Copper(I) bromide-dimethyl sulfide

Product Name: Copper(I) bromide-dimethyl sulfide
CAS No.: 54678-23-8
Chemical Name: Copper(I) bromide-dimethyl sulfide
Synonyms: COPPER(I) BROMIDE-DIMETHYL SULFIDE COMPLEX;COPPER(I) BROMIDE DIMETHYL SULFIDE;Bromocopper;Copper(I) bromide methyL;Copper, bromothiobismethane-;COPPER(1)BROMIDE DMS COMPLEX;bromo[thiobis[methane]]copper;COPPER BROMIDE-DIMETHYL SULFIDE;BROMO(DIMETHYLSULFIDE)COPPER(I);COPPER(1) BROMIDE DMS COMPLEX 95%
CBNumber: CB6332325
Molecular Formula: C2H6BrCuS
Formula Weight: 205.58
MOL File: 54678-23-8.mol

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Copper(I) bromide-dimethyl sulfide Property

Melting point:: 132 °C (dec.)(lit.)
form: Crystalline Powder and/or Chunks
color: Pale brown or pale green
Water Solubility: Soluble in water. Reacts with water and decomposes.
Sensitive: Moisture Sensitive/Air Sensitive
BRN: 4386581
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
InChIKey: PMHQVHHXPFUNSP-UHFFFAOYSA-M
CAS DataBase Reference: 54678-23-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-24/25
RIDADR: 1759
WGK Germany: 3
F: 10-13-21
HazardClass: 8
PackingGroup: III
HS Code: 29309090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 230502
Product name: Copper(I) bromide dimethyl sulfide complex
Purity: 99%
Packaging: 10g
Price: $118
Updated: 2024/03/01

Sigma-Aldrich

Product number: 230502
Product name: Copper(I) bromide dimethyl sulfide complex
Purity: 99%
Packaging: 50g
Price: $320
Updated: 2024/03/01

Alfa Aesar

Product number: 019368
Product name: Copper(I) bromide-dimethyl sulfide complex
Packaging: 2g
Price: $22.65
Updated: 2024/03/01

Alfa Aesar

Product number: 019368
Product name: Copper(I) bromide-dimethyl sulfide complex
Packaging: 10g
Price: $84.6
Updated: 2024/03/01

Strem Chemicals

Product number: 29-0225
Product name: Copper(I) bromide, dimethyl sulfide complex, 99%
Packaging: 25g
Price: $225
Updated: 2021/12/16

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Copper(I) bromide-dimethyl sulfide Chemical Properties,Usage,Production

Chemical Properties

off-white to beige, grey or green crystalline

Uses

Copper(I) bromide-dimethyl sulfide complex is used as catalyst for adding Grignard reagents to fullerenes.

Uses

Catalyst employed in the addition of Grignard reagents (alkyl, alkenyl, aryl) to fullerenes. This process adds 5 organic groups to [60]fullerene and 3 groups to [70]fullerene.

Uses

Copper(I) bromide-dimethyl sulfide can be used as catalyst for adding Grignard reagents to fullerenes.

Purification Methods

Purify it by recrystallisation in the presence of Me2S. A solution of the complex (1.02g) in Me2S (5mL) is slowly diluted with hexane (20mL), and the pure colourless prisms of the complex (0.96g) separate and are collected and dried, m 124-129o(dec). The complex is insoluble in hexane, Et2O, Me2CO, CHCl3 and CCl4. It dissolves in DMF and DMSO, but the solution becomes hot and green indicating decomposition. It dissolves in *C6H6, Et2O, MeOH and CHCl3 if excess of Me2S is added and a colourless solution is obtained. [House et al. J Org Chem 40 1460 1975.] Prior to use, the complex is dissolved in Me2S and evaporated to dryness in the weighed reaction flask [Bourgain-Commer.on et al. J Organomet Chem 228 321 1983].

Copper(I) bromide-dimethyl sulfide Preparation Products And Raw materials

Raw materials

Preparation Products

Ethyl 3-furancarboxylate 3-FURANMETHANOL

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Copper(I) bromide-dimethyl sulfide Suppliers

Belgium 1 China 147 Germany 1 India 4 Japan 1 Switzerland 1 United Kingdom 4 United States 16 Global 175

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View Lastest Price from Copper(I) bromide-dimethyl sulfide manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: Copper(I) bromide-dimethyl sulfide 54678-23-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-01

Hebei Mojin Biotechnology Co., Ltd

Product: Copper(I) bromide-dimethyl sulfide 54678-23-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-10-16

Career Henan Chemical Co

Product: Copper(I) bromide-dimethyl sulfide 54678-23-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 10KG
Release date: 2019-08-05

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54678-23-8

BrC2CuH6S

CH32SCuBr

CuBrCH3SCH3

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Catalysis and Inorganic Chemistry