1-N-Boc-2-Methylhydrazine
- Product Name
- 1-N-Boc-2-Methylhydrazine
- CAS No.
- 127799-54-6
- Chemical Name
- 1-N-Boc-2-Methylhydrazine
- Synonyms
- tert-butyl 2-methylhydrazine-1-carboxylate;tert-butyl 2-Methylhydrazinecarboxylate;1-Boc-2-methylhydrazine;N1-BOC-2-Methylhydrazine;1-N-Boc-2-Methylhydrazine;N2-BOC-N1-Methylhydrazine;tert-butyl N-(methylamino)carbamate;N'-methyl(tert-butoxy)carbohydrazide;tert-Butyl 2-methyhydrazinecarboxylate;1-(t-butyloxy)carbonyl-2-Methylhydrazine
- CBNumber
- CB62592972
- Molecular Formula
- C6H14N2O2
- Formula Weight
- 146.19
- MOL File
- 127799-54-6.mol
1-N-Boc-2-Methylhydrazine Property
- Melting point:
- 49-51℃
- Density
- 0.982±0.06 g/cm3 (20 ºC 760 Torr)
- storage temp.
- Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
- pka
- 10.73±0.43(Predicted)
- Appearance
- White to off-white Solid
- InChI
- InChI=1S/C6H14N2O2/c1-6(2,3)10-5(9)8-7-4/h7H,1-4H3,(H,8,9)
- InChIKey
- UZRUVUYVHGPEAP-UHFFFAOYSA-N
- SMILES
- N(C(OC(C)(C)C)=O)NC
Safety
- HS Code
- 2928009090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B812483
- Product name
- tert-Butyl2-methylhydrazinecarboxylate
- Packaging
- 500mg
- Price
- $220
- Updated
- 2021/12/16
- Product number
- AK-98717
- Product name
- tert-Butyl2-methylhydrazinecarboxylate
- Purity
- 98%
- Packaging
- 250mg
- Price
- $22
- Updated
- 2021/12/16
- Product number
- 224639
- Product name
- tert-Butyl2-methylhydrazinecarboxylate
- Purity
- 95%
- Packaging
- 100mg
- Price
- $50
- Updated
- 2021/12/16
- Product number
- 224639
- Product name
- tert-Butyl2-methylhydrazinecarboxylate
- Purity
- 95%
- Packaging
- 250mg
- Price
- $101
- Updated
- 2021/12/16
- Product number
- AK-98717
- Product name
- tert-Butyl2-methylhydrazinecarboxylate
- Purity
- 98%
- Packaging
- 5g
- Price
- $165
- Updated
- 2021/12/16
1-N-Boc-2-Methylhydrazine Chemical Properties,Usage,Production
Synthesis
127799-53-5
127799-54-6
The general procedure for the synthesis of 1-Boc-2-methylhydrazine from 1-Cbz-2-Boc-1-methylhydrazine is as follows: 24.8 g (70.8 mmol) of 1-benzyl-2-tert-butyl-1-methylhydrazine-1,2-dicarboxylate was dissolved in 500 mL of ethanol at room temperature and standard atmospheric pressure, and 1.24 g of palladium (10% activated charcoal) was added as a catalyst for the hydrogenation reaction. Upon completion of the reaction, the reaction mixture was filtered through diatomaceous earth to remove the catalyst and the filtrate was concentrated and dried under reduced pressure to give the product. The yield was 12.3 g with a purity of 48%, representing 57% of the theoretical yield.
References
[1] Journal of the Chemical Society - Perkin Transactions 1, 1997, # 16, p. 2297 - 2311
[2] Journal of the American Chemical Society, 1993, vol. 115, # 20, p. 8898 - 8906
[3] Tetrahedron Letters, 1996, vol. 37, # 2, p. 183 - 186
[4] Patent: US5030724, 1991, A
[5] Patent: US2016/52884, 2016, A1. Location in patent: Paragraph 0599-0600
1-N-Boc-2-Methylhydrazine Preparation Products And Raw materials
Raw materials
Preparation Products
1-N-Boc-2-Methylhydrazine Suppliers
- Tel
- --
- Fax
- --
- sales@ajchem.in
- Country
- India
- ProdList
- 6100
- Advantage
- 58
View Lastest Price from 1-N-Boc-2-Methylhydrazine manufacturers
- Product
- 1-N-Boc-2-Methylhydrazine 127799-54-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2020-01-08