Triethylsilyl trifluoromethanesulfonate

Product Name: Triethylsilyl trifluoromethanesulfonate
CAS No.: 79271-56-0
Chemical Name: Triethylsilyl trifluoromethanesulfonate
Synonyms: TRIETHYLSILYL TRIFLATE;TES-OTF;DKFELEX0305;TES TRIFLATE;Triethyl(trifluoromesyloxy)silane;Triethylsilyl trifluoromethanesulfote;TRIETHYLSILYL TRIFLUOROMETHANESULFONATE;TRIETHYLSILYL TRIFLUOROMETHANESULPHONATE;Triethylsilyltrifluoromethanesulphonate99%;Triethylsilyltrifluoromethanesulfonate,99%
CBNumber: CB6298346
Molecular Formula: C7H15F3O3SSi
Formula Weight: 264.34
MOL File: 79271-56-0.mol

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Triethylsilyl trifluoromethanesulfonate Property

Boiling point:: 85-86 °C/12 mmHg (lit.)
Density: 1.169 g/mL at 25 °C (lit.)
refractive index: n20/D 1.389(lit.)
Flash point:: 162 °F
storage temp.: Inert atmosphere,Room Temperature
solubility: Triethylsilyl Trifluoromethanesulfonate is readily sol hydrocarbons, dialkyl ethers, halogenated solvents. CH2Cl2 is employed most commonly. Reactions in 1,2-dichloroethane proceed faster than those in CCl4 or Et2O. Protic solvents and THF react with trialkylsilyl triflates and are therefore not suitable.
form: Fuming Liquid
Specific Gravity: 1.169
color: Clear colorless to light brown
Water Solubility: Miscible with dichloromethane, hydrocarbons, dialkyl ethers and halogenated solvents. Immiscible with water.
Sensitive: Moisture Sensitive
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
BRN: 3590541
Stability:: Moisture Sensitive and Hygroscopic, Moisture Sensitive And Hygroscopic
CAS DataBase Reference: 79271-56-0(CAS DataBase Reference)

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Safety

Hazard Codes: C,F
Risk Statements: 34-14
Safety Statements: 26-36/37/39-45-27
RIDADR: UN 3265 8/PG 2
WGK Germany: 3
F: 10-21
Hazard Note: Corrosive/Flammable
TSCA: No
HazardClass: 8
PackingGroup: II
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 279471
Product name: Triethylsilyl trifluoromethanesulfonate
Purity: 99%
Packaging: 10g
Price: $129
Updated: 2024/03/01

Sigma-Aldrich

Product number: 279471
Product name: Triethylsilyl trifluoromethanesulfonate
Purity: 99%
Packaging: 50g
Price: $147
Updated: 2024/03/01

TCI Chemical

Product number: T1689
Product name: Triethylsilyl Trifluoromethanesulfonate
Purity: >98.0%(T)
Packaging: 5g
Price: $45
Updated: 2024/03/01

TCI Chemical

Product number: T1689
Product name: Triethylsilyl Trifluoromethanesulfonate
Purity: >98.0%(T)
Packaging: 25g
Price: $128
Updated: 2024/03/01

Alfa Aesar

Product number: L14477
Product name: Triethylsilyl trifluoromethanesulfonate
Purity: 98%
Packaging: 5g
Price: $45.65
Updated: 2024/03/01

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Triethylsilyl trifluoromethanesulfonate Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light brown fuming liquid

Physical properties

85–86 °C/12 mmHg; d 1.169 g cm?3.

Uses

Triethylsilyl Trifluoromethanesulfonate can be used as potent silylating agent and as Lewis acid catalyst. Triethylsilyl ethers are generally more stable towards hydrolysis than are trimethylsilyl ethers, and consequently the Et3Si moiety has gained increasing use as a protecting group for alcohols. However, since it is often difficult to silylate sterically hindered hydroxyl groups using Et3SiCl, triethylsilyl perchlorate and triethylsilyl triflate (Et3SiOTf) were introduced to overcome this problem. Jefford has reported that condensation reactions of 2-trimethylsiloxyfuran with aldehydes can be catalyzed by Et3SiOTf to give mainly the threo addition product (eq 8).

Uses

Triethylsilyl trifluoromethanesulfonate acts as a silylating agent. It is also useful as a Lewis acid catalyst. Further, it reacts with 1-diazo-3,3-dimethyl-butan-2-one to prepare 1-diazo-3,3-dimethyl-1-(triethylsilyl)-2-butanone.

Preparation

Triethylsilyl Trifluoromethanesulfonate can be prepared by reacting chlorotriethylsilane with trifluoromethanesulfonic acid followed by distillation.

Triethylsilyl trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Triethylsilyl trifluoromethanesulfonate Suppliers

Belgium 3 China 189 France 2 Germany 5 India 12 Italy 1 Japan 5 Singapore 1 Switzerland 2 United Kingdom 11 United States 37 Global 268

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

Kanto Chemical Co. Inc.

Tel: --
Fax: --
Email: kanto-61@gms.kanto.co.jp
Country: Japan
ProdList: 530
Advantage: 58

FUJIFILM Wako Pure Chemical Corporation

Tel: --
Fax: --
Email: ffwk-cservice@fujifilm.com
Country: Japan
ProdList: 6222
Advantage: 58

Kanto Chemical Co., Inc.

Tel: --
Fax: --
Email: reag-info@gms.kanto.co.jp
Country: Japan
ProdList: 6756
Advantage: 74

Wako Pure Chemical Industries, Ltd.

Tel: --
Fax: --
Email: labchem-tec@wako-chem.co.jp
Country: Japan
ProdList: 6819
Advantage: 80

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View Lastest Price from Triethylsilyl trifluoromethanesulfonate manufacturers

LY Global chemicals co.,ltd .

Product: Triethylsilyl trifluoromethanesulfonate 79271-56-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000KG
Release date: 2023-03-09

Henan Aochuang Chemical Co.,Ltd.

Product: Triethylsilyl trifluoromethanesulfonate 79271-56-0
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-09-30

Zhuozhou Wenxi import and Export Co., Ltd

Product: Triethylsilyl trifluoromethanesulfonate 79271-56-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

79271-56-0, Triethylsilyl trifluoromethanesulfonateRelated Search:

Gabexate mesylate Trifluoromethanesulfonic acid COPPER(II) TRIFLUOROMETHANESULFONATE YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Pefloxacin mesylate Lithium trifluoromethanesulfonate Levofloxacin Methylate Danofloxacin mesylate Scandium trifluoromethanesulfonate Sodium trifluoromethanesulfonate Trifluoromethanesulfonic anhydride Triethylsilane Triethylene glycol dimethacrylate TRIISOPROPYLSILYL ACRYLATE triisopropylsilyl Methacrylate Sodium methanesulfinate Trifluoromethane Hydrogen Sulfide

TES TRIFLATE

TRIFLUOROMETHANESULFONIC ACID TRIETHYLSILYL ESTER

TRIETHYLSILYL TRIFLATE

TRIETHYLSILYL TRIFLUOROMETHANESULFONATE

TRIETHYLSILYL TRIFLUOROMETHANESULPHONATE

TES-OTF

1,1,1-TRIETHYLSILYL TRIFLUOROMETHANESULFONATE

TRIETHYLSILYL TRIFLUOROMETHANESULFONATE 99%

TRIETHYLSILYL TRIFLUOROMETHANESULFONATE, 99%TRIETHYLSILYL TRIFLUOROMETHANESULFONATE, 99%TRIETHYLSILYL TRIFLUOROMETHANESULFONATE, 99%

TriethylsilyltrifluoromethanesulphonateTESTriflate

Triethylsilyl trifluoromethanesulphonate 99%

Triethylsilyltrifluoromethanesulphonate99%

Triethylsilyl trifluoromethanesulfonate,TES triflate, Trifluoromethanesulfonic acid triethylsilylester

Triethylsilyl Triflate Trifluoromethanesulfonic Acid Triethylsilyl Ester

Triethylsilyltrifluoromethanesulfonate,99%

TES triflate, Trifluoromethanesulfonic acid triethylsilylester

Triethyl(trifluoromesyloxy)silane

Triethyl(trifluoromethylsulfonyloxy)silane

Triethylsilyl trifluoromethanesulfote

Methanesulfonic acid,1,1,1-trifluoro-, triethylsilyl ester

TIANFUCHEM--79271-56-0--Triethylsilyl trifluoromethanesulfonate

TRIETHYLSILYL TRIFLUOROMETHANESULFONATE TES triflate Triethylsilyl Triflate

DKFELEX0305

79271-56-0

CF3SO3SiCH2CH33

CF3SO3SiC2H53

Synthetic Reagents

Silicon-Based

Protection and Derivatization

Protecting and Derivatizing Reagents

Protection & Derivatization Reagents (for Synthesis)

Silicon Compounds (for Synthesis)

Si-O Compounds

Silyl Esters

Si (Classes of Silicon Compounds)

metal triflate compounds

Protection & Derivatization Reagents (for Synthesis)

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)

Silyl Esters

Si-O Compounds

Synthetic Organic Chemistry