 4-(bromomethyl)phenylcarbamate

Product Name
Tert-Butyl 4-(bromomethyl)phenylcarbamate
CAS No.
239074-27-2
Chemical Name
Tert-Butyl 4-(bromomethyl)phenylcarbamate
Synonyms
tert-Butyl (4-(bromomethyl);N-Boc-4-(broMoMethyl)aniline;4-(Bromomethyl)aniline, N-BOC protected;TERT-BUTYL 4-(BROMOMETHYL)PHENYLCARBAMATE;tert-butyl N-[4-(bromomethyl)phenyl]carbamate;4-(1,1-dimethylethoxycarbonylamino)benzylbromide;(4-Bromomethyl)phenyl]carbamic acid tert-butyl ester;Carbamic acid, [4-(bromomethyl)phenyl]-, 1,1-dimethylethyl e...;Carbamic acid, [4-(bromomethyl)phenyl]-, 1,1-dimethylethyl ester;Carbamic acid, N-[4-(bromomethyl)phenyl]-, 1,1-dimethylethyl ester
CBNumber
CB62459172
Molecular Formula
C12H16BrNO2
Formula Weight
286.16
MOL File
239074-27-2.mol
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Tert-Butyl 4-(bromomethyl)phenylcarbamate Property

Boiling point:
309.7±25.0 °C(Predicted)
Density 
1.376±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
13.49±0.70(Predicted)
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Safety

HS Code 
2921490090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

TRC
Product number
B201058
Product name
N-Boc-4-(Bromomethyl)aniline
Packaging
100mg
Price
$60
Updated
2021/12/16
AK Scientific
Product number
J55812
Product name
tert-Butyl4-(bromomethyl)phenylcarbamate
Packaging
1g
Price
$115
Updated
2021/12/16
AK Scientific
Product number
7355AJ
Product name
tert-Butyl4-(bromomethyl)phenylcarbamate
Packaging
1g
Price
$151
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0373079
Product name
TERT-BUTYL-4-(BROMOMETHYL)PHENYLCARBAMATE
Purity
95.00%
Packaging
5MG
Price
$498.97
Updated
2021/12/16
Crysdot
Product number
CD12092937
Product name
tert-Butyl(4-(bromomethyl)phenyl)carbamate
Purity
95%
Packaging
10g
Price
$559
Updated
2021/12/16
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Tert-Butyl 4-(bromomethyl)phenylcarbamate Chemical Properties,Usage,Production

Synthesis

To a 1 L round bottom flask was added (4-hydroxymethyl-phenyl)-carbamic acid tert-butyl ester (22.3 g, 0.10 mol) obtained from Examples 2pp through 2ooo, Step 1, dichloromethane (400 mL) and triphenylphospine (31.5 g, 0.12 mol). Upon cooling to 0 °C, N-bromosuccinimide (19.6 g, 0.11 mmol) was added in small portions, and the reaction was allowed to warm to room temperature and stirred under nitrogen for 1 h. The mixture was transferred into a large flask, and hexanes were added until the solution became turbid. The solution was eluted through a plug of silica (300 g) with 1:9 ethyl acetate: hexanes and concentrated to yield Tert-Butyl 4-(bromomethyl)phenylcarbamate (12.8 g, 0.057 mol, 57 percent) as a white solid.

References

[1] Journal of Medicinal Chemistry, 2015, vol. 58, # 23, p. 9354 - 9370
[2] Patent: WO2006/31806, 2006, A2. Location in patent: Page/Page column 99
[3] Journal of Medicinal Chemistry, 1989, vol. 32, # 4, p. 811 - 826

Tert-Butyl 4-(bromomethyl)phenylcarbamate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Tert-Butyl 4-(bromomethyl)phenylcarbamate manufacturers

Shanghai Rlavie Technology Co ltd
Product
N-Boc-4-(bromomethyl)aniline 239074-27-2
Price
US $0.00-0.00/KG
Min. Order
1g
Purity
98%min
Supply Ability
100kgs/month
Release date
2021-11-20
Honest Joy Holdings Limited
Product
tert-Butyl 4-(bromomethyl)phenylcarbamate 239074-27-2
Price
US $0.00/KG
Min. Order
1KG
Purity
97.7%
Supply Ability
100 tons
Release date
2022-01-26
Career Henan Chemical Co
Product
TERT-BUTYL 4-(BROMOMETHYL)PHENYLCARBAMATE 239074-27-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500kg
Release date
2019-12-26

239074-27-2, Tert-Butyl 4-(bromomethyl)phenylcarbamateRelated Search:

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  • Carbamic acid, [4-(bromomethyl)phenyl]-, 1,1-dimethylethyl ester
  • TERT-BUTYL 4-(BROMOMETHYL)PHENYLCARBAMATE
  • Carbamic acid, N-[4-(bromomethyl)phenyl]-, 1,1-dimethylethyl ester
  • 4-(1,1-dimethylethoxycarbonylamino)benzylbromide
  • tert-Butyl (4-(bromomethyl)
  • tert-butyl N-[4-(bromomethyl)phenyl]carbamate
  • N-Boc-4-(broMoMethyl)aniline
  • Carbamic acid, [4-(bromomethyl)phenyl]-, 1,1-dimethylethyl e...
  • (4-Bromomethyl)phenyl]carbamic acid tert-butyl ester
  • 4-(Bromomethyl)aniline, N-BOC protected
  • 239074-27-2