2,2-Bis(hydroxymethyl)butyric acid

Product Name: 2,2-Bis(hydroxymethyl)butyric acid
CAS No.: 10097-02-6
Chemical Name: 2,2-Bis(hydroxymethyl)butyric acid
Synonyms: 2,2-dimethylolbutanoic acid;2,2-BIS(HYDROXYMETHYL)BUTANOIC ACID;Dimethylolbutansure;2,2-Bis(hydroxymethy;DimethylolButanoicAcid;2,2-DIMETHYLOLBUTYRIC ACID;DimethylolButanoicAcid(Dmba);Dimethylolbutanoie Acid(DMBA);2,2-bis-(Hydroxymethyl)-n-buty;2,2-Dimethylolbutyric acid、DMBA
CBNumber: CB6407931
Molecular Formula: C6H12O4
Formula Weight: 148.16
MOL File: 10097-02-6.mol

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2,2-Bis(hydroxymethyl)butyric acid Property

Melting point:: 109-112 °C (lit.)
Boiling point:: 360.0±32.0 °C(Predicted)
Density: 1.263±0.06 g/cm3(Predicted)
vapor pressure: 0Pa at 25℃
storage temp.: Sealed in dry,Room Temperature
solubility: acetone: 18 wt. % at 40 °C
pka: 4.16±0.15(Predicted)
form: powder to crystal
color: White to Almost white
Water Solubility: 487g/L at 20℃
InChI: InChI=1S/C6H12O4/c1-2-6(3-7,4-8)5(9)10/h7-8H,2-4H2,1H3,(H,9,10)
InChIKey: JVYDLYGCSIHCMR-UHFFFAOYSA-N
SMILES: C(O)(=O)C(CO)(CO)CC
LogP: -0.68 at 20℃
CAS DataBase Reference: 10097-02-6(CAS DataBase Reference)
EPA Substance Registry System: Butanoic acid, 2,2-bis(hydroxymethyl)- (10097-02-6)

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Safety

Hazard Codes: Xi
Risk Statements: 41-52/53
Safety Statements: 26-39-61
WGK Germany: 1
Hazard Note: Irritant
TSCA: TSCA listed
HS Code: 29181990
Storage Class: 11 - Combustible Solids
Hazard Classifications: Aquatic Chronic 3
Eye Dam. 1

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H318Causes serious eye damage

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 470627
Product name: 2,2-Bis(hydroxymethyl)butyric acid
Purity: 98%
Packaging: 100g
Price: $80.7
Updated: 2025/07/31

TCI Chemical

Product number: B2038
Product name: 2,2-Bis(hydroxymethyl)butyric Acid
Purity: >97.0%(T)
Packaging: 25g
Price: $36
Updated: 2025/07/31

TCI Chemical

Product number: B2038
Product name: 2,2-Bis(hydroxymethyl)butyric Acid
Purity: >97.0%(T)
Packaging: 500g
Price: $192
Updated: 2025/07/31

TRC

Product number: H947613
Product name: 2,2-Bis(hydroxymethyl)butanoicAcid
Packaging: 2.5g
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 099134
Product name: 2,2-Bis(hydroxymethyl)butanoic acid
Purity: 95+%
Packaging: 100g
Price: $84
Updated: 2021/12/16

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2,2-Bis(hydroxymethyl)butyric acid Chemical Properties,Usage,Production

Uses

2,2-bis(hydroxymethyl)butyric acid is a good crosslinking agent and hydrophilic agent, or used to produce water-based high molecule system, is widely used in water soluble PU system, polyester resin and epoxy ester. With good solubility, it also is widely used in coating of water soluble PU system, adhesive and leather coating agent.. It will become a new kind of environment-friendly substitute of 2,2-Bis(hydroxymethyl)propionic acid.

Uses

Monomer for making water soluble polyurethanes and polyesters.

Flammability and Explosibility

Non flammable

Synthesis

In a 1000 ml four-necked flask add 96 grams of paraformaldehyde, 96 grams of water, start stirring, temperature, at about 50 degrees dropwise addition of 80 grams of content of 5 % liquid alkali, control pH between 9-10 in 2 hours dropwise addition is completed, continue to hold the reaction for 4 hours, raise the temperature to 80 ?? C to recover not fully reacted n-butyraldehyde, as well as a small amount of formaldehyde solution, endothermic steaming to 100 degrees Celsius, stop the distillation, lower the temperature, control at about 50 degrees Celsius, and slowly dropwise addition of 220 grams content of 27 % of hydrogen peroxide, control the completion of the drop in 2 hours, after the completion of the drop, insulation reaction for 6 hours, add concentrated sulfuric acid acid, reduce pressure to 12 kPa evaporation of water, evaporation, add methyl isobutyl ketone 200 grams of reflux to 100 ?? reflux division of water, after the division of water, lower the temperature, filtration of solid salts while hot, the filtrate is further cooled down, precipitation of crystals, get crude, the crude is added to the solvent to carry out a further The crude product was added into the solvent and recrystallized to obtain white crystals, and the total yield of 2,2-dihydroxymethylbutyric acid was 41%.

2,2-Bis(hydroxymethyl)butyric acid Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2-Bis(hydroxymethyl)butyric acid Suppliers

Americas 1 China 394 Europe 2 Germany 3 India 2 Japan 3 Slovakia 1 South Korea 2 Switzerland 1 The Netherlands 2 Ukraine 1 United Kingdom 10 United States 15 Global 437

Dongyang Baihang Chemical Co., Ltd.

Tel: 0579-86886233 18006543966
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Shanghai ideal Industrial Co., Ltd.

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Nantong Zhonghe Chemical New Materials Co., Ltd

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Guangzhou Rui Lion Biotechnology Co., LTD

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J & K SCIENTIFIC LTD.

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Meryer (Shanghai) Chemical Technology Co., Ltd.

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TCI (Shanghai) Development Co., Ltd.

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Beijing HwrkChemical Technology Co., Ltd

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Energy Chemical

Tel: 021-021-58432009 400-005-6266
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Zhang Jia Gang YaRui Chemical co.,Ltd

Tel: 0512-58961066 18921980669
Fax: 86-0512-58961068
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View Lastest Price from 2,2-Bis(hydroxymethyl)butyric acid manufacturers

Yunjian (Guangzhou) Import Export Trade Co., Ltd

Product: 2,2-Bis(hydroxymethyl)butyric acid 10097-02-6
Price: US $0.00/kg
Min. Order: 25kg
Purity: i
Supply Ability: 40MT
Release date: 2025-06-18

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 2,2-Bis(hydroxymethyl)butyric acid 10097-02-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-25

Hebei Chuanghai Biotechnology Co., Ltd

Product: 2,2-Bis(hydroxymethyl)butyric acid 10097-02-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-28

10097-02-6, 2,2-Bis(hydroxymethyl)butyric acidRelated Search:

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2,2-DIMETHYLOLBUTYRIC ACID

2,2-BIS(HYDROXYMETHYL)BUTYRIC ACID

2,2-BIS(HYDROXYMETHYL)-N-BUTYRIC ACID

2,2-BIS(HYDROXYMETHYL)BUTANOIC ACID

2,2-dimethylolbutanoic acid

2,2-Bis(hydroxymethy

Bis (hydroxyMethyl) butyric acid

2,2'-Bis(hydroxyMethyl)butyric acid(DMBA)

DimethylolButanoicAcid(Dmba)

DimethylolButanoicAcid

2,2-bis-(Hydroxymethyl)-n-buty

Butanoic acid, 2,2-bis(hydroxymethyl)-

Dimethylolbutansure

2,2-BIS(HYDROXYMETHYL)-N-BUTYRIC ACID 97+%

2,2-BIS(HYDROXYMETHYL)BUTYRIC ACID (DIMETHYLOL BUTANOIC ACID)

Dimethylolbutanoie Acid(DMBA)

2,2-DiMethylolbutanoieacid(DMBA)

2,2-Bis(hydroxyMethyl)butyric acid 98%

DMBA 2,2-Dimethylolbutyric Acid

2,2-dimethylolbutanoic acid, chain extender hydrophilic agent DMBA

2,2-Bis(hydroxymethyl)butyric acid Vetec(TM) reagent grade, 98%

2,2-Bis(hydroxymethyl)butyric Acid &gt

2,2'-Bis(hydroxymethyl)butyric acid

2,2-Dimethylolbutyric acid、DMBA

2,2-dihydroxymethylbutyric acid DMBA

10097-02-6

C2H5CCH2OH2CO2H

Fluorenes, etc. (reagent for high-performance polymer research)

Reagent for High-Performance Polymer Research

Alcohols

Monomers

Polymer Science

fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis

Organic acids

Fluorenes, etc. (reagent for high-performance polymer research)

Functional Materials

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bc0001

10097-02-6