9H-Carbazole, 3,6-diiodo-
- Product Name
- 9H-Carbazole, 3,6-diiodo-
- CAS No.
- 57103-02-3
- Chemical Name
- 9H-Carbazole, 3,6-diiodo-
- Synonyms
- 3,6-Diiodocarbazole;6-diiodo-9H-carbazole;3,6-Diiodocarbazole>3,6-Diiodo-9H-carbazole;9H-Carbazole, 3,6-diiodo-;9H-Carbazole, 3,6-diiodo-, 10 mM in DMSO;Pentamethylcyclopentadienylbis(triphenylphosphine)
- CBNumber
- CB62605900
- Molecular Formula
- C12H7I2N
- Formula Weight
- 419
- MOL File
- 57103-02-3.mol
9H-Carbazole, 3,6-diiodo- Property
- Melting point:
- 205.0 to 209.0 °C
- Boiling point:
- 498.3±25.0 °C(Predicted)
- Density
- 2.326±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- powder to crystal
- pka
- 15.68±0.30(Predicted)
- color
- White to Light yellow to Light orange
- InChI
- InChI=1S/C12H7I2N/c13-7-1-3-11-9(5-7)10-6-8(14)2-4-12(10)15-11/h1-6,15H
- InChIKey
- PECAOKZHORDWAI-UHFFFAOYSA-N
- SMILES
- N1C2=C(C=C(I)C=C2)C2=C1C=CC(I)=C2
Safety
- HS Code
- 29339900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- D4548
- Product name
- 3,6-Diiodocarbazole
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $111
- Updated
- 2025/07/31
- Product number
- D4548
- Product name
- 3,6-Diiodocarbazole
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $360
- Updated
- 2025/07/31
- Product number
- D493085
- Product name
- 3,6-Diiodo-9H-carbazole
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- OR54455
- Product name
- 3,6-Diiodo-carbazole
- Packaging
- 5g
- Price
- $37
- Updated
- 2021/12/16
- Product number
- 3H31-H-16
- Product name
- 3,6-Diiodocarbazole
- Packaging
- 5G
- Price
- $40
- Updated
- 2021/12/16
9H-Carbazole, 3,6-diiodo- Chemical Properties,Usage,Production
Synthesis
86-74-8
57103-02-3
General procedure for the synthesis of 3,6-diiodo-9H-carbazole from carbazole: Carbazole (24 g, 144 mmol) was dissolved in acetic acid (360 mL) and heated to 80 °C. Subsequently, finely ground potassium iodide (31.5 g, 189 mmol) was added to the reaction system and stirred for several minutes. Next, potassium iodate (24 g, 100 mmol) was carefully added in portions and the reaction temperature was maintained at 80 °C until the iodine was completely consumed. After completion of the reaction, the mixture was cooled to 40 °C and the solid product was collected by filtration. It was washed sequentially with acetic acid (30 mL), methanol (100 mL) and water to afford 3,6-diiodo-9H-carbazole (51 g, 90% yield) as a yellow solid. NMR hydrogen spectrum (300MHz, CDCl3, δ): 8.33 (multiple peaks, 2H), 8.15 (multiple peaks, 1H), 7.70-7.60 (multiple peaks, 2H), 7.23-7.20 (multiple peaks, 2H).
References
[1] Chemistry - An Asian Journal, 2010, vol. 5, # 10, p. 2162 - 2167
[2] Patent: US2009/54649, 2009, A1. Location in patent: Page/Page column 34-35
[3] Chemistry - A European Journal, 2015, vol. 21, # 48, p. 17379 - 17390
[4] Journal of Organic Chemistry, 2015, vol. 80, # 4, p. 2392 - 2396
[5] European Journal of Organic Chemistry, 2013, # 29, p. 6619 - 6628
9H-Carbazole, 3,6-diiodo- Preparation Products And Raw materials
Raw materials
Preparation Products
9H-Carbazole, 3,6-diiodo- Suppliers
- Tel
- --
- Fax
- --
- sales-in@tcichemicals.com
- Country
- India
- ProdList
- 6768
- Advantage
- 58
- Tel
- --
- Fax
- --
- sales@ajchem.in
- Country
- India
- ProdList
- 6100
- Advantage
- 58
View Lastest Price from 9H-Carbazole, 3,6-diiodo- manufacturers
- Product
- 3,6-Diiodo-9H-carbazole 57103-02-3
- Price
- US $36.00-358.00/g
- Min. Order
- 25g
- Purity
- 0.98
- Supply Ability
- 10kg
- Release date
- 2023-12-07
- Product
- 3,6-Diiodo-9H-carbazole 57103-02-3
- Price
- US $200.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-30
- Product
- 9H-Carbazole, 3,6-diiodo- 57103-02-3
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 95.0%min
- Supply Ability
- 1000kg
- Release date
- 2023-03-10