ChemicalBook > CAS DataBase List > 3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER

3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER

Product Name: 3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER
CAS No.: 941714-57-4
Chemical Name: 3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER
Synonyms: methyl 3-bromo-1H-pyrrole-2-carboxylate;Methyl 3-BroMopyrrole-2-carboxylate;SW-83;SWF-83;3-BroMo-1H-pyrrole-carboxylate Methyl;3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER;1H-Pyrrole-2-carboxylic acid, 3-bromo-, methyl ester
CBNumber: CB62665281
Molecular Formula: C6H6BrNO2
Formula Weight: 204.02
MOL File: 941714-57-4.mol

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3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER Property

Boiling point:: 286.2±20.0 °C(Predicted)
Density: 1.674±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 13.49±0.50(Predicted)
Appearance: White to yellow Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M293830
Product name: Methyl3-Bromo-1H-pyrrole-2-carboxylate
Packaging: 50mg
Price: $45
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4H23-9-15
Product name: Methyl 3-bromo-1H-pyrrole-2-carboxylate
Packaging: 1g
Price: $225
Updated: 2021/12/16

AK Scientific

Product number: 7019AJ
Product name: Methyl3-bromopyrrole-2-carboxylate
Packaging: 5g
Price: $290
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4H23-9-15
Product name: Methyl 3-bromo-1H-pyrrole-2-carboxylate
Packaging: 5G
Price: $800
Updated: 2021/12/16

Matrix Scientific

Product number: 113439
Product name: 3-Bromo-1H-pyrrole-2-carboxylic acid methyl ester
Packaging: 1g
Price: $662
Updated: 2021/12/16

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3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER Chemical Properties,Usage,Production

Synthesis

1192217-76-7

941714-57-4

a) Synthesis of methyl 3-bromo-1H-pyrrole-2-carboxylate: methyl 3-bromo-1-(phenylsulfonyl)-1H-pyrrole-2-carboxylate (6.59 g, 19.2 mmol) was dissolved in 132 mL of methanol. Sodium methanolate (1.55 g, 28.7 mmol) was added and the reaction mixture was stirred for 4 hours at room temperature. After completion of the reaction, the solvent was removed by evaporation and the residue was extracted by partitioning with saturated aqueous ammonium chloride solution and ethyl acetate. The organic layer was washed sequentially with water and brine, dried over anhydrous magnesium sulfate, filtered and concentrated under reduced pressure. Purification by fast column chromatography (eluent: 0% to 30% hexane/ethyl acetate gradient) afforded 3.32 g (85% yield) of the target product methyl 3-bromopyrrole-2-carboxylate. Low resolution mass spectrometry (LRMS) showed m/z: 203,205 ([M+1]+).

References

[1] Patent: WO2012/146666, 2012, A1. Location in patent: Page/Page column 188-189
[2] Patent: WO2014/60432, 2014, A1. Location in patent: Page/Page column 132

3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER 941714-57-4
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10000KGS
Release date: 2025-09-04

Career Henan Chemical Co

Product: 3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER 941714-57-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2019-12-30

941714-57-4, 3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTERRelated Search:

(1s,3r,4r)-3-[(tert-butoxycarbonyl)amino]-4-[(methylsulfonyl)oxy]cyclohexanecarboxylic acid ethyl ester LY-2484595 methyl exo-3-azabicyclo[3.1.0]hexane-6-carboxylate hydrochloride SW-80 2-iodo-1-(phenylsulfonyl)-1H-pyrrolo[2,3-b]pyridine 7-bromo-4-(trifluoromethyl)-1H-indole 6-Bromoisatin 3-Trifluoromethyl-1H-pyrrolo[2,3-b]pyridine 1H-Pyrrole-2-acetic acid, 3-(methoxycarbonyl)-1-methyl-, methyl ester Pyrido[4,3-d]pyrimidin-4(1H)-one (9CI) 1H-PYRROLO[2,3-B]PYRIDINE, 2-METHYL- BOC,BZL-L-ALA-OH

3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER

methyl 3-bromo-1H-pyrrole-2-carboxylate

Methyl 3-BroMopyrrole-2-carboxylate

3-BroMo-1H-pyrrole-carboxylate Methyl

1H-Pyrrole-2-carboxylic acid, 3-bromo-, methyl ester

SWF-83

SW-83

941714-57-4