ChemicalBook > CAS DataBase List > (3-Nitrobenzyl)methylamine

(3-Nitrobenzyl)methylamine

Product Name
(3-Nitrobenzyl)methylamine
CAS No.
19499-61-7
Chemical Name
(3-Nitrobenzyl)methylamine
Synonyms
N-Methyl-1-(3-nitrophenyl)MethanaMine;(3-Nitrobenzyl)methy;(3-NITROBENZYL)METHYLAMINE;3-Nitro-N-methylbenzylamine;N-Methyl-3-nitrobenzylamine;(3-NITROBENZYL)METHYLAMINE 95%;N-METHYL-N-(3-NITROBENZYL)AMINE;N-Methyl-3-nitrobenzylamine,95%;(3-Nitrobenzyl)MethylaMine, 98%+;N-Methyl-3-nitrobenzylaMine, 95%
CBNumber
CB6339788
Molecular Formula
C8H10N2O2
Formula Weight
166.18
MOL File
19499-61-7.mol
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(3-Nitrobenzyl)methylamine Property

Melting point:
160 °C
Boiling point:
128 °C
Density 
1.162±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
8.94±0.10(Predicted)
form 
Oil
Appearance
Light brown to brown Liquid
Water Solubility 
Slightly soluble in water.
InChI
InChI=1S/C8H10N2O2/c1-9-6-7-3-2-4-8(5-7)10(11)12/h2-5,9H,6H2,1H3
InChIKey
NTPAPKLGADEFAM-UHFFFAOYSA-N
SMILES
C1(CNC)=CC=CC([N+]([O-])=O)=C1
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Safety

HazardClass 
8
HS Code 
2921490090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
N926365
Product name
(3-Nitrobenzyl)methylamine
Packaging
500mg
Price
$60
Updated
2021/12/16
AK Scientific
Product number
W4161
Product name
(3-Nitrobenzyl)methylamine
Packaging
5g
Price
$114
Updated
2021/12/16
Apolloscientific
Product number
OR913010
Product name
N-Methyl-N-(3-nitrobenzyl)amine
Purity
98%
Packaging
10g
Price
$182
Updated
2021/12/16
Matrix Scientific
Product number
071763
Product name
(3-Nitrobenzyl)methylamine
Purity
95+%
Packaging
5g
Price
$200
Updated
2021/12/16
Matrix Scientific
Product number
071763
Product name
(3-Nitrobenzyl)methylamine
Purity
95+%
Packaging
1g
Price
$70
Updated
2021/12/16
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(3-Nitrobenzyl)methylamine Chemical Properties,Usage,Production

Uses

N-Methyl-3-nitrobenzylamine is employed as a important raw material and intermediate used in organic synthesis agrochemical, pharmaceutical and dyestuff field.

Synthesis

99-61-6

74-89-5

19499-61-7

1. m-Nitrobenzaldehyde (1 eq., 13.2 mmol, 2.0 g), 40% aqueous methylamine (1.1 eq., 14.5 mmol, 0.95 mL), and 3A molecular sieves (100 mg) were sequentially added to a screw-capped through-hole reaction vial. 2. The reaction mixture was heated at 80 °C for 24 hours. 3. After completion of the reaction, it was cooled to room temperature, the reaction mixture was diluted with chloroform (3 mL) and filtered to remove the molecular sieves. 4. The solvent was removed by rotary evaporation to obtain the crude product. The crude product was dissolved in methanol (30 mL) and cooled to 0°C. 5. Sodium borohydride (1.1 equiv, 14.5 mmol, 550 mg) was added in three batches and the reaction mixture was gradually warmed to room temperature and the reaction was continued for 24 hours. 6. Upon completion of the reaction, the reaction was quenched with 5% aqueous ammonium hydroxide (10 mL) and the solvent was removed by concentration by rotary evaporation. 7. The resulting aqueous layer was extracted with dichloromethane (3 x 10 mL) and the organic phases were combined. 8. The organic phase was dried with anhydrous sodium sulfate, filtered and the filtrate was concentrated by rotary evaporation. 9. The residue was purified by rapid chromatography on silica gel or distilled under vacuum to obtain the target product N-methyl-3-nitrobenzylamine.

References

[1] Molecules, 2017, vol. 22, # 12,
[2] Patent: WO2013/140347, 2013, A1. Location in patent: Page/Page column 48-49
[3] Patent: US2015/51257, 2015, A1. Location in patent: Paragraph 0519-0520

(3-Nitrobenzyl)methylamine Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (3-Nitrobenzyl)methylamine manufacturers

Henan Fengda Chemical Co., Ltd
Product
(3-Nitrobenzyl)methylamine 19499-61-7
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26
Shaanxi Dideu Medichem Co. Ltd
Product
(3-Nitrobenzyl)methylamine 19499-61-7
Price
US $0.00-0.00/Kg
Min. Order
1KG
Purity
99.0%
Supply Ability
100 tons
Release date
2020-01-10

19499-61-7, (3-Nitrobenzyl)methylamineRelated Search:

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