Description
ChemicalBook > CAS DataBase List > Sodium methanesulfinate

Sodium methanesulfinate

Description
Product Name
Sodium methanesulfinate
CAS No.
20277-69-4
Chemical Name
Sodium methanesulfinate
Synonyms
METHANESULFINIC ACID;methanesulfinate;Sodium methylsulfinate;METHANESULFINIC ACID SODIUM SALT;SKL256;SODIUM METHANESULFINATE;sodium methanesulphinate;SodiumMethanesulfinate>Sodium methanesulphinate, tech;METHANESULPHINIC ACID SODIUM SALT
CBNumber
CB7147892
Molecular Formula
CH5NaO2S
Formula Weight
104.1
MOL File
20277-69-4.mol
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Sodium methanesulfinate Property

Melting point:
222-226 °C (dec.) (lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Methanol, Water (Slightly)
form 
Powder
color 
White to light beige
Water Solubility 
soluble
Sensitive 
Air Sensitive & Hygroscopic
BRN 
3565430
Stability:
Hygroscopic
InChI
InChI=1S/CH4O2S.Na.H/c1-4(2)3;;/h1H3,(H,2,3);;
InChIKey
LYPGDCWPTHTUDO-UHFFFAOYSA-M
SMILES
S(O)(=O)C.[NaH]
CAS DataBase Reference
20277-69-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-20/21/22
Safety Statements 
36/37-24/25
RIDADR 
2811
WGK Germany 
3
PackingGroup 
III
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P330Rinse mouth.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
433063
Product name
Sodium methanesulfinate
Purity
technical grade, 85%
Packaging
1g
Price
$20.8
Updated
2024/03/01
Sigma-Aldrich
Product number
433063
Product name
Sodium methanesulfinate
Purity
technical grade, 85%
Packaging
10g
Price
$111
Updated
2024/03/01
TCI Chemical
Product number
M1255
Product name
Sodium Methanesulfinate
Purity
>90.0%(T)
Packaging
5g
Price
$82
Updated
2024/03/01
TCI Chemical
Product number
M1255
Product name
Sodium Methanesulfinate
Purity
>90.0%(T)
Packaging
25g
Price
$240
Updated
2024/03/01
Alfa Aesar
Product number
L11360
Product name
Methanesulfinic acid sodium salt, 95%
Packaging
1g
Price
$26.65
Updated
2024/03/01
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Sodium methanesulfinate Chemical Properties,Usage,Production

Description

Sodium methanesulfinate is an aliphatic sodium sulfinate. Conjugate addition of sodium methanesulfinate to vinyl heterocycles has been described. Cross-coupling reaction between aryl boronic acid and sodium methanesulfinate has been studied. It can be used in the preparation of alkyl methyl sulfone and methyl bis(4-tolyl)sulfoniumtrifluoromethanesulfonate. It is also employed in the synthesis of two sulfonyl type reversible addition-fragmentation transfer (RAFT) agents such as benzyl methylsulfonyldithioformate and benzyl phenylsulfonyldithioformate. Moreover, it can be used for synthesizing cyclooxygenase-2 inhibitors.

Chemical Properties

White to light beige powder

Uses

Sodium methylsulfinate can be used to synthesize cyclooxygenase-2 inhibitors.

General Description

Sodium methanesulfinate is an aliphatic sodium sulfinate. Conjugate addition of sodium methanesulfinate to vinyl heterocycles has been described. Cross-coupling reaction between aryl boronic acid and sodium methanesulfinate has been studied. Its stock solution was prepared from methanesulfonic acid by adding one equivalent of sodium hydroxide and diluting it to 4M.

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Sodium methanesulfinate Suppliers

Jiaxing Jilat Chemical Co. LTD
Tel
0573-82813639 15157377625
Fax
0573-82813637
Email
sales@jlightchem.com
Country
China
ProdList
167
Advantage
58
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
ELION INTERNATIONAL(HONGKONG) CO., LTD
Tel
177-6725-7858 15967138206
Fax
0571-85022751
Email
sales@hzbrown.com
Country
China
ProdList
74
Advantage
62
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Email
sales@accelachem.com
Country
China
ProdList
11725
Advantage
58
Jiangxi Boyang Pharmaceutical Chemical Co., Ltd.
Tel
15870608400
Email
717293806@qq.com
Country
China
ProdList
26
Advantage
58
Wuhan Circle Star Chem-medic Technology Co.,Ltd
Tel
18908653704
Email
marketing@circlestar-chem.com
Country
China
ProdList
5001
Advantage
58
Yancheng Yuntao Chemical Co., Ltd.
Tel
13512592619
Email
2838893166@qq.com
Country
China
ProdList
50
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
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View Lastest Price from Sodium methanesulfinate manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
Sodium methanesulfinate 20277-69-4
Price
US $980.00-750.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000
Release date
2024-08-15
Zhuozhou Wenxi import and Export Co., Ltd
Product
Sodium methanesulfinate 20277-69-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
Sodium methanesulfinate 20277-69-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-08

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