1-N-Boc-2-Methylhydrazine

Product Name: 1-N-Boc-2-Methylhydrazine
CAS No.: 127799-54-6
Chemical Name: 1-N-Boc-2-Methylhydrazine
Synonyms: tert-butyl 2-methylhydrazine-1-carboxylate;tert-butyl 2-Methylhydrazinecarboxylate;1-Boc-2-methylhydrazine;N1-BOC-2-Methylhydrazine;1-N-Boc-2-Methylhydrazine;N2-BOC-N1-Methylhydrazine;tert-butyl N-(methylamino)carbamate;N'-methyl(tert-butoxy)carbohydrazide;tert-Butyl 2-methyhydrazinecarboxylate;1-(t-butyloxy)carbonyl-2-Methylhydrazine
CBNumber: CB62592972
Molecular Formula: C6H14N2O2
Formula Weight: 146.19
MOL File: 127799-54-6.mol

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1-N-Boc-2-Methylhydrazine Property

Melting point:: 49-51℃
Density: 0.982±0.06 g/cm3 (20 ºC 760 Torr)
storage temp.: Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
pka: 10.73±0.43(Predicted)
Appearance: White to off-white Solid
InChI: InChI=1S/C6H14N2O2/c1-6(2,3)10-5(9)8-7-4/h7H,1-4H3,(H,8,9)
InChIKey: UZRUVUYVHGPEAP-UHFFFAOYSA-N
SMILES: N(C(OC(C)(C)C)=O)NC

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Safety

HS Code: 2928009090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B812483
Product name: tert-Butyl2-methylhydrazinecarboxylate
Packaging: 500mg
Price: $220
Updated: 2021/12/16

Ark Pharm

Product number: AK-98717
Product name: tert-Butyl2-methylhydrazinecarboxylate
Purity: 98%
Packaging: 250mg
Price: $22
Updated: 2021/12/16

Oakwood

Product number: 224639
Product name: tert-Butyl2-methylhydrazinecarboxylate
Purity: 95%
Packaging: 100mg
Price: $50
Updated: 2021/12/16

Oakwood

Product number: 224639
Product name: tert-Butyl2-methylhydrazinecarboxylate
Purity: 95%
Packaging: 250mg
Price: $101
Updated: 2021/12/16

Ark Pharm

Product number: AK-98717
Product name: tert-Butyl2-methylhydrazinecarboxylate
Purity: 98%
Packaging: 5g
Price: $165
Updated: 2021/12/16

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1-N-Boc-2-Methylhydrazine Chemical Properties,Usage,Production

Synthesis

127799-53-5

127799-54-6

The general procedure for the synthesis of 1-Boc-2-methylhydrazine from 1-Cbz-2-Boc-1-methylhydrazine is as follows: 24.8 g (70.8 mmol) of 1-benzyl-2-tert-butyl-1-methylhydrazine-1,2-dicarboxylate was dissolved in 500 mL of ethanol at room temperature and standard atmospheric pressure, and 1.24 g of palladium (10% activated charcoal) was added as a catalyst for the hydrogenation reaction. Upon completion of the reaction, the reaction mixture was filtered through diatomaceous earth to remove the catalyst and the filtrate was concentrated and dried under reduced pressure to give the product. The yield was 12.3 g with a purity of 48%, representing 57% of the theoretical yield.

References

[1] Journal of the Chemical Society - Perkin Transactions 1, 1997, # 16, p. 2297 - 2311
[2] Journal of the American Chemical Society, 1993, vol. 115, # 20, p. 8898 - 8906
[3] Tetrahedron Letters, 1996, vol. 37, # 2, p. 183 - 186
[4] Patent: US5030724, 1991, A
[5] Patent: US2016/52884, 2016, A1. Location in patent: Paragraph 0599-0600

1-N-Boc-2-Methylhydrazine Preparation Products And Raw materials

Raw materials

Preparation Products

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1-N-Boc-2-Methylhydrazine Suppliers

China 88 India 2 Switzerland 1 United States 6 Global 97

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View Lastest Price from 1-N-Boc-2-Methylhydrazine manufacturers

Career Henan Chemical Co

Product: 1-N-Boc-2-Methylhydrazine 127799-54-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-08

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127799-54-6