ChemicalBook > CAS DataBase List > Methyl 5-bromonicotinate

Methyl 5-bromonicotinate

Product Name
Methyl 5-bromonicotinate
CAS No.
29681-44-5
Chemical Name
Methyl 5-bromonicotinate
Synonyms
BUTTPARK 37\04-20;METHYL 5-BROMONICOTINATE;Methyl5-Bromonicotinate>5-bromopyridine-3-carboxyL;Methyl 5-bromonicotinate,98%;Methyl 5-bromonicotinate, 97%,;5-Bromonictinic acid ethyl ester;5-BROMONICOTIC ACID METHYL ESTER;5-BROMO NICOTINIC ACID METHYL ESTER;3-(Methoxycarbonyl)-5-bromopyridine
CBNumber
CB6384490
Molecular Formula
C7H6BrNO2
Formula Weight
216.03
MOL File
29681-44-5.mol
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Methyl 5-bromonicotinate Property

Melting point:
96-100 °C
Boiling point:
241.7±20.0 °C(Predicted)
Density 
1.579±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
solid
pka
0.84±0.20(Predicted)
color 
White
Water Solubility 
Slightly soluble in water.
InChI
InChI=1S/C7H6BrNO2/c1-11-7(10)5-2-6(8)4-9-3-5/h2-4H,1H3
InChIKey
AAJZXPWBILCHAW-UHFFFAOYSA-N
SMILES
C1=NC=C(Br)C=C1C(OC)=O
CAS DataBase Reference
29681-44-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
37/38-41-36/37/38
Safety Statements 
26-39-37/39
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
657425
Product name
Methyl 5-bromopyridine-3-carboxylate
Purity
97%
Packaging
5g
Price
$99.1
Updated
2024/03/01
TCI Chemical
Product number
M2008
Product name
Methyl 5-Bromonicotinate
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$32
Updated
2024/03/01
TCI Chemical
Product number
M2008
Product name
Methyl 5-Bromonicotinate
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$90
Updated
2024/03/01
Alfa Aesar
Product number
B20908
Product name
Methyl 5-bromonicotinate, 97%
Packaging
5g
Price
$98.65
Updated
2024/03/01
Alfa Aesar
Product number
B20908
Product name
Methyl 5-bromonicotinate, 97%
Packaging
1g
Price
$24.2
Updated
2021/12/16
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Methyl 5-bromonicotinate Chemical Properties,Usage,Production

Chemical Properties

white powder

Uses

A substrate used in a microwave-assisted, palladium-catalyzed arylation of acetone as its TMS enol ether.

Application

Methyl 5-bromonicotinate could be used to synthesize Pyridine alkaloids from Rubiaceae with various organometallic reagents by palladium-catalyzed cross-coupling reactions. This compound is a derivative of 5-bromonicotinic acid (BrnicH) which has been widely used in the last decade to obtain MOF materials with unique luminescence, magnetism, catalysis, and adsorption through assembling with lanthanide ions and transition metal ions, such as Cu(II), Co(II), Cd(II), Zn(II), and Pb(II)[1-2].

Synthesis

To an ice-cooled suspension of 5-bromo nicotinic acid (1.6g, 7.9 mmol) in diethyl ether (20ml), a solution of diazomethane in diethyl ether was added dropwise with stirring until the mixture remained yellow. The mixture was stirred for additional 15min (hood!), and the volatile compounds were removed by distillation in vaeuo. Finally, Methyl 5-bromonicotinate was obtained after purification[2].

References

[1] WENJIE LI . Syntheses, crystal structures, and properties of new metal–5-bromonicotinate coordination polymers[J]. Journal of Solid State Chemistry, 2015. DOI:10.1016/j.jssc.2015.01.002.
[2] Bracher, F., Papke, T. Total syntheses and antimicrobial activities of pyridine alkaloids from Rubiaceae. Monatsh Chem 126, 805–809 (1995). https://doi.org/10.1007/BF00807174

Methyl 5-bromonicotinate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl 5-bromonicotinate manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Methyl 5-bromonicotinate 29681-44-5
Price
US $10.00-8.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-12-05
Career Henan Chemical Co
Product
Methyl 5-bromonicotinate 29681-44-5
Price
US $7.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100KG
Release date
2018-12-17

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