ChemicalBook > CAS DataBase List > 1-N-Boc-2-Methylhydrazine

1-N-Boc-2-Methylhydrazine

Product Name
1-N-Boc-2-Methylhydrazine
CAS No.
127799-54-6
Chemical Name
1-N-Boc-2-Methylhydrazine
Synonyms
tert-butyl 2-methylhydrazine-1-carboxylate;tert-butyl 2-Methylhydrazinecarboxylate;1-Boc-2-methylhydrazine;N1-BOC-2-Methylhydrazine;1-N-Boc-2-Methylhydrazine;N2-BOC-N1-Methylhydrazine;tert-butyl N-(methylamino)carbamate;N'-methyl(tert-butoxy)carbohydrazide;tert-Butyl 2-methyhydrazinecarboxylate;1-(t-butyloxy)carbonyl-2-Methylhydrazine
CBNumber
CB62592972
Molecular Formula
C6H14N2O2
Formula Weight
146.19
MOL File
127799-54-6.mol
More
Less

1-N-Boc-2-Methylhydrazine Property

Melting point:
49-51℃
Density 
0.982±0.06 g/cm3 (20 ºC 760 Torr)
storage temp. 
Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
pka
10.73±0.43(Predicted)
Appearance
White to off-white Solid
InChI
InChI=1S/C6H14N2O2/c1-6(2,3)10-5(9)8-7-4/h7H,1-4H3,(H,8,9)
InChIKey
UZRUVUYVHGPEAP-UHFFFAOYSA-N
SMILES
N(C(OC(C)(C)C)=O)NC
More
Less

Safety

HS Code 
2928009090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

TRC
Product number
B812483
Product name
tert-Butyl2-methylhydrazinecarboxylate
Packaging
500mg
Price
$220
Updated
2021/12/16
Ark Pharm
Product number
AK-98717
Product name
tert-Butyl2-methylhydrazinecarboxylate
Purity
98%
Packaging
250mg
Price
$22
Updated
2021/12/16
Oakwood
Product number
224639
Product name
tert-Butyl2-methylhydrazinecarboxylate
Purity
95%
Packaging
100mg
Price
$50
Updated
2021/12/16
Oakwood
Product number
224639
Product name
tert-Butyl2-methylhydrazinecarboxylate
Purity
95%
Packaging
250mg
Price
$101
Updated
2021/12/16
Ark Pharm
Product number
AK-98717
Product name
tert-Butyl2-methylhydrazinecarboxylate
Purity
98%
Packaging
5g
Price
$165
Updated
2021/12/16
More
Less

1-N-Boc-2-Methylhydrazine Chemical Properties,Usage,Production

Synthesis

127799-53-5

127799-54-6

The general procedure for the synthesis of 1-Boc-2-methylhydrazine from 1-Cbz-2-Boc-1-methylhydrazine is as follows: 24.8 g (70.8 mmol) of 1-benzyl-2-tert-butyl-1-methylhydrazine-1,2-dicarboxylate was dissolved in 500 mL of ethanol at room temperature and standard atmospheric pressure, and 1.24 g of palladium (10% activated charcoal) was added as a catalyst for the hydrogenation reaction. Upon completion of the reaction, the reaction mixture was filtered through diatomaceous earth to remove the catalyst and the filtrate was concentrated and dried under reduced pressure to give the product. The yield was 12.3 g with a purity of 48%, representing 57% of the theoretical yield.

References

[1] Journal of the Chemical Society - Perkin Transactions 1, 1997, # 16, p. 2297 - 2311
[2] Journal of the American Chemical Society, 1993, vol. 115, # 20, p. 8898 - 8906
[3] Tetrahedron Letters, 1996, vol. 37, # 2, p. 183 - 186
[4] Patent: US5030724, 1991, A
[5] Patent: US2016/52884, 2016, A1. Location in patent: Paragraph 0599-0600

1-N-Boc-2-Methylhydrazine Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

1-N-Boc-2-Methylhydrazine Suppliers

China 88 India 2 Switzerland 1 United States 6 Global 97
https://www.shachemlin.cn/
Tel
021-68080707 18079794756
Email
soloman.lee@chemlin.com.cn
Country
China
ProdList
8473
Advantage
58
PharmaBlock Sciences (Nanjing),Inc.
Tel
025-86918202 4000255188
Fax
86-025-86918232
Email
sales@pharmablock.com
Country
China
ProdList
5000
Advantage
55
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9310
Advantage
66
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11035
Advantage
64
Chengdu HappySyn Pharmaceutical Technology Co., Ltd.
Tel
028-85114309 18982182443
Email
yangli@happysyn.com
Country
China
ProdList
2151
Advantage
55
Shijiazhuang suchen Chemical Technology Co. LTD
Tel
186-33933494 18032288352
Fax
0311-85310887
Email
1130239@qq.com
Country
China
ProdList
202
Advantage
60
Nanjing Norris-Pharm Technology Co., Ltd
Tel
18652989687
Fax
+86-25-52131256
Email
sales@norris-pharm.com
Country
China
ProdList
8878
Advantage
55
Shanghai Yolne Chemical Co., Ltd.
Tel
021-62960152
Fax
021-52212593
Email
934678158@qq.com
Country
China
ProdList
9899
Advantage
55
Aloespharm Co., Ltd.
Tel
021-20960837
Fax
021-20960837
Email
market@aloespharm.com
Country
China
ProdList
1302
Advantage
55
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Shanghai HuanChuan Industry Co.,Ltd.
Tel
021-61478794
Fax
021-61478794
Email
sales@hcshhai.com
Country
China
ProdList
9793
Advantage
50
Shanghai Song Yuan Chemical Technology Co., Ltd.
Tel
010-1234567 18521000990
Fax
86-021-33275113
Email
sonyuanchemical@163.com
Country
China
ProdList
6479
Advantage
50
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66028182 18626450290
Email
yftan@aikonchem.com
Country
China
ProdList
16679
Advantage
50
Cool Pharm, Ltd
Tel
021-60455363 18019463053
Fax
50966098
Email
sales@coolpharm.com
Country
China
ProdList
12346
Advantage
58
NovoChemy Ltd.
Tel
86-(0)21-31261262 373522135
Fax
86-(0)21-33250524
Email
sales@novochemy.com
Country
China
ProdList
6498
Advantage
58
Hubei Chuangliankangcheng Pharmaceutical Co., Ltd.
Tel
027-65388397 18164111589
Fax
027-65388397
Email
3321478047@qq.com
Country
China
ProdList
2007
Advantage
55
skychemical Co.Ltd
Tel
021-20960837,QQ1332204249
Fax
021-20960837
Email
sales@skychemical.com
Country
China
ProdList
3341
Advantage
55
TaiChem Taizhou Limited
Tel
052386810091
Email
zcwy9518@yeah.net
Country
China
ProdList
3912
Advantage
58
ShangHai Biochempartner Co.,Ltd
Tel
177-54423994 17754423994
Fax
QQ:2853530913
Email
2853530910@QQ.com
Country
China
ProdList
8000
Advantage
62
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Shanghai Kangman Biological Technology Co., Ltd.
Tel
18800375331
Fax
021-50908862
Email
kangmansales@163.com
Country
China
ProdList
7570
Advantage
55
Taian Jiaye Biotechnology Co.Ltd
Tel
13127280945
Email
285424065@qq.com
Country
China
ProdList
9976
Advantage
55
LinkChem Technology Co., Ltd.
Tel
021-58950110 13124863828
Fax
021-20922272
Email
sales@linkchem.cn
Country
China
ProdList
2998
Advantage
58
Capot Chemical Co.,Ltd.
Tel
+86-（0）57185586718; +8613336195806
Fax
+86-571-85864795
Email
sales@capot.com
Country
China
ProdList
29735
Advantage
60
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 400821072
Fax
021-58955996
Email
malulu@leyan.com
Country
China
ProdList
25000
Advantage
58
Suzhou Devi Pharma Technology Co., Ltd.
Tel
0512-66565816 18651107528
Fax
0512-66565816
Country
China
ProdList
1040
Advantage
58
Shanghai SPAR pharmaceutical technology co., LTD
Tel
021-000000 13917643586;
Email
admin@jingshipharmatech.com
Country
China
ProdList
9855
Advantage
58
Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
4009004166/18616739031 18616739031
Email
3007523370@qq.com
Country
China
ProdList
52687
Advantage
58
Shanghai Akasaka Biotechnology Co., Ltd.
Tel
15121162054
Country
CHINA
ProdList
635
Advantage
58
Suzhou Vosun Biotech Co.,Ltd
Tel
18934576691
Fax
0512-82177265
Email
yq@vosunbio.com
Country
China
ProdList
735
Advantage
58
Jinan Carbotang Biotech Co.,Ltd.
Tel
+8615866703830
Email
figo.gao@foxmail.com
Country
China
ProdList
8497
Advantage
58
Zhejiang J&C Biological Technology Co.,Limited
Tel
+1-2135480471
Email
sales@sarms4muscle.com
Country
China
ProdList
10473
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
+86-0551-65418684 +8618949823763
Fax
0086-551-65418684
Email
sales@tnjchem.com
Country
China
ProdList
25356
Advantage
58
CD Chemical Group Limited
Tel
+8615986615575
Fax
0086-13651442114
Email
info@codchem.com
Country
China
ProdList
20342
Advantage
58
Blocksynth Pharmaceutical Technology Co.,Ltd
Tel
0086-19817745290; +8619817745290
Email
bd@blocksynth.com
Country
China
ProdList
5661
Advantage
58
Shanghai Jiegu Biotechnology Co., Ltd.
Tel
021-51698675
Email
sales@jiejiegroup.com
Country
China
ProdList
8020
Advantage
58
Shanghai Kaiwei Chemical Technology Co., Ltd.
Tel
021-58461859 15821823057
Email
service@aiviche.com
Country
China
ProdList
49312
Advantage
58
career henan chemical co
Tel
+86-0371-86658258 +8613203830695
Fax
0086-371-86658258
Email
factory@coreychem.com
Country
China
ProdList
29798
Advantage
58
Shanghai Moheng Technology Co., Ltd.
Tel
15001930925
Email
sales@mohengsci.com
Country
CHINA
ProdList
424
Advantage
58
Antai Fine Chemical Technology Co.,Limited
Tel
18503026267
Email
info@antaichem.com
Country
CHINA
ProdList
9636
Advantage
58
Beijing Aomi Jiade Pharmaceutical Technology Co., Ltd
Tel
+86-13522808617
Email
omichem@126.com
Country
China
ProdList
6413
Advantage
58
Henan Weitesi Chemical Technology Co. LTD
Tel
0371-0371-55135753 18003832934
Fax
QQ：2853979818
Email
2853979818@qq.com
Country
China
ProdList
9991
Advantage
58
Chongqing Kemai Material Technology Co., Ltd
Tel
17830741407
Fax
QQ：2479150351
Email
sales@chem47.com
Country
China
ProdList
1768
Advantage
58
Energy Chemical
Tel
021-58432009 400-005-6266
Fax
021-58436166
Email
marketing1@energy-chemical.com
Country
China
ProdList
44894
Advantage
58
Shanghai Dexuan Pharmaceutical Technology Co., Ltd
Tel
1701086315
Fax
1701086315@qq.com
Email
dexuanpharma@126.com
Country
China
ProdList
9475
Advantage
58
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.
Tel
021-51816796-820 13611835272
Fax
021-5161 3951
Email
sales2@sunwaypharm.com
Country
China
ProdList
44119
Advantage
58
Shanghai Jiajie Biotechnology Co., Ltd
Tel
19542788059
Email
sales@jonellchem.com
Country
China
ProdList
425
Advantage
58
Zhengzhou Akem Chemical Co., Ltd
Tel
13303867194
Email
3001317055@qq.com
Country
China
ProdList
9681
Advantage
58
Guangzhou Yunmen Biotechnology Co., Ltd
Tel
0751-18902340975/189023400307 18902340307
Fax
0751-2819901
Email
3356812514@qq.com
Country
China
ProdList
9249
Advantage
58
More
Less

View Lastest Price from 1-N-Boc-2-Methylhydrazine manufacturers

Career Henan Chemical Co
Product
1-N-Boc-2-Methylhydrazine 127799-54-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-08

127799-54-6, 1-N-Boc-2-MethylhydrazineRelated Search:

1-Boc-2-cyanopiperidine (R)-1-Boc-2-Phenylpiperazine 1-Boc-2-Methylpiperazine tert-butyl 2,5-dihydrofuran-3-carboxylate Isopropyl-α-[2-methylhydrazino]-p-toluamide

  • 2-Methylhydrazinecarboxylic acid tert-butyl ester
  • 1-N-Boc-2-Methylhydrazine
  • 1-(t-butyloxy)carbonyl-2-Methylhydrazine
  • Hydrazinecarboxylic acid, 2-Methyl-, 1,1-diMethylethyl ester
  • 1-(t-butylo×y)carbonyl-2-Methylhydrazine
  • tert-butyl 2-Methylhydrazinecarboxylate
  • 2-Methylhydrazinecarboxylic acid tert-butyl est
  • tert-butyl 2-methylhydrazine-1-carboxylate
  • 2-Methylhydrazinecarboxylic acid,1,1-dimethylethyl ester
  • 1-Boc-2-methylhydrazine
  • tert-butyl N-(methylamino)carbamate
  • N2-BOC-N1-Methylhydrazine
  • N'-methyl(tert-butoxy)carbohydrazide
  • 2-Methyl-2-propanyl 2-methylhydrazinecarboxylate
  • tert-Butyl 2-methyhydrazinecarboxylate
  • N1-BOC-2-Methylhydrazine
  • 127799-54-6