Copper(I) bromide-dimethyl sulfide

Product Name: Copper(I) bromide-dimethyl sulfide
CAS No.: 54678-23-8
Chemical Name: Copper(I) bromide-dimethyl sulfide
Synonyms: COPPER(I) BROMIDE-DIMETHYL SULFIDE COMPLEX;COPPER(I) BROMIDE DIMETHYL SULFIDE;Bromocopper;Copper(I) bromide methyL;Copper, bromothiobismethane-;COPPER(1)BROMIDE DMS COMPLEX;bromo[thiobis[methane]]copper;COPPER BROMIDE-DIMETHYL SULFIDE;BROMO(DIMETHYLSULFIDE)COPPER(I);COPPER(1) BROMIDE DMS COMPLEX 95%
CBNumber: CB6332325
Molecular Formula: C2H6BrCuS
Formula Weight: 205.58
MOL File: 54678-23-8.mol

More

Less

Copper(I) bromide-dimethyl sulfide Property

Melting point:: 132 °C (dec.)(lit.)
form: Crystalline Powder and/or Chunks
color: Pale brown or pale green
Water Solubility: Soluble in water. Reacts with water and decomposes.
Sensitive: Moisture Sensitive/Air Sensitive
BRN: 4386581
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
InChIKey: PMHQVHHXPFUNSP-UHFFFAOYSA-M
CAS DataBase Reference: 54678-23-8(CAS DataBase Reference)

More

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-24/25
RIDADR: 1759
WGK Germany: 3
F: 10-13-21
HazardClass: 8
PackingGroup: III
HS Code: 29309090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 230502
Product name: Copper(I) bromide dimethyl sulfide complex
Purity: 99%
Packaging: 10g
Price: $118
Updated: 2024/03/01

Sigma-Aldrich

Product number: 230502
Product name: Copper(I) bromide dimethyl sulfide complex
Purity: 99%
Packaging: 50g
Price: $320
Updated: 2024/03/01

Alfa Aesar

Product number: 019368
Product name: Copper(I) bromide-dimethyl sulfide complex
Packaging: 2g
Price: $22.65
Updated: 2024/03/01

Alfa Aesar

Product number: 019368
Product name: Copper(I) bromide-dimethyl sulfide complex
Packaging: 10g
Price: $84.6
Updated: 2024/03/01

Strem Chemicals

Product number: 29-0225
Product name: Copper(I) bromide, dimethyl sulfide complex, 99%
Packaging: 25g
Price: $225
Updated: 2021/12/16

More

Less

Copper(I) bromide-dimethyl sulfide Chemical Properties,Usage,Production

Chemical Properties

off-white to beige, grey or green crystalline

Uses

Copper(I) bromide-dimethyl sulfide complex is used as catalyst for adding Grignard reagents to fullerenes.

Uses

Catalyst employed in the addition of Grignard reagents (alkyl, alkenyl, aryl) to fullerenes. This process adds 5 organic groups to [60]fullerene and 3 groups to [70]fullerene.

Uses

Copper(I) bromide-dimethyl sulfide can be used as catalyst for adding Grignard reagents to fullerenes.

Purification Methods

Purify it by recrystallisation in the presence of Me2S. A solution of the complex (1.02g) in Me2S (5mL) is slowly diluted with hexane (20mL), and the pure colourless prisms of the complex (0.96g) separate and are collected and dried, m 124-129o(dec). The complex is insoluble in hexane, Et2O, Me2CO, CHCl3 and CCl4. It dissolves in DMF and DMSO, but the solution becomes hot and green indicating decomposition. It dissolves in *C6H6, Et2O, MeOH and CHCl3 if excess of Me2S is added and a colourless solution is obtained. [House et al. J Org Chem 40 1460 1975.] Prior to use, the complex is dissolved in Me2S and evaporated to dryness in the weighed reaction flask [Bourgain-Commer.on et al. J Organomet Chem 228 321 1983].

Copper(I) bromide-dimethyl sulfide Preparation Products And Raw materials

Raw materials

Preparation Products

Ethyl 3-furancarboxylate 3-FURANMETHANOL

More

Less

Copper(I) bromide-dimethyl sulfide Suppliers

Belgium 1 China 147 Germany 1 India 4 Japan 1 Switzerland 1 United Kingdom 4 United States 16 Global 175

Shanghai Chemart Chemical Technology Co., Ltd.

Tel: 021-021-50400622 15618790390
Email: info@chemart.cn
Country: China
ProdList: 223
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

Beijing dtftchem Technology Co., Ltd.

Tel: 010-60275820 13031183356
Fax: 010-60270825
Email: elainezt@sina.com
Country: China
ProdList: 1390
Advantage: 62

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44689
Advantage: 61

Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12438
Advantage: 60

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9414
Advantage: 66

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
Advantage: 64

More

Less

View Lastest Price from Copper(I) bromide-dimethyl sulfide manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: Copper(I) bromide-dimethyl sulfide 54678-23-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-01

Hebei Mojin Biotechnology Co., Ltd

Product: Copper(I) bromide-dimethyl sulfide 54678-23-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-10-16

Career Henan Chemical Co

Product: Copper(I) bromide-dimethyl sulfide 54678-23-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 10KG
Release date: 2019-08-05

54678-23-8, Copper(I) bromide-dimethyl sulfideRelated Search:

Dimethyl sebacate N,N-Dimethylformamide Dimethyl sulfoxide IRON (II) BROMIDE Phosphorus tribromide Dimethyl carbonate Borane-methyl sulfide complex Dacthal ETHANE Thioanisole Cupric bromide Cuprous bromide Dimethyl sulfate Zinc bromide Potassium bromide Boron tribromide Dimethyl sulfide Hydrogen bromide

bromo[thiobis[methane]]copper

CUPROUS BROMIDE METHYLSULFIDE COMPLEX

COPPER(I) BROMIDE DIMETHYL SULFIDE

COPPER(I) BROMIDE-DIMETHYL SULFIDE COMPLEX

BROMO(DIMETHYLSULFIDE)COPPER(I)

Copper(I) bromide methylsulfide complex

Copper, bromothiobismethane-

COPPER BROMIDE-DIMETHYL SULFIDE

Copper(I) bromide methyl sulfide complex, Cuprous bromide methyl sulfide complex

Copper(i)bromide-dimethyl sulfide complex,99%

Copper (I) bromide dimethylsulphide complex

Copper(I) bromide dimethyl sulfide complex,Copper(I) bromide methyl sulfide complex, Cuprous bromide methyl sulfide complex

Copper (I) bromide dimethylsulphide complex 99%

Copper(I) broMide-diMethyl sulfide coMplex, 99% 10GR

Copper(Ⅰ) bromide-dimethyl sulfide complex

Copper(I) bromide methyL

Copper(I) broMide diMethyl sulfide coMplex 99%

COPPERBROMIDE-DIMETHYL SULFIDE COMPLEX

Cuprous bromide dimethyl sulfide complex

C**Copper(I) bromide-dimethyl sulfide

Copper(I) bromide-dimethyl sulfide ISO 9001：2015 REACH

COPPER(1) BROMIDE DMS COMPLEX 95%

Bromocopper

COPPER(1)BROMIDE DMS COMPLEX

54678-23-8

BrC2CuH6S

CH32SCuBr

CuBrCH3SCH3

C2H6BrCuS

CuBrSCH32

C2H6SBrCu

Catalysis and Inorganic Chemistry