Tris(4-fluorophenyl)phosphine

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Tris(4-fluorophenyl)phosphine

Product Name: Tris(4-fluorophenyl)phosphine
CAS No.: 18437-78-0
Chemical Name: Tris(4-fluorophenyl)phosphine
Synonyms: Tris(4-fL;Tris(4-fluorophe;Tris(4-fluorophenyl);TRI(4-FLUOROPHENYL)PHOSPHINE;Tris(4-Flurophenyl)Phosphine;Tri-(p-fluorophenyl)phosphine;TRIS(P-FLUOROPHENYL)PHOSPHINE;TRIS(4-FLUOROPHENYL)PHOSPHINE;tris(4-fluorophenyl)phosphane;Phosphine, tris(p-fluorophenyl)-
CBNumber: CB6286703
Molecular Formula: C18H12F3P
Formula Weight: 316.26
MOL File: 18437-78-0.mol

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Tris(4-fluorophenyl)phosphine Property

Melting point:: 79-83 °C(lit.)
Boiling point:: 160°C/0.1mmHg(lit.)
storage temp.: Inert atmosphere,Room Temperature
form: Crystalline Powder
color: White to very slightly yellow
Water Solubility: Insoluble in water.
Sensitive: Air Sensitive
BRN: 919838
InChI: InChI=1S/C18H12F3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
InChIKey: GEPJPYNDFSOARB-UHFFFAOYSA-N
SMILES: P(C1=CC=C(F)C=C1)(C1=CC=C(F)C=C1)C1=CC=C(F)C=C1
CAS DataBase Reference: 18437-78-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 395099
Product name: Tris(4-fluorophenyl)phosphine
Purity: 98%
Packaging: 5g
Price: $153
Updated: 2024/03/01

TCI Chemical

Product number: T2900
Product name: Tris(4-fluorophenyl)phosphine
Purity: >98.0%(GC)
Packaging: 5g
Price: $143
Updated: 2024/03/01

Alfa Aesar

Product number: A14813
Product name: Tris(4-fluorophenyl)phosphine
Purity: 98%
Packaging: 1g
Price: $27.65
Updated: 2024/03/01

Alfa Aesar

Product number: A14813
Product name: Tris(4-fluorophenyl)phosphine
Purity: 98%
Packaging: 5g
Price: $108.65
Updated: 2024/03/01

Strem Chemicals

Product number: 15-7890
Product name: Tris(p-fluorophenyl)phosphine, 99%
Packaging: 1g
Price: $58
Updated: 2024/03/01

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Tris(4-fluorophenyl)phosphine Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

Tris(4-fluorophenyl)phosphine (TFPP) and tris(2,2,2- trifluoroethyl) phosphite (TTFP) were used as flame-retarding additives in Li-ion battery clectrolytes.
Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Uses

Tris(4-fluorophenyl)phosphine, is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.

Uses

Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

Preparation

with 4-bromofluorobenzene, magnesium, and phosphorous (III) trichloride.3 Alternatively, reduction of tris(4-fluorophenyl)phosphine oxide with an iron catalyst.

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Synthesis

Tris (4-fluorophenyl)phosphine oxide could be used as a starting material to synthesize Tris(4-fluorophenyl)phosphine. Into the reactor were added 0.2 mmol of tris(4-fluorophenyl)phosphine oxide, 0.36 mmol of trifluoroacetic anhydride, and 1 ml of dioxane as a solvent. Stir at room temperature under a nitrogen atmosphere for 30 min; after the reaction, continue adding 0.2 mmol of sodium bicarbonate, 0.24 mmol of 15-Crown-5, and 1.2 mmol of sodium hydride under a nitrogen environment. Under 150 ℃, stir for 24 hours, stop the reaction, cool to room temperature, and distilled under reduced pressure to remove the solvent. The crude product is separated by column chromatography to obtain Tris(4-fluorophenyl)phosphine with a yield of 74%.

Tris(4-fluorophenyl)phosphine Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris(4-fluorophenyl)phosphine Suppliers

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View Lastest Price from Tris(4-fluorophenyl)phosphine manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: Tris(4-fluorophenyl)phosphine 18437-78-0
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 tons
Release date: 2020-01-14

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Tris(4-fluorophenyl)phosphine 18437-78-0
Price: US $0.00/G
Min. Order: 100G
Purity: 98%min
Supply Ability: 30kg/month
Release date: 2023-02-03

Career Henan Chemical Co

Product: TRIS(4-FLUOROPHENYL)PHOSPHINE 18437-78-0
Price: US $1.00/KG
Min. Order: 1G
Purity: 99%
Supply Ability: 1MT
Release date: 2018-08-09

18437-78-0, Tris(4-fluorophenyl)phosphineRelated Search:

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Phosphine, tris(p-fluorophenyl)-

TRIS(4-FLUOROPHENYL)PHOSPHINE

TRIS(P-FLUOROPHENYL)PHOSPHINE

TRI(4-FLUOROPHENYL)PHOSPHINE

Tri-(p-fluorophenyl)phosphine

Tris(4-Flurophenyl)Phosphine

Tris(4-fluorophenyl)phosphine,99%

Tris(p-fluorophenyl)phosphine,99%

Tris(4-fluorophenyl)phosphine 98%

Tris(4-fluorophenyl)phosphine98%

Tris(4-fluorophe

Tris(4-fluorophenyl)

tris(4-fluorophenyl)phosphane

Tris(4-fL

Phosphine, tris(4-fluorophenyl)-

18437-78-0

FC6H43P

C18H12F3P

pFC6H43P

Catalysis and Inorganic Chemistry

Phosphine Ligands

Phosphorus Compounds

Achiral Phosphine

Aryl Phosphine

Ligand

Catalysis and Inorganic Chemistry

Phosphine Ligands

Phosphorus Compounds

organophosphorus ligand